全文获取类型
收费全文 | 581篇 |
免费 | 8篇 |
国内免费 | 12篇 |
专业分类
化学 | 335篇 |
晶体学 | 1篇 |
力学 | 32篇 |
综合类 | 11篇 |
数学 | 42篇 |
物理学 | 88篇 |
无线电 | 92篇 |
出版年
2023年 | 5篇 |
2022年 | 20篇 |
2021年 | 29篇 |
2020年 | 18篇 |
2019年 | 25篇 |
2018年 | 19篇 |
2017年 | 12篇 |
2016年 | 25篇 |
2015年 | 15篇 |
2014年 | 19篇 |
2013年 | 50篇 |
2012年 | 43篇 |
2011年 | 34篇 |
2010年 | 20篇 |
2009年 | 20篇 |
2008年 | 24篇 |
2007年 | 34篇 |
2006年 | 21篇 |
2005年 | 24篇 |
2004年 | 8篇 |
2003年 | 20篇 |
2002年 | 32篇 |
2001年 | 7篇 |
2000年 | 4篇 |
1999年 | 9篇 |
1998年 | 7篇 |
1997年 | 5篇 |
1995年 | 7篇 |
1994年 | 4篇 |
1993年 | 8篇 |
1992年 | 1篇 |
1991年 | 5篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1979年 | 3篇 |
1977年 | 2篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1970年 | 2篇 |
1968年 | 2篇 |
1961年 | 1篇 |
1960年 | 1篇 |
1959年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有601条查询结果,搜索用时 31 毫秒
451.
Anwar Usman Ibrahim Abdul Razak Hoong‐Kun Fun Suchada Chantrapromma Yan Zhang Jian‐Hua Xu 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(4):o239-o241
The crystal of the title compound, C20H17NO4, which was used for collecting intensity data was twinned. Each of the two crystallographically independent molecules in the asymmetric unit has a planar indole moiety perpendicular to a planar oxopropyl moiety. The distribution of the bonds at the central C atom joining the oxopropyl, phenyl and indole substituents is also planar. The packing is stabilized by intermolecular C—H?O interactions, as well as by dipole–dipole and van der Waals interactions. 相似文献
452.
Phenols were converted to their magnesium salts with the MgCl2-Et3N base system and subsequently reacted with Eschenmoser's salt, affording N,N-dimethyl substituted benzylamines in high to excellent yields. A series of mono N-substituted benzylamines were prepared in one-pot syntheses by ortho-formylation of phenols to corresponding salicylaldehydes, which in turn reacted with amines to imines. The imines were subsequently reduced to mono N-substituted benzylamines. Some of these benzylamines were further converted, without work-up, to mono N-substituted dihydro-2H-1,3-benzoxazines. 相似文献
453.
Abdel-Khalek Ahmed A. Ewais Hassan A. Khaled Eman S.H. Abdel-Hamied Anwar 《Transition Metal Chemistry》2003,28(6):635-639
The kinetics of oxidation of [CoIINS(H2O)2]3– by N-bromosuccinimide (NBS) in aqueous solution has been studied spectrophotometrically in the 20–40 °C range. The reaction is first order each in [NBS] and [CoIINS(H2O)2]3–, and the rate of reaction increases with increasing pH between 6.64 and 7.73. The thermodynamic activation parameters have been calculated. The experimental rate law is consistent with a mechanism in which the deprotonated [CoIINS(H2O)(OH)]4– is considered to be the most reactive species compared to its conjugate acid. It is assumed that electron transfer takes place via an inner-sphere mechanism. 相似文献
454.
455.
Bimal B. Chakraborty Siddique Anwar Saurav Das Satya B. Paul Golam Mohiuddin Joydip De 《Liquid crystals》2018,45(11):1644-1653
In this work, hydrogen-bonded liquid crystal exhibiting phase dependent fluorescence has been reported. The H-bonded materials were prepared using pyridenyl benzothiazole and alkoxy benzoic acid as H-bond acceptor and donor respectively. The formation of the target materials was confirmed via different spectroscopic technique and their mesogenic behaviour has been studied through polarising optical microscope, differential scanning calorimetry and 2D-X-ray diffraction. The H-bonded mesogenic material showed aggregation dependent fluorescence switching when subjected to transformation from isotropic-nematic-crystalline phase sequence. Computational studies were performed to probe into fluorescence switching behaviour of the mesogenic material. 相似文献
456.
457.
