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31.
Aftab Aslam Parwaz Khan Anish Khan Abdullah M Asiri Heba A Kashmery 《Russian Journal of Physical Chemistry B, Focus on Physics》2018,12(3):412-421
The oxidation of Rizatriptan by diperiodatoargentate(III) has been studied by spectrophotometry at neutral pH. The kinetics of the reaction of Rizatriptan has been shown to principle of non-complementary oxidation steps. The initial step involves the deprotonated of the diperiodatoargentate(III) with the alkali; this rearranges during the displacement of a ligand to give free periodate and takes up another ligand monoperiodateargentate(III), combines with a substrate to endow with an intermediate complex which decomposes within a slow step to provide the final product in the following step with a first-order rate constant. The main product was identified by spot test, Fourier- transform infrared spectroscopy, Nuclear magnetic resonance and Liquid chromatography-mass spectrometry spectrum. A conceivable mechanism including pre equilibrium of adducts development between the complex and reductant was planned from the kinetics study. The rate conditions got from system can clarify all exploratory phenomena, and the activation parameters alongside rate constants of the rate determining step were ascertained. 相似文献
32.
Joint spectrum sensing and resource allocation optimization using genetic algorithm for frequency hopping–based cognitive radio networks 下载免费PDF全文
Sang‐Jo Yoo Anish Prasad Shrestha Myunghwan Seo Chul‐Hee Han Minho Park Kwang‐Eog Lee 《International Journal of Communication Systems》2018,31(13)
In cognitive radio (CR) networks, secondary users should effectively use unused licensed spectrums, unless they cause any harmful interference to the primary users. Therefore, spectrum sensing and channel resource allocation are the 2 main functionalities of CR networks, which play important roles in the performance of a CR system. To maximize the CR system utility, we propose a joint out‐of‐band spectrum sensing and operating channel allocation scheme based on genetic algorithm for frequency hopping–based CR networks. In this paper, to effectively sense the primary signal on hopping channels at each hopping slot time, a set of member nodes sense the next hopping channel, which is called out‐of‐band sensing. To achieve collision‐free cooperative sensing reporting, the next channel detection notification mechanism is presented. Using genetic algorithm, the optimum sensing and data transmission schedules are derived. It selects a sensing node set that participate the spectrum sensing for the next expected hopping channel during the current channel hopping time and another set of nodes that take opportunity for transmitting data on the current hopping channel. The optimum channel allocation is performed in accordance with each node's individual traffic demand. Simulation results show that the proposed scheme can achieve reliable spectrum sensing and efficient channel allocation. 相似文献
33.
Hybrid Paper–Plastic Microchip for Flexible and High‐Performance Point‐of‐Care Diagnostics 下载免费PDF全文
Mohamed Shehata Draz Maryam Moazeni Manasa Venkataramani Harini Lakshminarayanan Ecem Saygili Nivethitha Kota Lakshminaraasimulu Kamyar Mehrabi Kochehbyoki Manoj Kumar Kanakasabapathy Shirin Shabahang Anish Vasan Mohamad Ali Bijarchi Adnan Memic Hadi Shafiee 《Advanced functional materials》2018,28(26)
A low‐cost and easy‐to‐fabricate microchip remains a key challenge for the development of true point‐of‐care (POC) diagnostics. Cellulose paper and plastic are thin, light, flexible, and abundant raw materials, which make them excellent substrates for mass production of POC devices. Herein, a hybrid paper–plastic microchip (PPMC) is developed, which can be used for both single and multiplexed detection of different targets, providing flexibility in the design and fabrication of the microchip. The developed PPMC with printed electronics is evaluated for sensitive and reliable detection of a broad range of targets, such as liver and colon cancer protein biomarkers, intact Zika virus, and human papillomavirus nucleic acid amplicons. The presented approach allows a highly specific detection of the tested targets with detection limits as low as 102 ng mL?1 for protein biomarkers, 103 particle per milliliter for virus particles, and 102 copies per microliter for a target nucleic acid. This approach can potentially be considered for the development of inexpensive and stable POC microchip diagnostics and is suitable for the detection of a wide range of microbial infections and cancer biomarkers. 相似文献
34.
Taewoo Kwon Author VitaeEmre Ertin Author Vitae Anish AroraAuthor Vitae 《Ad hoc Networks》2012,10(4):696-708
Full scale experimentation with wireless networks in deployment environments is difficult. Therefore a common validation technique is to test a prototype network in a convenient environment prior to deployment. In this paper, we consider the problem of obtaining comparable protocol performance when the test and deployment environments differ in RF propagation environment and/or inter-node spacing. To achieve comparable protocol behavior in the two settings, we propose the concept of “link usage spectrum”. Based on the hypothesis that the link usage spectrum is a gross predictor for network performance, we show how to replicate in the test setting the link usage spectrum of the protocol that is expected in the deployment setting. We show our technique for achieving comparable protocol behavior via experiments and simulations in multiple indoor and outdoor propagation environments. The link usage spectrum is protocol specific; we illustrate for a family of protocols how the link usage spectrum is calculated analytically, from the protocol metric for choosing forwarding links in the network, and how power scaling can be used to match the link usage spectrum across networks. 相似文献
35.
