维生素B12与DNA相互作用的电化学研究

维生素B12与DNA相互作用的电化学研究;维生素B12; DNA; 循环伏安法; 紫外可见吸收光谱法     

膜乳化-液中干燥法制备单分散高分子微球

粒径可控的单分散高分子微球,在分析化学中可用作高效液相色谱填料^[1,2];在化学工业中可用作催化剂载体;在生物领域中用于药物释放、癌症与肝炎等临床诊断、细胞标记与识别等^[3].高分子微球的制备方法大致可分为两类,一是利用由单体出发的聚合反应或缩聚反应形成微球,二是高分子溶液经物理或物理化学手段处理后形成微球^[4]     

Thermal Fission Rate Calculated Numerically by Particles Multi-passing over Saddle Point

Langevin simulation of the particles multi-passing over the saddle point is proposed to calculate thermal fission rate. Due to finite friction and the corresponding thermal fluctuation, a backstreaming exists in the process of the particle descent from the saddle to the scission. This leads to that the diffusion behind the saddle point has influence upon the stationary flow across the saddle point. A dynamical correction factor, as a ratio of the flows of multi- and first-overpassing the saddle point, is evaluated analytically. The results show that the fission rate calculated by the particles multi-passing over the saddle point is lower than the one calculated by the particle firstly passing over the saddle point, and the former approaches the results at the scission point.     

Asymmetrical Diffusion-Induced Directional Motion

Competition between anomalous diffusion and normal diffusion along two different directions of the track for a Brownian motor, combined with a periodic potential flashing, can lead to a macroscopic motion. The current is calculated analytically by using the Astumian-Bier‘s approach of the step number per cycle. It is shown that the direction of current occurs reversal for different waiting times of the potential off and the magnitude of current is prominently enhanced. Moreover, a thermal “green“ noise is proposed to produce the ballistic diffusion, numerical simulations for the average velocity of the particle in the presence of ballistic and normal diffusions support the present theoretical findings.     

催化动力学光度法测定蒙药和发样中痕量锌(Ⅱ)

研究了在微酸性介质中,过氧化氢氧化钙试剂的褪色反应受Zn(Ⅱ)的催化而加速,据此建立了锌的新催化光度法,考察了该催化反应的适宜条件及动力学性质。该方法的检出限为0.68 μg·L-1,表观活化能为E_a=45.1 kJ·mol-1,反应速率常量为k=5.80×10-3s-1,测定范围0.80～40.00 μg·L-1,成功用于蒙药和发样中锌的测定。     

新型位置灵敏光电倍增管的性能测量

位置灵敏型光电倍增管(PS-PMT)代表了基于单个管子的原理开发新概念γ相机的技术进步.最近,日本滨松公司出品了一种新型紧凑型的PSPMT—R7600-C12.根据正电子放射断层成像系统(PET)的应用特点,我们测试了由该PS-PMT组合成的闪烁晶体阵列探测器的空间分辨率、空间线性度、增益均匀性及时间分辨率LSO与该PS-PMT的组合空间分辨率达到1.4mm,而且显示出良好的空间线性、增益均匀性及优异的时间分辨特性.     

新颖的能量函数准则下的主分量分析算法

本文通过一个新颖的能量函数把Ｏｊａ规则与准确的梯度搜索联系起来,从而证明了Ｏｊａ规则可以通过梯度搜索而获得。推导了相应的梯度算法和递归最小二乘算法,根据Ｌｙａｐｕｎｏｖ稳定性原理和随机扰动理论分析了算法的全局渐近收敛性能。最后,给出了跟踪时变ＤＯＡ的计算机模拟结果。     

Shannon采样点到Daubechies小波采样点的转换

获得了带限信号在Daubechies小波基下一个特殊预滤波算法采样点的转换误差和系统误差上界较精确的定量估计且这个算法关于尺度不再是线性收敛,而以N阶小波的消失矩收敛.     

基于器官跟踪的人脸实时跟踪方法

头肩序列图像的人脸跟踪有着广泛的应用,但目前的大多数跟踪算法难以同时满足精确与快速的要求.本文提出了一种基于器官跟踪的人脸实时跟踪算法,利用形态学运算对嘴进行跟踪,进而通过对人脸对称性的分析,实现了对头肩序列中人脸的跟踪.由于算法只涉及简单的形态学运算^[1]和局部的旋转运算,速度达到实时要求,同时人脸对称性的分析保证了跟踪结果的精确性.     

Calculating the feature method of short text based on analytic hierarchy process

In order to model the accurate interest preference of microblog users and discover user groups with similar in-terest, a new method was proposed which considered the total amount of retweets, comments and attitudes of each mi-croblog for text feature calculation with utilizing classic analytical hierarchy process method. The proposed method used three indicators to evaluate the importance of the text feature representation and made an improvement on traditional tf-idf feature calculation method to fit for short text. Furthermore, this method was also implemented in the traditional clustering algorithm. Experimental results show that, compared with the traditional tf-idf method, the improved approach has a better clustering effect on the average scattering for clusters and the total separation between clusters.