The magnesium ramsey interferometer: Applications and prospects

In this paper it will be shown that an atom interferometer, based on the coherent splitting of the atomic wavefunction by four travelling waves (Ramsey interferometer), may be explained by a purely mechanical interpretation. As our first application of this Ramsey interferometer we have measured the phase shifts respectively optical length changes in a magnesium atomic beam caused by the acceleration of the partial atomic wave in one arm of the interferometer. This acceleration was achieved by the dipole force exerted by an off-resonant crossing laser beam which interacted with the ground state part of the wavefunction only. Further applications of this interferometer and improvements due to laser cooling will be discussed.     

Human neuronal stargazin-like proteins, γ2, γ3 and γ4; an investigation of their specific localization in human brain and their influence on CaV2.1 voltage-dependent calcium channels expressed in Xenopus oocytes.

Background  

Stargazin (γ₂) and the closely related γ₃, and γ₄ transmembrane proteins are part of a family of proteins that may act as both neuronal voltage-dependent calcium channel (VDCC) γ subunits and transmembrane α-amino-3-hydroxy-5-methyl-4-isoxazoleproponinc (AMPA) receptor regulatory proteins (TARPs). In this investigation, we examined the distribution patterns of the stargazin-like proteins γ₂, γ₃, and γ₄ in the human central nervous system (CNS). In addition, we investigated whether human γ₂ or γ₄ could modulate the electrophysiological properties of a neuronal VDCC complex transiently expressed in Xenopus oocytes.     

On toric h-vectors of centrally symmetric polytopes

We prove tight lower bounds for the coefficients of the toric h-vector of an arbitrary centrally symmetric polytope generalizing previous results due to R. Stanley and the author using toric varieties. Our proof here is based on the theory of combinatorial intersection cohomology for normal fans of polytopes developed by G. Barthel, J.-P. Brasselet, K. Fieseler and L. Kaup, and independently by P. Bressler and V. Lunts. This theory is also valid for nonrational polytopes when there is no standard correspondence with toric varieties. In this way we can establish our bounds for centrally symmetric polytopes even without requiring them to be rational. Received: 24 March 2004     

Direct Imaging of Octahedral Distortion in a Complex Molybdenum Vanadium Mixed Oxide

Complex Mo,V‐based mixed oxides that crystallize in the orthorhombic M1‐type structure are promising candidates for the selective oxidation of small alkanes. The oxygen sublattice of such a complex oxide has been studied by annular bright field scanning transmission electron microscopy. The recorded micrographs directly display the local distortion in the metal oxygen octahedra. From the degree of distortion we are able to draw conclusions on the distribution of oxidation states in the cation columns at different sites. The results are supported by X‐ray diffraction and electron paramagnetic resonance measurements that provide integral details about the crystal structure and spin coupling, respectively.     

Optimization of extraction procedure and chromatographic separation of glyphosate, glufosinate and aminomethylphosphonic acid in soil

Analysing herbicides in soil is a complex issue that needs validation and optimization of existing methods. An extraction and analysis method was developed to assess concentrations of glyphosate, glufosinate and aminomethylphophonic acid (AMPA) in field soil samples. After testing extractions by accelerated solvent extraction and ultrasonic extraction, agitation was selected with the best recoveries. Water was preferred as solvent extraction because it resulted in a cleaner chromatogram with fewer impurities than was the case with alkaline solvents. Analysis was performed by FMOC pre-column derivatization followed by high-performance liquid chromatography (HPLC) on a 300 mm C(18) column which permitted enhanced separation and sensitivity than a 250 mm C(18) column and increased resistance than the NH(2) column for soil samples. This extraction and analysis method allowing a minimum of steps before the injection in the HPLC with fluorescence detection is efficient and sensitive for a clay-loamy soil with detection limits of 103 μg kg(-1) for glyphosate, 15 μg kg(-1) for glufosinate and 16 μg kg(-1) for AMPA in soil samples.