全文获取类型
收费全文 | 267篇 |
免费 | 11篇 |
国内免费 | 2篇 |
专业分类
化学 | 111篇 |
晶体学 | 2篇 |
力学 | 7篇 |
数学 | 17篇 |
物理学 | 83篇 |
无线电 | 60篇 |
出版年
2024年 | 1篇 |
2023年 | 1篇 |
2022年 | 6篇 |
2021年 | 5篇 |
2020年 | 7篇 |
2019年 | 6篇 |
2018年 | 7篇 |
2017年 | 3篇 |
2016年 | 12篇 |
2015年 | 3篇 |
2014年 | 10篇 |
2013年 | 33篇 |
2012年 | 7篇 |
2011年 | 15篇 |
2010年 | 7篇 |
2009年 | 8篇 |
2008年 | 21篇 |
2007年 | 16篇 |
2006年 | 7篇 |
2005年 | 17篇 |
2004年 | 9篇 |
2003年 | 6篇 |
2002年 | 6篇 |
2001年 | 5篇 |
2000年 | 9篇 |
1999年 | 4篇 |
1998年 | 5篇 |
1997年 | 11篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1992年 | 4篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1970年 | 1篇 |
1968年 | 1篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1945年 | 1篇 |
排序方式: 共有280条查询结果,搜索用时 15 毫秒
171.
Let $X^{k}_{m,n}=\Sigma^{k} (\mathbb{R}\mathbb{P}^{m}/\mathbb{R}\mathbb{P}^{n})$ . In this note we completely determine the values of k, m, n for which the total Stiefel–Whitney class w(ξ)=1 for any vector bundle ξ over $X^{k}_{m,n}$ . 相似文献
172.
173.
Joel L. Plawsky Sashidhar S. Panchamgam Shripad J. Gokhale Peter C. Wayner Jr. Sunando DasGupta 《Superlattices and Microstructures》2004,35(3-6):559
A vertical constrained vapor bubble, VCVB, made of fused silica was used to study the stability and oscillations of an evaporating wetting film of HFE- 7000® in a corner. The film thickness profile was measured as a function of time and axial position using an advanced form of image analyzing interferometry. The curvature, apparent contact angle, and pressure profiles for the evaporating film were calculated from the measured film thickness profiles. Oscillation of the liquid film was observed and profiles for both the advancing and receding films were obtained. These are the first such detailed profiles obtained for an oscillating meniscus below a thickness of 0.1 μm.The film thickness profiles demonstrated the spreading of the meniscus during advance as well as the presence of a curvature gradient near the contact line region. The maximum curvature decreased for the advancing menisci and increased with time for the receding menisci. An increase in the adsorbed film thickness was associated with the advancing stage and a decrease with the receding stage. Pressure profiles were measured as a function of position indicating the potential for driving the flow of the fluid toward or away from the contact line. As the film advances or recedes, the pressure gradients change as a function of position fueling the next oscillation cycle. 相似文献
174.
Andrew M. Crawford Patrick Kurecka Tsz Kwan Yim Claire Kozemchak Aniruddha Deb Lubomír Dostál Cheng-Jun Sun Dale L. Brewe Raul Barrea James E. Penner-Hahn 《Journal of synchrotron radiation》2016,23(4):901-908
An X‐ray fluorescence flow cytometer that can determine the total metal content of single cells has been developed. Capillary action or pressure was used to load cells into hydrophilic or hydrophobic capillaries, respectively. Once loaded, the cells were transported at a fixed vertical velocity past a focused X‐ray beam. X‐ray fluorescence was then used to determine the mass of metal in each cell. By making single‐cell measurements, the population heterogeneity for metals in the µM to mM concentration range on fL sample volumes can be directly measured, a measurement that is difficult using most analytical methods. This approach has been used to determine the metal composition of 936 individual bovine red blood cells (bRBC), 31 individual 3T3 mouse fibroblasts (NIH3T3) and 18 Saccharomyces cerevisiae (yeast) cells with an average measurement frequency of ~4 cells min?1. These data show evidence for surprisingly broad metal distributions. Details of the device design, data analysis and opportunities for further sensitivity improvement are described. 相似文献
175.
MacCormack's explicit time-marching scheme is used to solve the full Navier–Stokes unsteady, compressible equations for internal flows. The requirement of a very fine grid to capture shock as well as separated flows is circumvented by employing grid clustering. The numerical scheme is applied for axisymmetric as well as two-dimensional flows. Numerical predictions are compared with experimental data and the qualitative as well as the quantitative agreement is found to be quite satisfactory. © 1997 John Wiley & Sons, Ltd. 相似文献
176.
