Kinetics of Forward Extraction of V(IV) in V(IV)‐SO42−(H+, Na+)‐Cyanex 301–Kerosene System Using the Lewis Cell Technique

Kinetics of the extraction of V(IV) from acidic sulfate medium by Cyanex 301 dissolved in kerosene has been investigated using a constant interfacial area stirred cell with laminar flow (Lewis cell). Reaction orders with respect to different concentration terms, rate constant, activation energy, entropy change in activation, and the enthalpy change in activation have been measured at a phase circulation speed of 3 Hz. The rate equation at 293 K is F (kmol/m²s) = 10^?7.02 (1 + 0.025[V(IV)]^?1)^?1 (1 + 398[H⁺])^?1 (1 + 0.10 [HA]_o^?1)^?1 (1 +  3.16 [SO₄^2?]). Based on the experimental results, the mechanism of extraction has been proposed.     

Influence of Nonequilibrium LO Phonons on High-frequency Performance of One-dimensional Hot Electrons in Quantum Wires of Polar Semiconductors

Small-signal ac transport of degenerate one-dimensional hot electrons in quantum wires of GaAs and In_0.53Ga_0.47As is studied for lattice temperatures of 77 K and 300 K. The carrier energy loss via polar optic phonons and momentum losses via polar optic phonons, acoustic phonons and ionized impurities are included in the calculations. Alloy disorder scattering in momentum loss is additionally incorporated for (In,Ga)As. The consideration of nonequilibrium optical phonons or hot phonons is found to enhance the 3dB cut-off frequency (f_3dB) considerably, where the ac mobility falls to 0.707 of its low frequency value. f_3dB is generally higher for (In,Ga)As quantum wire than for GaAs.     

On the detection of chipless RFID through signal space representation

paper presents a novel approach to model and represent chipless radio-frequency identification (RFID) frequency signatures. The approach involves the geometrical representation of chipless RFID frequency signatures in a signal space. A small set of orthonormal basis functions is derived using singular value decomposition in order to represent the 2 ^b possible tag signatures of a b-bit chipless tag. Each tag signature is represented as a point in an L-dimensional signal space, and minimum distance detection is used to extract the information bit sequence of the tag. Detection error probability is also examined through analytical derivations and Monte Carlo simulation. A set of 3-bit tags were fabricated to validate the approach. Experimental results show that the new approach is capable of accurately detecting information contained in chipless RFID tags. This approach offers a solid mathematical framework for developing novel detection methods for chipless tags.     

Fabrication and Simulation of an Indium Gallium Arsenide Quantum-Dot-Gate Field-Effect Transistor (QDG-FET) with ZnMgS as a Tunnel Gate Insulator

An indium gallium arsenide quantum-dot-gate field-effect transistor using Zn_0.95Mg_0.05S as the gate insulator is presented in this paper, showing three output states which can be used in multibit logic applications. The spatial wavefunction switching effect in this transistor has been investigated, and modeling simulations have shown supporting evidence that additional output states can be achieved in one transistor.     

Investigation of true remnant polarization response in heterostructured artificial biferroics

Epitaxial bilayered thin films composed of ferromagnetic La_0.6Sr_0.4MnO₃ and ferroelectric 0.7Pb (Mg_1/3Nb_2/3)O3–0.3(PbTiO₃) were fabricated on LaAlO₃ (100) substrates by pulsed laser ablation. Ferroelectric, ferromagnetic and magneto–dielectric characterizations performed earlier indicated the possible existence of strain-mediated magneto–electric coupling in these biferroic heterostructures. In order to investigate their true remnant polarization characteristics, usable in devices, room-temperature polarization versus electric field, positive-up negative-down (PUND) pulse polarization studies and remnant hysteresis measurements were carried out. The PUND and remnant hysteresis measurements revealed the significant contribution of the non-remnant component in the observed polarization hysteresis response of these heterostructures.     

Cyclometalated Iridium(III) Complexes with Deoxyribose Substituents

Fundamental study of enzymatic nucleoside transport suffers for lack of optical probes that can be tracked noninvasively. Nucleoside transporters are integral membrane glycoproteins that mediate the salvage of nucleosides and their passage across cell membranes. The substrate recognition site is the deoxyribose sugar, often with little distinction among nucleobases. Reported here are nucleoside analogues in which emissive, cyclometalated iridium(III) complexes are “clicked” to C‐1 of deoxyribose in place of canonical nucleobases. The resulting complexes show visible luminescence at room temperature and 77 K with microsecond‐length triplet lifetimes. A representative complex is crystallographically characterized. Transport and luminescence are demonstrated in cultured human carcinoma (KB3‐1) cells.     

Nonvolatile Memories Using Quantum Dot (QD) Floating Gates Assembled on II–VI Tunnel Insulators

This paper presents preliminary data on quantum dot gate nonvolatile memories using nearly lattice-matched ZnS/Zn_0.95Mg_0.05S/ZnS tunnel insulators. The GeO _x -cladded Ge and SiO _x -cladded Si quantum dots (QDs) are self-assembled site-specifically on the II–VI insulator grown epitaxially over the Si channel (formed between the source and drain region). The pseudomorphic II–VI stack serves both as a tunnel insulator and a high-κ dielectric. The effect of Mg incorporation in ZnMgS is also investigated. For the control gate insulator, we have used Si₃N₄ and SiO₂ layers grown by plasma- enhanced chemical vapor deposition.     

Enhanced frequency upconversion of Sm3+ ions by elliptical Au nanoparticles in dichroic Sm3+: Au-antimony glass nanocomposites

Dichroic Sm³⁺: Au-antimony glass nanocomposites are synthesized in a new reducing glass (dielectric) matrix (mol%) K₂O–B₂O₃–Sb₂O₃ (KBS) by a single-step melt-quench technique involving selective thermochemical reduction. X-ray diffraction (XRD) and selected area electron diffraction (SAED) results indicate that Au⁰ nanoparticles are grown along the (2 0 0) plane direction. The transmission electron microscopic (TEM) image reveals the elliptical Au⁰ nanoparticles having major axis range 12–17 nm. Dichroic behavior is due to elliptical shape of Au⁰ nanoparticles of aspect ratio ～1.2. Au⁰ NPs of concentration of 0.03 wt% (4.1 × 10¹⁸ atoms/cm³) drastically enhances the intensity (～7-folds) of electric dipole ⁴G_5/2 → ⁶H_9/2 red transition (636 nm) of Sm³⁺ ions and then attenuates with further increase in Au⁰ concentration. The magnetic dipole ⁴G_5/2 → ⁶H_5/2 green (566 nm) and ⁴G_5/2 → ⁶H_7/2 orange (602 nm) transitions remain almost unaffected by presence of nano Au⁰. Local field enhancement (LFE) induced by Au⁰ SPR and energy transfer (ET) from fluorescent Au⁰ → Sm³⁺ ions are found to be responsible for the enhancement while reverse ET from Sm³⁺ → Au⁰ and optical re-absorption due to Au⁰ SPR for attenuation.