Redefined element factor for simplified i.d.t. design

It is shown that the response of interdigital transducers with uniform periodicity and duty factor can be written as the product of a redefined element factor and an array factor even if the magnitude and phase of the electrode voltages are completely arbitrary.     

An area model for on-chip memories and its application

An area model suitable for comparing data buffers of different organizations (e.g. caches versus register files) and arbitrary sizes is described. The area model considers the supplied bandwidth of a memory cell and includes such buffer overhead as control logic, driver logic and tag storage. The model gave less than 10% error when verified against real caches and register files. It is shown that, comparing caches and register files in terms of area for the same storage capacity, caches generally occupy more area per bit than register files for small caches because the overhead dominates the cache area at these sizes. For larger caches, the smaller storage cells in the cache provide a smaller total cache area per bit than the register set. Studying cache performance (traffic ratio) as a function of area, it is shown that, for small caches (less than the area occupied by 256 registers bits-r.b.e.-or 32 b), direct-mapped caches perform significantly better than four-way set-associative caches and, for caches of medium areas (between 256 r.b.e. and 4096 r.b.e.), both direct-mapped and set-associative caches perform better than fully associative caches     

Der Resonanznachweis von Ionen im Omegatron

Ohne Zusammenfassung     

Carbon monoxide as an intrinsic ligand to iron in the active site of the iron-sulfur-cluster-free hydrogenase H2-forming methylenetetrahydromethanopterin dehydrogenase as revealed by infrared spectroscopy

The iron-sulfur-cluster-free hydrogenase Hmd (H(2)-forming methylenetetrahydromethanopterin dehydrogenase) from methanogenic archaea has recently been found to contain one iron associated tightly with an extractable cofactor of yet unknown structure. We report here that Hmd contains intrinsic CO bound to the Fe. Chemical analysis of Hmd revealed the presence of 2.4 +/- 0.2 mol of CO/mol of iron. Fourier transform infrared spectra of the native enzyme showed two bands of almost equal intensity at 2011 and 1944 cm(-)(1), interpreted as the stretching frequencies of two CO molecules bound to the same iron in an angle of 90 degrees . We also report on the effect of extrinsic (12)CO, (13)CO, (12)CN(-), and (13)CN(-) on the IR spectrum of Hmd.     

Hole- and electron-vibrational couplings in oligoacene crystals: intramolecular contributions

The hole-vibrational coupling is reported for anthracene, tetracene, and pentacene on the basis of a joint experimental and theoretical study of ionization spectra using high-resolution gas-phase photoelectron spectroscopy and first-principles correlated quantum-mechanical calculations. The hole-vibrational coupling is found to be significantly smaller than the electron-vibrational coupling in the case of these oligomers; however, both quantities are predicted to converge to the same value when increasing the chain length.     

Layer 1 virtual private network management by users

The layer 1 virtual private network (LlVPN) technology supports multiple user networks over a common carrier transport network. Emerging L1VPN services allow: L1VPNs to be built over multiple carrier networks; L1VPNs to lease or trade resources with each other; and users to reconfigure an L1VPN topology, and add or remove bandwidth. The trend is to offer increased flexibility and provide management functions as close to users as possible, while maintaining proper resource access right control. In this article two aspects of the L1VPN service and management architectures are discussed: management of carrier network partitions for L1VPNs, and L1VPN management by users. We present the carrier network partitioning at the network element (NE) and L1VPN levels. As an example, a transaction language one (TL1) proxy is developed to achieve carrier network partitioning at the NE level. The TL1 proxy is implemented without any modifications to the existing NE management system. On top of the TL1 proxy, a Web services (WS)-based L1VPN management tool is implemented. Carriers use the tool to partition resources at the L1VPN level by assigning resources, together with the WS-based management services for the resources, to L1VPNs. L1VPN administrators use the tool to receive resource partitions from multiple carriers and partner L1VPNs. Further resource partitioning or regrouping can be conducted on the received resources, and leasing or trading resources with partner LlVPNs is supported. These services offer a potential business model for a physical network broker. After the L1VPN administrators compose the use scenarios of resources, and make the use scenarios available to the L1VPN end users as WS, the end users reconfigure the L1VPN without intervention from the administrator. The tool accomplishes LlVPN management by users     

De novo design and characterization of copper centers in synthetic four-helix-bundle proteins.

The design and chemical synthesis of de novo metalloproteins on cellulose membranes with the structure of an antiparallel four-helix bundle is described. All possible combinations of three different sets of amphiphilic helices were assembled on cyclic peptide templates which were bound by a cleavable linker to the cellulose. In the hydrophobic interior, the four-helix bundle proteins carry a cysteine and several histidines at various positions for copper ligation. This approach was used successfully to synthesize, for the first time, copper proteins based on a four-helix bundle. UV-vis spectra monitored on the solid support showed ligation of copper(II) by about one-third out of the 96 synthesized proteins and tetrahedral complexes of cobalt(II) by most of these proteins. Three of the most stable copper-binding proteins were synthesized in solution and their structural properties analyzed by spectroscopic methods. Circular dichroism, one-dimensional NMR, and size-exclusion chromatography indicate a folding into a compact state containing a high degree of secondary structure with a reasonably ordered hydrophobic core. They displayed UV-vis absorption, resonance Raman, and EPR spectra intermediate between those of type 1 and type 2 copper centers. The present approach provides a sound basis for further optimizing the copper binding and its functional properties by using combinatorial protein chemistry guided by rational principles.