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131.
M. Gogna E. Suarez P.-Y. Chan F. Al-Amoody S. Karmakar F. Jain 《Journal of Electronic Materials》2011,40(8):1769-1774
This paper presents fabrication and characterization of a quantum dot-based floating gate nonvolatile memory device with site-specific
self-assembly of germanium oxide-cladded germanium (GeO
x
-Ge) quantum dots on SiO2 and ZnS/ZnMgS/ZnS (II–VI lattice-matched high-κ dielectric) tunnel insulator material. These monodispersed and individually cladded quantum dots have the potential to store
charge uniformly in the floating gate and are well suited for nonvolatile memory applications. 相似文献
132.
Anirban Karmakar 《Supramolecular chemistry》2013,25(7):667-674
Different hydrates of the receptor, N-[2-(4-methoxy-phenyl)-ethyl]-2-(quinolin-8-yloxy)acetamide (I), and its co-crystals with acetic acid and l(+)α-hydroxy-phenylacetic acid are synthesised and their structures are studied. The acids such as acetic acid, l(+)α-hydroxy-phenylacetic acid quench fluorescence of I. The receptor I shows a fluorescence quenching on interaction with perchloric acid in benzene, whereas in methanol the solution of I results in the generation of a new fluorescence emission at higher wavelengths. The crystal structure of the perchlorate salt is determined to explain the protonation behaviour of the receptor I and the perchlorate salt in methanol leads to fluorescence emission at a place different from that of the parent compound. 相似文献
133.
Şükriye Ulubay Karabiberoğlu Ebru Mavioglu Ayan Zekerya Dursun 《Electroanalysis》2013,25(8):1933-1945
A silver nanoparticle decorated poly(thiophene) modified glassy carbon electrode (GCE) was prepared for determination of caffeic acid. The Ag/PTh/GCE surface was characterized by scanning electron microscopy (SEM) and energy‐dispersive X‐ray (EDX) spectroscopy. The modified electrode has shown higher electrocatalytic activity towards the oxidation of caffeic acid. The peak current of was found linear in the concentration range from 1.00×10?8 to 4.83×10?6 M with a detection limit of 5.3×10?9 M (S/N=3). The modified electrode was used for determination of CA concentration in red wine samples. The thermodynamic constants, entropy change (ΔS), enthalpy change (ΔH) and Gibbs free energy change (ΔG) were calculated as ?166.34 J/(mol K), ?154.24 kJ/mol and ?104.75 kJ/mol at 25 °C, respectively. 相似文献
134.
The structures and proton‐coupled behavior of adenine–thymine (A‐T) and a modified base pair containing a thymine isostere, adenine–difluorotoluene (A‐F), are studied in different solvents by dispersion‐corrected density functional theory. The stability of the canonical Watson–Crick base pair and the mismatched pair in various solvents with low and high dielectric constants is analyzed. It is demonstrated that A‐F base pairing is favored in solvents with low dielectric constant. The stabilization and conformational changes induced by protonation are also analyzed for the natural as well as the mismatched base pair. DNA sequences capable of changing their sequence conformation on protonation are used in the construction of pH‐based molecular switches. An acidic medium has a profound influence in stabilizing the isostere base pair. Such a large gain in stability on protonation leads to an interesting pH‐controlled molecular switch, which can be incorporated in a natural DNA tract. 相似文献
135.
A previously unknown class of highly substituted benzoquinoline–spirooxindole are easily prepared by a novel application of a mild and efficient catalyst SbCl3 for carbon–carbon and carbon–nitrogen bond formation reaction involving isatin, alkyne (dialkyl but-2-ynedioate) with aromatic amine (2-naphthylamine) in a one-pot three-component reaction. This protocol of one-pot synthesis afforded a library of dialkyl 2′-oxo-4H-spiro[benzo[f]quinoline-3,3′-indoline]-1,2-dicarboxylate derivatives, a potential bioactive compound in very good to excellent yields. 相似文献
136.
Ayan Chatterjee 《Annals of Physics》2011,(2):307-322
The paper deals with the extension of the Weak Isolated Horizon (WIH) formulation of black hole horizons to the non-minimally coupled scalar fields. In the early part of the paper, we introduce an appropriate Holst type action to incorporate scalar fields non-minimally coupled to gravity and construct the covariant phase space of the theory. Using this phase space, we proceed to prove the laws of black hole mechanics. Further, we show that with a gauge fixing, the symplectic structure on the horizon reduces to that of a U(1) Chern–Simons theory. The level of the Chern–Simons theory is shown to depend on the non-minimally coupled scalar field. 相似文献
137.
