MHNAMT,a new locating and chelating agent in thin-layer chromatographic determination of Cu(II), Co(II), Ni(II), Pd(II), Pt(IV), and Rh(III)

Summary Synthesis of MHNAMT [3-methyl-4-(2-hydroxy-1 naphthalideneamino)-5-mercapto-1,2,4-triazole] and its IR and NMR spectral data are reported. The high stability of the characteristically coloured chelates with Cu(II), Co(II), Ni(II), Pd(II), Pt(IV) and Rh(III) has been made the basis for their efficient ascending TLC separations on silica gel G layers, when present together. Results of three different solvent systems are included to assess efficient resolution of the chelates.     

Dynamic nuclear polarization at 9T using a novel 250GHz gyrotron microwave source

In this communication, we report enhancements of nuclear spin polarization by dynamic nuclear polarization (DNP) in static and spinning solids at a magnetic field strength of 9T (250 GHz for g=2 electrons, 380 MHz for 1H). In these experiments, 1H enhancements of up to 170+/-50 have been observed in 1-13C-glycine dispersed in a 60:40 glycerol/water matrix at temperatures of 20K; in addition, we have observed significant enhancements in 15N spectra of unoriented pf1-bacteriophage. Finally, enhancements of approximately 17 have been obtained in two-dimensional 13C-13C chemical shift correlation spectra of the amino acid U-13C, 15N-proline during magic angle spinning (MAS), demonstrating the stability of the DNP experiment for sustained acquisition and for quantitative experiments incorporating dipolar recoupling. In all cases, we have exploited the thermal mixing DNP mechanism with the nitroxide radical 4-amino-TEMPO as the paramagnetic dopant. These are the highest frequency DNP experiments performed to date and indicate that significant signal enhancements can be realized using the thermal mixing mechanism even at elevated magnetic fields. In large measure, this is due to the high microwave power output of the 250 GHz gyrotron oscillator used in these experiments.     

Heat transport in turbulent rayleigh-Benard convection

We present measurements of the Nusselt number N as a function of the Rayleigh number R in cylindrical cells with aspect ratios 0. 510(7) they are consistent with N = asigma-1/12R1/4+bsigma-1/7R3/7 as proposed by Grossmann and Lohse for sigma greater, similar2.     

Intensity-reversal in the donor bound exciton luminescence of GaAs

A self-reversal model is presented to explain the luminescence dependence of the donor bound exciton intensity. The line broadening mechanism is attributed to rotational interaction with non-rigid rotator states. Line reversal results from absorption by non-broadened states near the crystal surface. The absence of a similar excitation intensity dependence for acceptor bound excitons is explained.     

Photoluminescence studies of the amphoteric behavior of carbon and germanium in GaAs

Recombination radiation due to an exciton bound to neutral donors and neutral acceptors in high purity vapor phase epitaxial GaAs is investigated using high resolution photoluminescence spectroscopy at liquid helium temperatures. It is found that those samples which show the presence of germanium acceptors also exhibit a strong residual donor referred to in the literature as X₃. Samples containing carbon acceptors however, do not show the presence of X₃. In the past X₃ has been identified by some groups as due to carbon on the gallium site. The work presented here sugests that the X₃ donor is associated with germanium. This identification of the X₃ donor is in agreement with a recent assignment based on the far infrared study of neutron transmuted GaAs.     

The electroweak mixing angle in unified gauge theories

We study in detail the factors that influence the unification relations among the coupling parameters of strong and electroweak interactions. We find that the factor that decides the unification relations in a theory is the fermion content of the theory. The specific ‘observed’ group of strong and electroweak interactions used and the specific unification group in which these interactions are embedded are largely irrelevant. In particular, we find that the unification value of the electroweak mixing angle is the same for almost all models of interest. We also explicitly illustrate that the canonical value 3/8 of the mixing angle is a characteristic result of the currently popular sequential doublets scheme of fermions. Addition of extra fermion singlets reduces the mixing angle to 1/4. We propose this sequential triplets scheme of fermions as an interesting alternative to the current scheme.     

The stereochemistry of allohimachalol

Allohimachalol, an unusual rearranged sesquiterpene from the essential oil of $\text{Cedrus}$$\text{deodara}$ Loud., is shown to have structure 3.