Thermal behavior of cardanol resin reinforced 20 mm long untreated bagasse fiber composites

Recently the attention in composite materials reinforced with natural fibers has significantly increased due to the new environmental legislation as well as consumer pressure that forced manufacturing industries to search substitutes for the conventional materials, e.g., glass fibers. In this way, the objective of the paper was to evaluate the thermal properties of sugarcane bagasse fiber-cardanol resin composites. Fibers were cut down to 20?mm length in diagonally. These fibers were mixed with the cardanol and epoxy resin, and fabricate in a biocomposites with different compositions, such as 0, 5, 10, 15, and 20?wt%. The thermal properties were evaluated by thermal gravimetric analysis and differential thermogravimetry analysis and also chemical formulation studied in Fourier transform infrared spectroscopy. The results showed the improved thermal strength of the composites in comparison to the neat polymer (0?wt%).     

Synergistic extraction and spectrophotometric determination of copper(II) using 1-(2',4'-dinitro aminophenyl)-4,4,6-trimethyl-1,4-dihydropyrimidine-2-thiol: analysis of alloys, pharmaceuticals and biological samples

A simple and selective spectrophotometric method was developed for the determination of copper(II) with 1-(2',4'-dinitro aminophenyl)-4,4,6-trimethyl-1,4-dihydropyrimidine-2-thiol [2',4'-dinitro APTPT] as a chromogenic reagent. The procedure was based on the synergistic extraction of copper(II) with 2',4'-dinitro APTPT in the presence of 0.5 mol L(-1) pyridine to give green colored ternary complex of a molar ratio 1:2:2 (M:L:Py) in the pH range 8.7-10.5. It exhibits a maximum absorption of colored complex at 445 nm and 645 nm in chloroform against the reagent blank. Beer's law was followed in the concentration range 10-80 μg mL(-1) of copper(II) and optimum range of 20-70 μg mL(-1) the metal as evaluated from Ringbom's plot. The molar absorptivity and Sandell's sensitivity of copper(II)-2',4'-dinitro APTPT-pyridine complex in chloroform are 0.87×10(3) L mol(-1)c m(-1) and 0.072 μg cm(-2), respectively. The interfering effects of various cations and anions were also studied, and use of suitable masking agents enhances the selectivity of the method. The proposed method is rapid, reproducible and successfully applied for the determination of copper(II) in binary and synthetic mixtures, alloys, pharmaceutical formulations, environmental and fertilizer samples. Comparison of the results with those obtained using an atomic absorption spectrophotometer also tested the validity of the method.     

Experimental and computational studies of selective recognition of Hg2+ by amide linked lower rim 1,3-dibenzimidazole derivative of calix[4]arene: species characterization in solution and that in the isolated complex, including the delineation of the nanostructures

Amide linked lower rim 1,3-dibenzimidazole derivative of calix[4]arene, L has been shown to be sensitive and selective to Hg(2+) in aqueous acetonitrile solution based on fluorescence spectroscopy, and the stoichiometry of the complexed species has been found to be 1:1. The selectivity of L toward Hg(2+) has been shown among 11 M(2+) ions, viz., Mn(2+), Fe(2+), Co(2+), Ni(2+), Cu(2+), Zn(2+), Cd(2+), Hg(2+), Pb(2+), Ca(2+), and Mg(2+) studied, including those of the mercury group and none of these ions impede the recognition of Hg(2+) by L. Role of the solvent on the recognition of Hg(2+) has been demonstrated. The role of calix[4]arene platform and the benzimidazole moieties in the recognition of Hg(2+) by L has been delineated upon performing such studies with five different molecules of relevance as reference molecular systems. The binding cores formed by the receptor L and the reference compounds have been established based on the single crystal XRD structures, and the preferential metal ion binding cores have been discussed. The binding of Hg(2+) with L has been further established based on (1)H and (13)C NMR, ESI MS, absorption, and fluorescence lifetime measurements. Some of these techniques have been used to establish the stoichiometry of the species formed. The complex species formed between L and Hg(2+) have been isolated and characterized and found to be 1:1 species even in the isolated complex. Whereas transmission electron microscopy (TEM), atomic force microscopy (AFM), and scanning electron microscopy (SEM) provided the nanostructural behavior of L, the TEM and SEM demonstrated that the mercury complex has different characteristics when compared to L. The TEM, SEM, and powder XRD studies revealed that whereas L is crystalline, that of the mercury complex is not, perhaps a reason for not being able to obtain single crystals of the complex. Binding characteristics of Hg(2+) toward L have been established based on the DFT computational calculations.     

Performance and Analysis of Advanced and Enhanced Security Protocol for Vehicular Ad Hoc Networks (VANETs)

VANETs- Vehicular Ad Hoc Networks depends on organizing the innovation where the vehicles go about as versatile hubs for shaping a correspondence arrange. The arrangement of vehicular specially appointed systems doesn't just encourage novel telematics applications. The selection of dynamic wellbeing application raises new dangers to street wellbeing if security issues are not appropriately taken care-of. An extraordinary dynamic security application is viewed as the empowers those foresights the passing of the trading of nearby threat alerts that depends on singular perceptions. VANET is considered by many specialist co-ops in urban situations. As it were, communicate tempest corrupts the directing presentation. The issue is addressed and examined by various protocols such as AODV, DSR, DYMO, TORA and TIHOO. The proposed protocol Advanced and enhanced security protocol for VANET (AESP-VANET) which is an upgraded that also depends on improved fluffy and cuckoo ways for dealing with location of the steadiest way between a source and a goal hub. The disclosure of the courses is restricted brilliantly by AESP-VANET by utilizing fuzzy framework thereby constraining the messages that are course demand. The improved cuckoo calculation in hybrid methodology, which is one of the best meta-calculations particularly in the huge inquiry space, brilliantly chooses the most steady and ideal course among realized courses by computing an upgraded wellness work. AESP-VANET gives out the result using Network Simulator-2. This shows a tremendous improvement in the throughput, overhead, and many more parameters which is the objective of the proposed model.