Puja Das Karmakar Venkata Sundeep Seesala Aniruddha Pal Santanu Dhara Soumit Chatterjee Sagar Pal 《Journal of polymer science. Part A, Polymer chemistry》2018,56(20):2354-2363
A novel, pH-responsive supramolecular graft copolymeric micelle, composed of dextran and poly (oleic acid), has been synthesized through reversible addition fragmentation chain transfer polymerization with controlled Mn and narrow polydispersity. The structural properties of the copolymer have been studied using FTIR and 1H NMR spectral analyses. Critical micelle concentration (CMC) has been determined fluorometrically and conductometrically. The copolymer shows pH responsive micellar stability, which has been confirmed using DLS study. Dextran-g-OA copolymer demonstrates spherical morphology at CMC, while rod-like assembly has been evidenced beyond CMC that is probably because of the structural alteration of copolymeric chains at higher copolymer concentration. Dextran-g-OA is noncytotoxic toward MG-63 cells. As the self-assemble nature of copolymer micelle promotes the oral administration of hydrophobic drugs, nifedipine (NFD, a hydrophobic drug) has been used as model drug that has been encapsulated substantially into the core of the micelle. The copolymer releases the loaded NFD at a much slower rate in simulated gastric fluid (pH 1.2) and relatively faster in simulated intestinal fluid (pH 7.4) with a cumulative release of ~95% within 24 h, suggesting an ideal candidate as nifedipine carrier. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 2354–2363 相似文献
177.
Copper‐Catalyzed Regioselective Cascade Alkylation and Cyclocondensation of Quinoline N‐Oxides with Diazo Esters: Direct Access to Conjugated π‐Systems 下载免费PDF全文
Aniruddha Biswas Ujjwal Karmakar Arun Pal Dr. Rajarshi Samanta 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(39):13826-13830
An inexpensive copper‐catalyzed cascade regioselective alkylation, followed by cyclocondensation of quinoline N‐oxides with α‐diazo esters has been achieved successfully to provide heteroarene‐containing conjugated π‐systems. The developed method is simple, straightforward, and economical with a broad range of substrate scope. The dual role of copper catalyst in the C?H bond functionalization and in Lewis acid‐promoted cyclization was explored. 相似文献
178.
Suppose a device is subjected to a sequence of shocks occurring randomly in time according to a homogeneous Poisson process. In this paper we introduce a class of non-monotonic aging distributions, the so-called New Worse then Better than Used in Failure Rate (NWBUFR) and New Worse then Better than Average Failure Rate (NWBAFR). It is shown under appropriate conditions on the probability of surviving a given number of shocks that the non-monotonic aging classes NWBUFR and NWBAFR arise from suitable Poisson shock models. 相似文献
179.
Kakali Mukherjee Rumpa Saha Aniruddha Ghosh Bidyut Saha 《Research on Chemical Intermediates》2013,39(6):2267-2286
Chromium can exist in different oxidation states (e.g. 0, III, VI). Chromium can be both beneficial and toxic to animals and humans depending on its oxidation state and concentration. At low concentration, Cr(III) is essential for animal and human health. Chromium(VI) compounds are highly soluble, mobile and bioavailable compared to trivalent chromium. Chromium(VI) is dangerous for humans due to its toxicity and carcinogenic properties. The presence of hexavalent chromium in waste water is a potential hazard to aquatic animals and humans. Various methods are adopted for the removal of hexavalent chromium from industrial effluents. Among these different techniques, biosorption is the most promising one. In this process, the various components present in biomaterial reduce the toxic hexavalent chromium to non-toxic trivalent chromium. Algae, fungi and bacteria have biosorption properties, and cell walls are responsible for biosorption of dead biomaterial. But this process removes chromium from waste water very slowly. So for chemical modification of biosorbents, optimization of biosorption parameters is required to increase the effectiveness of this process. 相似文献
180.
Rumpa Saha Sumanta K. Ghosh Aniruddha Ghosh Indrajit Saha Kakali Mukherjee Ankita Basu Bidyut Saha 《Research on Chemical Intermediates》2013,39(2):631-643
Chromic acid oxidation of dl-mandelic acid in the presence and absence of different promoters has been studied in aqueous media under the kinetic conditions [mandelic acid]T ? [Cr(VI)]T and [promoter]T ? [Cr(VI)]T at 30 °C. The promoters used in this oxidation reaction, picolinic acid (PA), 2,2′-bipyridine (bpy), and 1,10-phenanthroline (phen), are strong chelating ligands which form complexes with most transition metal ions. The reaction is first-order with regard to [H+], [mandelic acid]T, and [Cr(VI)]T and also has first-order dependence on [promoter]T. HCrO4 ? was found to be kinetically active in the absence of promoters; in the presence of promoters the Cr(VI)–promoter complexes were believed to be the active oxidants. In this path the Cr(VI)-promoter complex in each case undergoes nucleophilic attack by the mandelic acid to form a ternary complex which subsequently undergoes redox decomposition involving 3e transfer as the rate-determining step. Among the three promoters oxidation is much faster with 1,10-phenanthroline. 相似文献