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911.
Andrea Sabatino Emanuele Penocchio Giulio Ragazzon Alberto Credi Diego Frezzato 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(40):14479-14486
The first study in which stochastic simulations of a two‐component molecular machine are performed in the mass‐action regime is presented. This system is an autonomous molecular pump consisting of a photoactive axle that creates a directed flow of rings through it by exploiting light energy away from equilibrium. The investigation demonstrates that the pump can operate in two regimes, both experimentally accessible, in which light‐driven steps can be rate‐determining or not. The number of photons exploited by an individual molecular pump, as well as the precision of cycling and the overall efficiency, critically rely on the operating regime of the machine. This approach provides useful information not only to guide the chemical design of a self‐assembling molecular device with desired features, but also to elucidate the effect of the environment on its performance, thus facilitating its experimental investigation. 相似文献
912.
Diego Mateo Andrea Santiago‐Portillo Josep Albero Sergio Navaln Mercedes Alvaro Hermenegildo García 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(49):18007-18012
Prolonged (weeks) UV/Vis irradiation under Ar of UiO‐66(Zr), UiO66 Zr‐NO2, MIL101 Fe, MIL125 Ti‐NH2, MIL101 Cr and MIL101 Cr(Pt) shows that these MOFs undergo photodecarboxylation of benzenedicarboxylate (BDC) linker in a significant percentage depending on the structure and composition of the material. Routine characterization techniques such as XRD, UV/Vis spectroscopy and TGA fail to detect changes in the material, although porosity and surface area change upon irradiation of powders. In contrast to BCD‐containing MOFs, zeolitic imidazolate ZIF‐8 does not evolve CO2 or any other gas upon irradiation. 相似文献
913.
Andrei Hutanu Steffen Kiessig Andrea Bathke Rolf Ketterer Sonja Riner Jan Olaf Stracke Markus Wild Bernd Moritz 《Electrophoresis》2019,40(22):3014-3022
Charge heterogeneity profiling is important for the quality control (QC) of biopharmaceuticals. Because of the increasing complexity of these therapeutic entities [1], the development of alternative analytical techniques is needed. In this work, flow‐through partial‐filling affinity capillary electrophoresis (FTPFACE) has been established as a method for the analysis of a mixture of two similar monoclonal antibodies (mAbs). The addition of a specific ligand results in the complexation of one mAb in the co‐formulation, thus changing its migration time in the electric field. This allows the characterization of the charged variants of the non‐shifted mAb without interferences. Adsorption of proteins to the inner capillary wall has been circumvented by rinsing with guanidine hydrochloride before each injection. The presented FTPFACE approach requires only very small amounts of ligands and provides complete comparability with a standard CZE of a single mAb. 相似文献
914.
Jakob Knelles Dr. Stuart Beardsworth Korinna Bader Dr. Johanna R. Bruckner Andrea Bühlmeyer Robert Forschner Kevin Schweizer Dr. Wolfgang Frey Prof. Dr. Frank Giesselmann Prof. Dr. Yann Molard Prof. Dr. Sabine Laschat 《Chemphyschem》2019,20(17):2210-2216
A series of tetraguanidinium tetraphenylethene (TPE) arylsulfonates with different chain lengths was prepared via ionic self-assembly of tetraguanidinium TPE chloride and the respective methyl arylsulfonates. Liquid crystalline properties were studied by differential scanning calorimetry, polarizing optical microscopy and X-ray diffraction. Tetraguanidinium TPE arylsulfonates with chain lengths of C8–C12 displayed hexagonal columnar mesophases over a broad temperature range, while derivatives with longer chains showed oblique columnar phases. In solution all compounds displayed aggregation-induced emission behaviour. Temperature-dependent luminescence spectra of the bulk phase of the tetraguanidinium TPE arylsulfonate with C14 side chains revealed a strong luminescence both in the solid state and the oblique columnar mesophase. The emission behaviour was rationalized by a unique combination of restriction of intramolecular rotation of the TPE core, Coulomb interaction between the guanidinium cations and π–π interactions of the anionic arylsulfonate moieties. 相似文献
915.
Mischa Baier Nils H. Rustmeier Joachim Harr Norbert Cyrus Guido J. Reiss Andrea Grafmüller Brbel S. Blaum Thilo Stehle Laura Hartmann 《Macromolecular bioscience》2019,19(5)
Divalent precision glycooligomers terminating in N‐acetylneuraminic acid (Neu5Ac) or 3′‐sialyllactose (3′‐SL) with varying linkers between scaffold and the glycan portions are synthesized via solid phase synthesis for co‐crystallization studies with the sialic acid‐binding major capsid protein VP1 of human Trichodysplasia spinulosa‐associated Polyomavirus. High‐resolution crystal structures of complexes demonstrate that the compounds bind to VP1 depending on the favorable combination of carbohydrate ligand and linker. It is found that artificial linkers can replace portions of natural carbohydrate linkers as long as they meet certain requirements such as size or flexibility to optimize contact area between ligand and receptor binding sites. The obtained results will influence the design of future high affinity ligands based on the structures presented here, and they can serve as a blueprint to develop multivalent glycooligomers as inhibitors of viral adhesion. 相似文献
916.
Pittner Angelina Wendt Sebastian Zopf David Dathe André Grosse Norman Csáki Andrea Fritzsche Wolfgang Stranik Ondrej 《Analytical and bioanalytical chemistry》2019,411(8):1537-1547
Analytical and Bioanalytical Chemistry - In this work we describe a very fast and flexible method for fabrication of plasmon-supporting substrates with micro-patterning capability, which is... 相似文献
917.
We identify excitonic confinement in one-dimensional molecular chains (i.e., polyacetylene and H2) as the main driving force for the saturation of the chain polarizability as a function of the number of molecular units. This conclusion is based on first principles time-dependent density-functional theory calculations using a recently developed exchange-correlation kernel that accounts for excitonic effects. The failure of simple local and semilocal functionals is shown to be linked to the lack of memory effects, spatial ultranonlocality, and self-interaction corrections. These effects get smaller as the gap reduces, in which case such simple approximations do perform better. 相似文献
918.
The existence of the two-electron cusp in atomic collisions, i.e., the enhanced emission of two electrons in the forward direction with velocities equal to that of the projectile, has been investigated experimentally. Using a time-of-flight technique, the energies of the two electrons resulting from the simultaneous target and projectile ionization in 100-keV He(0)+He collisions have been measured by detecting triple coincidence between the electrons and the outgoing He(+) ion. The coincidence yield clearly shows a peak as a function of the electron energies at the expected cusp position. Furthermore, a strong correlation was found between the energies of the two electrons, which is traced back to an angular correlation of 180 degrees in the projectile-centered reference system. 相似文献
919.
We present a novel reflectometric technique for the measurement of orientation and modulus of the linear birefringence vector in single-mode optical fibers. The technique provides information also on circular birefringence, although this component, if present, appears as a rotation of the linear birefringence. A detailed theoretical analysis is reported and validated by experimental results. 相似文献
920.
A reconfigurable coupled-resonator optical waveguide made of a few directly coupled ring resonators is employed to control the delay of data streams modulated at tens of gigabits per second. A delay of 8 bit lengths (1 optical byte) with a small pulse broadening and 1 dB/bit fractional loss is achieved by using only eight rings. The limiting role of waveguide loss and spurious backreflections is experimentally investigated. The high storage efficiency (1 bit/ring) of the device enables an easy, reliable, hitless, and relatively low-power-consuming management of the delay. A higher storage efficiency is demonstrated to be associated to an unavoidable higher pulse distortion. 相似文献