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131.
Berthold J.E. 《Proceedings of the IEEE. Institute of Electrical and Electronics Engineers》1990,78(3):486-511
The functions necessary in broadband communications systems at speeds above 50 Mb/s are discussed. The types of components and functionality that are needed for access to networks and for the transmission and routing of traffic within networks are identified. Integrated circuit components used for customer-network access, network multiplexing, and switching are reviewed. It is shown that currently available digital VLSI technology is capable of achieving both the speeds and the levels of integration necessary to allow broadband network access even to residential subscribers 相似文献
132.
In order to clarify the validity of the theory of nuclearβ-transition a new formulation is given. The nuclear properties are contained in form factors, arising from a decomposition of the matrix element of the V-A operator for nuclear states. The connection of these form factors with nuclear physics matrix elements is tabulated. The total transition amplitude can be written as an integral over these form factors folded with off-shell amplitudes for elastic and inelastic electron scattering on nuclei. 相似文献
133.
An apparatus is described, which permits the evaporation of nonconducting substances with high melting points by electron bombardment. 相似文献
134.
Berthold J. Maier 《Archiv der Mathematik》1981,37(1):113-128
Ohne ZusammenfassungDiese Arbeit enthält Ergebnisse aus der an der Albert-Ludwigs-Universität, Freiburg angefertigten Dissertation [11]. 相似文献
135.
Matthias Weil Berthold Stger 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(9):i79-i81
In contrast with the multiple twinning and/or domain formation found in the mica‐like polymorphs of CaTe2O5, calcium pentaoxidoditellurate(IV), that have been prepared by solid‐state reactions and for which complete structure determinations have not been successful up to now, the crystal structure of a hydrothermally grown phase was fully determined from a non‐twinned crystal. The structure is made up of alternating layers of Ca2+ cations and of 2∞[Te2O5]2− anions stacked along [100]. The lone‐pair electrons E of the TeIV atoms are stereochemically active and protrude into channels within the anionic layer. In comparison with analogous MIITe2O5 structures (M = Mg, Mn, Ni or Cu) with ditellurate(IV) anions that are exclusively made up of corner‐sharing TeOx (x = 3–5) polyhedra resulting in flat 2∞[Te2O5]2− layers, the anionic layers in CaTe2O5 are undulating and are built of corner‐ and edge‐sharing [TeO4] polyhedra. 相似文献
136.
The borohydride complex [Ni(II)2L(mu-BH4)]+ (3) where L(2-) represents a sterically demanding hexaaza-dithiophenolate ligand reacts rapidly with elemental sulfur in acetonitrile at ambient temperature to produce the cationic complexes [Ni(II)2L(mu-SH)]+ (4) and [(Ni(II)2L) 2(mu-S6)]2+ (6). Both complexes were isolated as ClO4(-) or BPh4(-) salts and characterized by IR and UV/vis spectroscopy and X-ray crystallography. Complex 4 (also accessible from [Ni(II)2L(ClO4)]+ (5) and Na2S.9H2O) features an unprecedented N3Ni(II)(mu-SR)2(mu-SH)Ni(II)N3 core structure, the hydrosulfide ligand being deeply buried in the binding-cavity of the bowl-shaped [Ni(II)2L]2+ complex. In 6, a helical S6(2-) chain, with a structure reminiscent to that of plastic sulfur, is almost completely encapsulated by two [Ni(II)2L]2+ subunits. In contrast to other triply sulfur-bridged N3Ni(II)(SR)3Ni(II)N3 structures whose ground states are typically of S = 0, 4 reveals an S = 2 ground-state which is attained by a ferromagnetic exchange interaction between the two Ni(II) (S = 1) ions ( J = 18 cm (-1), H = -2JS1S2). Intradimer ferromagnetic exchange interactions are also present in 6 ( J = 23 cm (-1)). A qualitative explanation for this difference is offered. 相似文献
137.
Sathiyamoorthy Murugesan Berthold Stger Ernst Pittenauer Günter Allmaier Luis F. Veiros Karl Kirchner 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2016,128(9):3097-3100
The synthesis and reactivity of a CoI pincer complex [Co(ϰ3P,CH,P‐P(CH)PNMe‐iPr)(CO)2]+ featuring an η2‐ Caryl−H agostic bond is described. This complex was obtained by protonation of the CoI complex [Co(PCPNMe‐iPr)(CO)2]. The CoIII hydride complex [Co(PCPNMe‐iPr)(CNtBu)2(H)]+ was obtained upon protonation of [Co(PCPNMe‐iPr)(CNtBu)2]. Three ways to cleave the agostic C−H bond are presented. First, owing to the acidity of the agostic proton, treatment with pyridine results in facile deprotonation (C−H bond cleavage) and reformation of [Co(PCPNMe‐iPr)(CO)2]. Second, C−H bond cleavage is achieved upon exposure of [Co(ϰ3P,CH,P‐P(CH)PNMe‐iPr)(CO)2]+ to oxygen or TEMPO to yield the paramagnetic CoII PCP complex [Co(PCPNMe‐iPr)(CO)2]+. Finally, replacement of one CO ligand in [Co(ϰ3P,CH,P‐P(CH)PNMe‐iPr)(CO)2]+ by CNtBu promotes the rapid oxidative addition of the agostic η2‐Caryl−H bond to give two isomeric hydride complexes of the type [Co(PCPNMe‐iPr)(CNtBu)(CO)(H)]+. 相似文献
138.
The Bis(pentafluoroethyl)germylene Trimethylphosphane Adduct (C2F5)2Ge⋅PMe3: Characterization,Ligand Properties,and Reactivity 下载免费PDF全文
Dr. Stefanie Pelzer Beate Neumann Dr. Hans‐Georg Stammler Dr. Nikolai Ignat'ev Prof. Dr. Berthold Hoge 《Angewandte Chemie (International ed. in English)》2016,55(20):6088-6092
The synthesis of the germylene phosphane adduct (C2F5)2Ge?PMe3 is described. Starting from (C2F5)3GeH in an excess of PMe3, heating was applied, whereupon reductive elimination of C2F5H occurred. The molecular structure was ascertained by X‐ray diffraction and compared with information obtained by quantum chemical methods. The ligand properties were derived by studying the IR spectrum of the nickel(0) complex [Ni(CO)3{Ge(C2F5)2(PMe3)}] in the CO region. (C2F5)2Ge?PMe3 turned out to be a π‐accepting ligand comparable to PMe3, in terms of Tolman's electronic parameter. Furthermore a [2+4] cycloaddition reaction with 2,3‐dimethyl‐1,3‐butadiene, and σ‐bond insertion reactions were recorded. Activation of the C?Cl bond in dichloromethane gives rise to the formation of the phosphonium ylide complex [(C2F5)2Cl2Ge‐CH2PMe3], which was fully characterized by X‐ray diffraction. 相似文献
139.
Robin F. Weitkamp Beate Neumann Dr. Hans-Georg Stammler Prof. Dr. Berthold Hoge 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(3):915-920
The reaction of a saline phosphazenium hydroxide hydrate with siloxanes led to a novel kind of silanol-silanolate anions. The weakly coordinating behavior of the cation renders the formation of silanol-silanolate hydrogen bonds possible, which otherwise suffer from detrimental silanolate–oxygen cation interactions. We investigated the influence of various weakly coordinating cations on silanol-silanolate motifs, particularly with regard to different cation sizes. While large cations favor the formation of intramolecular hydrogen bonds resulting in cyclic structures, the less bulky tetramethyl ammonium cation encourages the formation of polyanionic silanol-silanolate chains in the solid state. 相似文献
140.