When a sensor network is deployed to detect objects penetrating a protected region, it is not necessary to have every point
in the deployment region covered by a sensor. It is enough if the penetrating objects are detected at some point in their
trajectory. If a sensor network guarantees that every penetrating object will be detected by at least k distinct sensors before it crosses the barrier of wireless sensors, we say the network provides k-barrier coverage. In this paper, we develop theoretical foundations for k-barrier coverage. We propose efficient algorithms using which one can quickly determine, after deploying the sensors, whether
the deployment region is k-barrier covered. Next, we establish the optimal deployment pattern to achieve k-barrier coverage when deploying sensors deterministically. Finally, we consider barrier coverage with high probability when
sensors are deployed randomly. The major challenge, when dealing with probabilistic barrier coverage, is to derive critical
conditions using which one can compute the minimum number of sensors needed to ensure barrier coverage with high probability.
Deriving critical conditions for k-barrier coverage is, however, still an open problem. We derive critical conditions for a weaker notion of barrier coverage,
called weak k-barrier coverage. 相似文献
36.
It is demonstrated how the energy-dependent Green’s function for the Schrödinger-Coulomb problem can be deduced from a knowledge of the harmonic oscillator time-propagator. All the known results of the Coulomb system are shown to be elegantly derivable from such a connection. 相似文献
37.
Dr. Sebastian Götze Dr. Nahid Azzouz Dr. Yu‐Hsuan Tsai Prof. Dr. Uwe Groß Anika Reinhardt Dr. Chakkumkal Anish Prof. Dr. Peter H. Seeberger Dr. Daniel Varón Silva 《Angewandte Chemie (International ed. in English)》2014,53(50):13701-13705
Around 2 billion people worldwide are infected with the apicomplexan parasite Toxoplasma gondii which induces a variety of medical conditions. For example, primary infection during pregnancy can result in fetal death or mental retardation of the child. Diagnosis of acute infections in pregnant women is challenging but crucially important as the drugs used to treat T. gondii infections are potentially harmful to the unborn child. Better, faster, more reliable, and cheaper means of diagnosis by using defined antigens for accurate serological tests are highly desirable. Synthetic pathogen‐specific glycosylphosphatidylinositol (GPI) glycan antigens are diagnostic markers and have been used to distinguish between toxoplasmosis disease states using human sera. 相似文献
38.
Aftab Aslam Parwaz Khan Anish Khan Abdullah M. Asiri Naved Azum Malik Abdul Rub Sher Bahadar Khan Mohammed M. Rahman Abdulrahman O. Al-Youbi 《Research on Chemical Intermediates》2014,40(4):1703-1714
The mechanism of dismutation of MnO4 2? via the complex [MTZ–MnO4·OH]2?, formed during the oxidation of metronidazole (MTZ), has been investigated spectrophotometrically at different temperatures. The stoichiometry of the reaction is 1:1, i.e. 1 mol MTZ reacts with 1 mol Mn(VII).The reaction is first order in permanganate, less than first order in [MTZ] and [alkali]. The effects of added products and the dielectric constant and ionic strength of the reaction medium were investigated. The main products were identified by spot test and FT-IR. A mechanism involving a free radical has been proposed. In the equilibrium step MTZ binds to the MnO4 ? species to form a complex (C). Investigation of the reaction at different temperatures enabled determination of the activation data for the slow step of proposed mechanism. The proposed mechanism and the derived rate laws are consistent with the observed kinetics. 相似文献
39.
40.
An organic-inorganic composite, poly-o-anisidine Sn(IV) phosphate, was chemically synthesized by mixing ortho-anisidine into
gels of Sn(IV) phosphate with different mixing volume ratios. Studies on the effect of eluant concentration, elution behavior
and separation of metal ions were carried out to understand the ion-exchange capabilities. Due to Cd(II) selective nature
of composite, revealed by distribution studies, Cd(II) ion selective membrane electrode was fabricated. The analytical utility
of the electrode was established by employing it as an indicator electrode in electrometric titrations having fast response
time, 3–5s, and long life span of six months. Some physical parameters like self-diffusion coefficient (D0), activation energy (Ea) and entropy of activation (ΔS0) have been evaluated under conditions favoring a particle diffusion-controlled mechanism by studying ion-exchange kinetics.
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