Aurophilic interactions as a subject of current research: an up-date

Recently accumulated experimental evidence for aurophilic interactions in and between molecular gold(I) compounds and the results of pertinent theoretical calculations are reviewed for the period from 2007 to mid-2011. The influence of the intra- and intermolecular bonding contacts between the closed-shell metal centres, Au-Au, on the molecular and crystal structures, and the consequences of these effects for the chemical and physical properties of gold compounds are summarized for the various classes of mono- and polynuclear systems. The literature survey builds on the contents of previous reviews and relates new experimental and theoretical findings to earlier observations (353 references).     

Proton and calcium-gated ionic mesochannels: phosphate-bearing polymer brushes hosted in mesoporous thin films as biomimetic interfacial architectures

Rational construction of interfaces based on multicomponent responsive systems in which molecular transport is mediated by structures of nanoscale dimensions has become a very fertile research area in biomimetic supramolecular chemistry. Herein, we describe the creation of hybrid mesostructured interfaces with reversible gate-like transport properties that can be controlled by chemical inputs, such as protons or calcium ions. This was accomplished by taking advantage of the surface-initiated polymerization of 2-(methacryloyloxy)ethyl phosphate (MEP) monomer units into and onto mesoporous silica thin films. In this way, phosphate-bearing polymer brushes were used as "gatekeepers" located not only on the outer surface of mesoporous thin films but also in the inner environment of the porous scaffold. Pore-confined PMEP brushes respond to the external triggering chemical signals not only by altering their physicochemical properties but also by switching the transport properties of the mesoporous film. The ion-gate response/operation was based on the protonation and/or chelation of phosphate monomer units in which the polymer brush works as an off-on switch in response to the presence of protons or Ca(2+) ions. The hybrid meso-architectured interface and their functional features were studied by a combination of experimental techniques including ellipso-porosimetry, cyclic voltammetry, X-ray reflectivity, grazing incidence small-angle X-ray scattering, X-ray photoelectron spectroscopy, and in situ atomic force microscopy. In this context, we believe that the integration of stimuli-responsive polymer brushes into nanoscopic supramolecular architectures would provide new routes toward multifunctional biomimetic nanosystems displaying transport properties similar to those encountered in biological ligand-gated ion channels.     

Organogelators and Polymer Crystallisation

The specific impact of low molecular weight organic gels on polymer crystallisation is examined. Conventional nucleating agents (NA) influence the polyolefins crystallisation and improve their mechanical properties, via an epitaxial mechanism. In the particular case where the pair NA/polymer form a gel at intermediate temperatures on cooling, optical properties (clarity) are significantly improved. This improvement is linked with the ability of organic gels to develop 3-D fibrillar network. The fibres morphology offers a large specific area, thus produces a high density of nuclei, homogeneously dispersed. Gelling organic molecules are certainly a promising route towards the design of efficient additives in polymer processing.     

Household energy use patterns and social organisation for optimal energy management in a multi‐user solar energy system

Multi‐user systems (MUS) for electrification of rural villages have specific advantages compared with individual systems (SHS). However, as MUS serve multiple consumers, shared energy use presents a challenging problem to the communities. Despite the increased performance of MUS over SHS, they still produce a limited amount of available energy, and users cannot consume as much electricity as they wish without considering the needs of the other users. This means that energy distribution among village residents has to be organised and energy consumption has to be controlled. There are different ways to achieve energy distribution. One possibility is to leave it to the users themselves to organise rational energy use according to their needs and daily routines. For the development of a self‐managed scheme, knowledge is required not only of the users' total energy consumption, but also of their individual energy use patterns. With knowledge of the community's energy consumption habits, rules for adequate energy use can be developed more accurately. The present study describes community energy management in a Cuban village using a central photovoltaic installation. Applying different methods, data were collected in order to identify individual energy use patterns and to investigate how villagers distribute energy and what rules of use are in effect. We wanted to find out whether their energy management leads to well‐adapted energy use patterns and reasonable system performance. The results show that the village residents have developed rules and agreements for coordination of their energy use that have led to good adaptation to the dynamics of energy production. Copyright © 2006 John Wiley & Sons, Ltd.