Das A Heo J Jankowski M Guo W Zhang L Deng H Bhattacharya P 《Physical review letters》2011,107(6):066405
We report ultralow threshold polariton lasing from a single GaN nanowire strongly coupled to a large-area dielectric microcavity. The threshold carrier density is 3 orders of magnitude lower than that of photon lasing observed in the same device, and 2 orders of magnitude lower than any existing room-temperature polariton devices. Spectral, polarization, and coherence properties of the emission were measured to confirm polariton lasing. 相似文献
138.
S. BhattacharjeeP. Karmakar A.K. SinhaA. Charkrabarti 《Applied Surface Science》2011,257(15):6775-6778
We have investigated the formation and growth of nano sized ripple topography on ZnO thin films by 10 keV O1+ bombardment at impact angles of 80° and 60°, varying the ion fluence from 5 × 1016 to 1 × 1018 ions/cm2. At 80° the ripples are oriented along the ion beam direction whereas at 60° it is perpendicular to the ion beam direction. The developed ion induced structures are characterized by atomic force microscopy (AFM) and the alignment, variation of rms roughness, wavelength and correlation length of the structures are discussed with the existing model and basic concept of ion surface interaction. 相似文献
139.
Charge‐Transfer Complex Formation in Gelation: The Role of Solvent Molecules with Different Electron‐Donating Capacities
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Shibaji Basak Sumantra Bhattacharya Dr. Ayan Datta Prof. Arindam Banerjee 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(19):5721-5726
A naphthalenediimide (NDI)‐based synthetic peptide molecule forms gels in a particular solvent mixture (chloroform/aromatic hydrocarbon, 4:1) through charge‐transfer (CT) complex formation; this is evident from the corresponding absorbance and fluorescence spectra at room temperature. Various aromatic hydrocarbon based solvents, including benzene, toluene, xylene (ortho, meta and para) and mesitylene, have been used for the formation of the CT complex. The role of different solvent molecules with varying electron‐donation capacities in the formation of CT complexes has been established through spectroscopic and computational studies. 相似文献
140.
Light Harvesting and Directional Energy Transfer in Long‐Lived Homo‐ and Heterotrimetallic Complexes of FeII,RuII, and OsII
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Dinesh Maity Chanchal Bhaumik Sourav Mardanya Srikanta Karmakar Dr. Sujoy Baitalik 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(41):13242-13252
A new family of trimetallic complexes of the form [(bpy)2M(phen‐Hbzim‐tpy)M′(tpy‐Hbzim‐phen)M(bpy)2]6+ (M=RuII, Os; M′=FeII, RuII, Os; bpy=2,2′‐bipyridine) derived from heteroditopic phenanthroline–terpyridine bridge 2‐{4‐[2,6‐di(pyridin‐2‐yl) pyridine‐4‐yl]phenyl}‐1H‐imidazole[4,5‐f][1,10]phenanthroline (phen‐Hbzim‐tpy) were prepared and fully characterized. Zn2+ was used to prepare mixed‐metal trimetallic complexes in situ by coordinating with the free tpy site of the monometallic precursors. The complexes show intense absorptions throughout the UV/Vis region and also exhibit luminescence at room temperature. The redox behavior of the compounds is characterized by several metal‐centered reversible oxidation and ligand‐centered reduction processes. Steady‐state and time‐resolved luminescence data show that the potentially luminescent RuII‐ and OsII‐based triplet metal‐to‐ligand charge‐transfer (3MLCT) excited states in the triads are quantitatively quenched, most likely by intercomponent energy transfer to the lower lying 3MLCT (for Ru and Os) or triplet metal‐centered (3MC) excited states of the FeII subunit (nonluminescent). Interestingly, iron did not adversely affect the photophysics of the respective systems. This suggests that the multicomponent molecular‐wire‐like complexes investigated here can behave as efficient light‐harvesting antennas, because all the light absorbed by the various subunits is efficiently channeled to the subunit(s) in which the lowest‐energy excited states are located. 相似文献