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X. Zhou Y. Guo X. Sun X. Lei X. Chen Z. Liu Y. Zhang H. Jin Y. Luo S. X. Wen G. J. Yuan G. S. Li C. X. Yang 《Zeitschrift für Physik A Hadrons and Nuclei》1995,351(1):3-4
The high spin states of119Te, populated in110Pd(13C,4n) and110Pd(12C,3n) reactions, have been studied through -ray spectroscopy. The level scheme has been established upto a spin of 55/2. Three-quasiparticle states, based on g2
7/2h11/2 and g7/2d5/2h11/2 configurations, have been identified. The 35/2 and 39/2 states are suggested to be the fully aligned states constituted by five valence h11/2
3, g7/2, d5/2 quasiparticles. 相似文献
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To evaluate the impact of zinc sulfate (ZnSO4) concentration on the structural properties of the films, Cd1-xZnxS thin films were formed on glass substrates using chemical bath deposition (CBD) in this study. The effect of ZnSO4 precursor concentration on the surface morphology, optical properties, and morphological structure of the Cd1-xZnxS films was investigated. To study the impact of zinc doping content on the performance metrics of Cu(In1-xGax)Se2 (CIGS) cells in the experimental group and to improve the buffer layer thickness, simulations were run using one-dimensional solar cell capacitance simulator (SCAPS-1D) software. 相似文献
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Shiyu Huang Yuan Chang Zhuwei Li Jiaqi Cao Yurou Song Junfeng Gao Licheng Sun Jungang Hou 《Advanced functional materials》2023,33(21):2211631
Photoredox catalysis is a green solution for organics transformation and CO2 conversion into valuable fuels, meeting the challenges of sustainable energy and environmental concerns. However, the regulation of single-atomic active sites in organic framework not only influences the photoredox performance, but also limits the understanding of the relationship for photocatalytic selective organic conversion with CO2 valorization into one reaction system. As a prototype, different single-atomic metal (M) sites (M2+ = Fe2+, Co2+, Ni2+, Cu2+, and Zn2+) in hydrogen-bonded organic frameworks (M-HOF) backbone with bridging structure of metal-nitrogen are constructed by a typical “two-in-one” strategy for superior photocatalytic C N coupling reactions integrated with CO2 valorization. Remarkably, Zn-HOF achieves 100% conversion of benzylamine oxidative coupling reactions, 91% selectivity of N-benzylidenebenzylamine and CO2 conversion in one photoredox cycle. From X-ray absorption fine structure analysis and density functional theory calculations, the superior photocatalytic performance is attributed to synergic effect of atomically dispersed metal sites and HOF host, decreasing the reaction energy barriers, enhancing CO2 adsorption and forming benzylcarbamic acid intermediate to promote the redox recycle. This work not only affords the rational design strategy of single-atom active sites in functional HOF, but also facilitates the fundamental insights upon the mechanism of versatile photoredox coupling reaction systems. 相似文献
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Clinical information about a variety of disorders is available through blood cell counting, which is usually done by manual methods. However, manual methods are complex, time-consuming and susceptible to the subjective experience of inspectors. Although many efforts have been made to develop automated blood cell counting algorithms, the complexity of blood cell distribution and the highly overlapping nature of some red blood cells (RBCs) remain significant challenges that limit the improvement of analytical accuracy. Here, we proposed an end-to-end method for blood cell counting based on deep learning. Firstly, U-Net++ was used to segment the whole blood cell image into several regions of interest (ROI), and each ROI contains only one single cell or multiple overlapping cells. Subsequently, YOLOv5 was used to detect blood cells in each ROI. Specifically, we proposed several strategies, including fine classification of RBCs, adaptive adjustment for non-maximal suppression (NMS) threshold and blood cell morphology constraints to improve the accuracy of detection. Finally, the detection outcomes for each ROI were combined and superimposed. The results show that our method can effectively address the issue of high overlap and precisely segment and detect blood cells, with a 98.18% accuracy rate for blood cell counting. 相似文献
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Qin Yang Bingqing Ge Pei Yuan Shuting Luo Hongwei Zhang Zhengyu Zhao Jiujun Zhang Shidong Wang Xiaojun Bao Xiangdong Yao 《Advanced functional materials》2023,33(25):2214588
Electrocatalytic hydrogenation (ECH) is a burgeoning strategy for the sustainable utilization of hydrogen. However, how to effectively suppress the competitive hydrogen evolution reaction (HER) is a big challenge to ECH catalysis. In this study, amine (NH2 R)-coordinated Pd nanoparticles loaded on carbon felt (Pd@CF) as a catalyst is successfully synthesized by a one-step solvothermal reduction method using oleylamine as the reducing agent. An exceptional ECH reactivity on benzaldehyde is achieved on the optimal Pd@CF catalyst in terms of a high conversion (89.7%) and selectivity toward benzyl alcohol (89.8%) at −0.4 V in 60 min. Notably, the Faradaic efficiency for producing benzyl alcohol is up to 90.2%, much higher than that catalyzed by Pd@CF-without N-group (41.1%) and thecommercial Pd/C (20.9%). The excellent ECH performance of Pd@CF can be attributed to the enriched electrons on Pd surface resulted from the introduction of NH2 R groups, which strengthens both the adsorption of benzaldehyde and the adsorbed hydrogen (Hads) on Pd, preventing the combination of Hads to form H2, that is, inhibiting the HER. This study gives a new insight into design principles of highly efficient electrocatalysts for the hydrogenation of unsaturated aldehydes molecules. 相似文献
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Yuan Deng Yihai Yang Yuanhang Xiao He-Lou Xie Ruochen Lan Lanying Zhang Huai Yang 《Advanced functional materials》2023,33(35):2301319
Switchable passive radiative cooling (PRC) smart windows can modulate sunlight transmission and spontaneously emit heat to outer space through atmospheric transparent window, presenting great potential in building energy conservation. However, realizing stable and on-demand control of the cooling efficiency for PRC materials is still challenging. Herein, an electro-controlled polymer-dispersed liquid crystal (PDLC) smart window showing PRC property is designed and prepared by adding mid-infrared emitting reactive monomers into the conventional PDLC matrix. It is found that not only the electro-optical properties but also the PRC efficiency of PRC PDLC film are tunable by regulating the content of the mid-infrared emitting components, film thickness, and micromorphology. This advanced PRC PDLC material achieves a near/sub-ambient temperature when the solar irradiance is below 400 W m−2 and can dynamically manage daytime cooling efficiency. Importantly, its PRC efficiency is capable of being tuned in an on-demand and ultrafast millisecond-scale way, whose controllable transparency enables multistage heat regulation. This study is hoped to provide new inspiration in the preparation of advanced optical devices and energy-efficient equipment. 相似文献