Natasha Anwar Abbas Khan Mohib Shah Saad Anwar 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2018,92(1):124-131
This study deals with the synthesis and physicochemical investigation of silver nanoparticles using an aqueous extract of Monotheca buxifolia (Flac.). On the treatment of aqueous solution of silver nitrate with the plant extract, silver nanoparticles were rapidly fabricated. The synthesized particles were characterized by using UV–visible spectrophotometry (UV), Fourier transform infrared spectroscopy (FTIR), Energy dispersive X-ray (EDX) and Scanning electron microscopy (SEM). The formation of AgNPs was confirmed by noting the change in colour through visual observations as well as via UV–Vis spectroscopy. UV–Vis spectrum of the aqueous medium containing silver nanoparticles showed an absorption peak at around 440 nm. FTIR was used to identify the chemical composition of silver nanoparticles and Ag-capped plant extract. The presence of elemental silver was also confirmed through EDX analysis. The SEM analysis of the silver nanoparticles showed that they have a uniform spherical shape with an average size in the range of 40–78 nm. This green system showed better capping and stabilizing agent for the fine particles. Further, in vitro the antioxidant activity of Monotheca buxifolia (Flac.) and Ag-capped with the plant was also evaluated using FeCl3/K3Fe (CN)6 essay. 相似文献
458.
Heyne K Mohammed OF Usman A Dreyer J Nibbering ET Cusanovich MA 《Journal of the American Chemical Society》2005,127(51):18100-18106
We have studied the structural changes induced by optical excitation of the chromophore in wild-type photoactive yellow protein (PYP) in liquid solution with a combined approach of polarization-sensitive ultrafast infrared spectroscopy and density functional theory calculations. We identify the nuC8-C9 marker modes for solution phase PYP in the P and I0 states, from which we derive that the first intermediate state I0 that appears with a 3 ps time constant can be characterized to have a cis geometry. This is the first unequivocal demonstration that the formation of I0 correlates with the conversion from the trans to the cis state. For the P and I0 states we compare the experimentally measured vibrational band patterns and anisotropies with calculations and find that for both trans and cis configurations the planarity of the chromophore has a strong influence. The C7=C8-(C9=O)-S moiety of the chromophore in the dark P state has a trans geometry with the C=O group slightly tilted out-of-plane, in accordance with the earlier reported structure obtained in an X-ray diffraction study of PYP crystals. In the case of I0, experiment and theory are only in agreement when the C7=C8-(C9=O)-S moiety has a planar configuration. We find that the carboxylic side group of Glu46 that is hydrogen-bonded to the chromophore phenolate oxygen does not alter its orientation on going from the electronic ground P state, via the electronic excited P state to the intermediate I0 state, providing conclusive experimental evidence that the primary stages of PYP photoisomerization involve flipping of the enone thioester linkage without significant relocation of the phenolate moiety. 相似文献
459.
Promethazine-HCl reacts with potassium persulphate to give a pinkish red color complex exhibiting maximum absorbance at 515 nm. The reaction is selective for promethazine-HCl, with 1 μg/mL as visual limit of identification and provides a basis for a new spectrophotometric determination method. The color forming reaction obeys Beer's Law from 0.001 to 0.125 mg/mL of promethazine-HCl. The relative standard deviation does not exceed 0.005 mg/mL. The method is successfully applied to pure and pharmaceutical formulations of promethazine-HCl. The quantitative assessment of tolerable amounts of possible interferants was also studied. The results are reproducible within ±1% and in good agreement with those obtained by the standard procedure. 相似文献
460.
The viscosities, η, and refractive indices, n, of pure dimethylsulphoxide (DMSO), benzene, toluene, o‐xylene, m‐xylene, p‐xylene and mesitylene, and those of their 54 binary mixtures, with DMSO as common component, covering the whole composition range have been measured at 298.15, 303.15, 308.15, 313.15, and 318.15 K. From the experimental data, the deviations in viscosity, Δη and deviations in molar refraction, ΔRm have been calculated. The variation of these parameters with composition and temperature of the mixtures have been discussed in terms of molecular interaction in these mixtures. The effect of the number and position of the methyl groups in these aromatic hydrocarbons on molecular interactions in these mixtures has also been discussed. The free energies, ΔG*, enthalpies, ΔH* and entropies, ΔS* of activation of viscous flow have also been obtained by using Eyring viscosity equation. The ΔH* values were found independent of temperature. The dependence of these thermodynamic parameters on composition of the mixtures has been discussed. Further, the viscosities and refractive indices of these binary mixtures were calculated theoretically from pure component data by using various empirical and semi‐empirical relations and the results were compared with the experimental findings. 相似文献