Synthesis and characterization of Li1.05Co1/3Ni1/3Mn1/3O1.95X0.05 (X = Cl,Br) cathode materials for lithium-ion battery

In order to improve the thermal stability and dynamic performance of LiCo_1/3Ni_1/3Mn_1/3O₂ materials, Cl-doped and Br-doped materials were synthesized via the co-precipitation method. The morphology, structure, electrochemical performance and thermal stability were characterized by environment scanning electron microscopy (ESEM), X-ray diffraction (XRD), electrochemical impedance spectroscopy (EIS), charge–discharge cycling and differential scanning calorimetry (DSC). Results show that all materials had a stable layered structure with α-NaFeO₂ and that Cl-doping slightly increased the size of grains. Both Cl-doping and Br-doping improved the high rate of discharge capacity, cycle-life performance and thermal stability, but Cl-doping was better than Br-doping in improving the material structure stability, dynamic performance and thermal stability.     

Synthesis,structures, and electrochemistry of diiron toluene-3,4-dithiolate complexes containing phosphine ligands

Transition Metal Chemistry - In this paper, four diiron toluene-3,4-dithiolate complexes with phosphine ligands were synthesized and characterized. Treatment of complex...     

Synthesis,characterization, and electrochemistry of monophosphine‐containing diiron propane‐1,2‐dithiolate complexes related to the active site of [FeFe]‐hydrogenases

Five monophosphine‐substituted diiron propane‐1,2‐dithiolate complexes as the active site models of [FeFe]‐hydrogenases have been synthesized and characterized. Reactions of complex [Fe₂(CO)₆{μ‐SCH₂CH(CH₃)S}] ( 1 ) with a monophosphine ligand tris(4‐methylphenyl)phosphine, diphenyl‐2‐pyridylphosphine, tris(4‐chlorophenyl)phosphine, triphenylphosphine, or tris(4‐fluorophenyl)phosphine in the presence of the oxidative agent Me₃NO·2H₂O gave the monophosphine‐substituted diiron complexes [Fe₂(CO)₅(L){μ‐SCH₂CH(CH₃)S}] [L = P(4‐C₆H₄CH₃)₃, 2 ; Ph₂P(2‐C₅H₄N), 3 ; P(4‐C₆H₄Cl)₃, 4 ; PPh₃, 5 ; P(4‐C₆H₄F)₃, 6 ] in 81%–94% yields. Complexes 2 – 6 have been characterized by elemental analysis, spectroscopy, and X‐ray crystallography. In addition, electrochemical studies revealed that these complexes can catalyze the reduction of protons to H₂ in the presence of HOAc.     

Alkylation of Allyl/Alkenyl Sulfones by Deoxygenation of Alkoxyl Radicals

A challenging deoxygenation of alkoxyl radicals from readily accessible alcohol derivatives was developed, affording facile synthesis of functionalized alkenes with good functional group tolerance under mild reaction conditions. Because alkoxyl radicals can easily undergo β-fragmentations or hydrogen abstractions, this new strategy for deoxygenation of alkoxyl radicals is highly valuable. Moreover, mechanistic studies revealed that the electron-neutral phosphine acts as the deoxygenation reagent.     

Numerical analysis of a second order algorithm for simplified magnetohydrodynamic flows

In this paper, we construct a second order algorithm based on the spectral deferred correction method for the time-dependent magnetohydrodynamics flows at a low magnetic Reynolds number. We present a complete theoretical analysis to prove that this algorithm is unconditionally stable, consistent and second order accuracy. Finally, two numerical examples are given to illustrate the convergence and effectiveness of our algorithm.     

GMSK混合信号的PSP盲分离算法

针对GMSK混合信号的单通道盲分离问题进行了研究。由于不能直接采用逐幸存路径处理(PSP)算法对GMSK混合信号进行分离,考虑对GMSK信号作线性近似处理,使得GMSK混合信号适用于PSP算法。该算法通过在符号序列和信道参数组成的联合空间进行最大似然估计,保留最优路径,输出符号对,从而获得分离信号。仿真结果表明,使用PSP算法对GMSK混合信号进行分离的误码率性能略优于粒子滤波算法误码率性能,但复杂度远低于粒子滤波算法。     

红外焦平面探测器中间层杨氏模量提取研究

为系统研究热冲击下InSb焦平面探测器的形变规律,需借助多层材料形变分析方程组求得其形变解析解。本文在分析、模拟双组份弹性材料均匀混合后其等效杨氏模量随体积分数变化趋势的基础上,借助有限元软件ANSYS对InSb焦平面探测器中间层等效杨氏模量的提取进行系统研究。分析结果表明,直接采用线弹性材料模型模拟的结果与真实材料的等效杨氏模量相去甚远,需用黏塑性模型方能给出符合实际的中间层等效杨氏模量;在InSb焦平面探测器典型结构设计中,中间层的等效杨氏模量随体积分数的演化规律可用线性方程描述,这为后续探测器结构优化提供了理论分析模型支撑。     

基于SSTDR的线缆故障检测算法

针对目前线缆故障检测方法对定位结果准确性和可行性的影响,文中利用Matlab的Simulink仿真平台建立线缆故障模型,结合线缆特性建立系统模型,对扩散频谱时域反射方法进行了研究,采用直接序列扩频信号作为测试信号在线缆上传输,进行检测分析,并根据传输时间差等参数判断故障距离。对测试信号的不同调制方法进行仿真分析后,验证了该方法在线缆故障定位中的可行性,以及线缆故障测量中以BPSK和QPSK效果最佳。