     

A new piecewise exponential estimator of a survival function

In 1983, Kitchin, Langberg and Proschan introduced a piecewise exponential estimator (PEXE) of a survival function for censored data that is undefined beyond the last observation. We propose a new PEXE that provides an exponential tail with a hazard rate determined by a novel nonparametric consideration.     

Excitation of ion cyclotron waves at the difference frequency of two microwave beams in a semiconductor

This paper presents an investigation of the resonant excitation of the electrostatic ion cyclotron wave at the difference frequency of two microwave beams propagating in a magnetoactive solid state plasma, viz. n InSb. The resonant excitation of the electrostatic ion cyclotron wave occurs when the difference frequency of the two microwave beams and the difference of their propagation vectors satisfy the dispersion relation corresponding to the electrostatic ion cyclotron wave. For typical plasma parameters of n InSb and microwave beams of power densities 1 MW cm^?2, the power density of the excited ion cyclotron wave is 0.40 kW cm^?2 when external magnetic field is $\text{1.46 kG (}\text{Ω}{}_{\mathrm{c}}\text{ω}\text{) = 0.1)}$. The power density of the excited ion cyclotron wave increases with the magnetic field. This study may provide new means for the characterisation and diagnostic of semiconductors.     

Static lateral stiffness of wire rope isolators

This paper presents an analytical model for the static lateral stiffness of Wire Rope Isolators (WRI). The wire rope isolator, which is a passive isolation device, has been widely adopted as a shock and vibration isolation for many types of equipment and lightweight structures. The major advantage of the WRI is its ability to provide isolation in all three planes and in any orientation. The WRI in the lateral roll mode, is required to possess the required lateral stiffness to support and isolate the equipment effectively. The static lateral stiffness of WRI depends mainly on the geometrical characteristics and wire rope properties. The model developed in this paper is validated experimentally using a series of monotonic loading tests. The flexural rigidity of the wire ropes, which is required in the model, was determined from the transverse bending test on several wire rope cables. It was observed that the lateral stiffness is significantly influenced by the wire rope diameter and height of the isolator. The proposed analytical model can be used for the evaluation of lateral stiffness and in the preliminary design of the WRI.     

Proofs of the Parisi and Coppersmith‐Sorkin random assignment conjectures

Suppose that there are n jobs and n machines and it costs c_ij to execute job i on machine j. The assignment problem concerns the determination of a one‐to‐one assignment of jobs onto machines so as to minimize the cost of executing all the jobs. When the c_ij are independent and identically distributed exponentials of mean 1, Parisi [Technical Report cond‐mat/9801176, xxx LANL Archive, 1998] made the beautiful conjecture that the expected cost of the minimum assignment equals . Coppersmith and Sorkin [Random Structures Algorithms 15 ( 6 ), 113–144] generalized Parisi's conjecture to the average value of the smallest k‐assignment when there are n jobs and m machines. Building on the previous work of Sharma and Prabhakar [Proc 40th Annu Allerton Conf Communication Control and Computing, 20 , 657–666] and Nair [Proc 40th Annu Allerton Conf Communication Control and Computing, 17 , 667–673], we resolve the Parisi and Coppersmith‐Sorkin conjectures. In the process we obtain a number of combinatorial results which may be of general interest.© 2005 Wiley Periodicals, Inc. Random Struct. Alg. 2005     

Mechanisms with learning for stochastic multi-armed bandit problems

The multi-armed bandit (MAB) problem is a widely studied problem in machine learning literature in the context of online learning. In this article, our focus is on a specific class of problems namely stochastic MAB problems where the rewards are stochastic. In particular, we emphasize stochastic MAB problems with strategic agents. Dealing with strategic agents warrants the use of mechanism design principles in conjunction with online learning, and leads to non-trivial technical challenges. In this paper, we first provide three motivating problems arising from Internet advertising, crowdsourcing, and smart grids. Next, we provide an overview of stochastic MAB problems and key associated learning algorithms including upper confidence bound (UCB) based algorithms. We provide proofs of important results related to regret analysis of the above learning algorithms. Following this, we present mechanism design for stochastic MAB problems. With the classic example of sponsored search auctions as a backdrop, we bring out key insights in important issues such as regret lower bounds, exploration separated mechanisms, designing truthful mechanisms, UCB based mechanisms, and extension to multiple pull MAB problems. Finally we provide a bird’s eye view of recent results in the area and present a few issues that require immediate future attention.     

Ideals of analytic deviation one with respect to a Cohen-Macaulay module

Let (A, m) be a Cohen-Macaulay local ring, M a Cohen-Macaulay A-module of dimension d ≥ 1 and I a proper ideal of analytic deviation one with respect to M. In this paper we study the Cohen-Macaulayness of associated graded module of a Cohen-Macaulay module. We show that if I is generically a complete intersection of analytic deviation one and reduction number at most one with respect to M then G _I (M) is Cohen-Macaulay. When analytic spread of I with respect to M equals d we prove a similar result when reduction number of an ideal is atmost two.