Development of Hydroprocessing Route to Transportation Fuels from Non-Edible Plant-Oils

Catalysts with tunable porosity, crystallinity and acidity can selectively produce aviation fuels and road transportation fuels via hydroprocessing of non-edible oils. Here we discuss several catalyst supports—mesoporous alumina, silica–alumina and hierarchical mesoporous zeolites, developed and used as support for hydroprocessing catalysts (Ni–Mo, Co–Mo, Ni–W), for the selective production of transportation fuels. These developed catalysts were used for the hydroconversion of waste cooking-oil, jatropha-oil, algal-oil and their mixtures with petroleum refinery oils. The physicochemical properties of the catalyst were tuned for optimal performance on the basis of evaluation results on high pressure fixed bed microreactors and pilot scale reactors. These studies targeted the production of transportation fuels (gasoline, kerosene and diesel) by hydroprocessing (hydrotreating or hydrocracking) renewable feed stocks or co-processing with fossil based oils. Modelling and process optimization studies for prediction of kinetic rate parameters and to know the reaction pathways for the conversion of these feed stocks to various range of hydrocarbon fuels, were also carried out. These studies provided the vital information that the reaction pathways were temperature dependent.     

Synthesis of novel benzopyrano[3,2-c]coumarins via tandem base promoted nucleophilic substitution and intramolecular electrophilic aromatic cyclization

Efficient and facile synthesis of 7H-benzopyrano[3,2-c]coumarins has been achieved by mild base promoted reaction of 4-chloro-3-formylcoumarin with diversely functionalized resorcinols. All the products were obtained as pure precipitates from the reaction mixture and the structure of the product was confirmed by X-ray analysis.     

Metal‐Free Triplet Phosphors with High Emission Efficiency and High Tunability

Design of highly efficient phosphorescent emitters based on metal‐ and heavy atom‐free boron compounds has been demonstrated by taking advantage of the singlet fission process. The combination of a suitable molecular scaffold and appropriate electronic nature of the substituents has been utilized to tailor the phosphorescence emission properties in solution, neat solid, and in doped PMMA thin films.     

Non‐dominated sorting particle swarm optimization (NSPSO) and network security policy enforcement for Policy Space Analysis

Network operators depend on security services with the aim of safeguarding their IT infrastructure. Various types of network security policies are employed on a global scale and are disseminated among several security middleboxes implemented in networks. But, owing to the complications in security policies, it is not quite efficient to directly use the path‐wise enforcement schemes that are prevalent. The major motivation of this work is to improve security levels and solve the policy enforcement problem. For the first time, this work reports the issue of policy enforcement on middleboxes. The major contribution of this work is to design security policy enforcement as a Weighted K Set Covering Problem, and we designed a Policy Space Analysis (PSA) tool intended for a group of operations in the security policy. This PSA tool was developed based on range‐signified hyper‐rectangles, which are indexed by the Hilbert R‐tree. Leveraging the PSA, we first investigated the topological features of various kinds of policies. Balancing the PSA tool in a non‐dominated sorting particle swarm optimization technique exposes the intrinsic difficulties of this security strategy and provides guidance for designing the enforcement approach. In addition, in this research, a new fuzzy rule‐based classification system is introduced for packet classification. A scope‐wise policy enforcement algorithm was proposed, which chooses a moderate number of enforcement network nodes for deploying multiple policy subsets in a greedy manner. This scheme is much quicker compared with the first one and therefore has found its application in real‐time deployments.     

Molecular forces and elastic constants of polyethylene single crystals

Polyethylene has an orthorhombic lattice for which nine elastic constants exist; they are obtained in terms of the intra- and intermolecular forces. Constants involved in the 6-12 Lennard-Jones potential approximating the London dispersion type of van der Waals' forces are obtained by computing the crystal potential energy and comparing it with the cohesive energy. First and second nearest-neighbor interactions are considered to establish relationship between the elastic constants and the interaction constants. The latter are obtained in terms of the C—C bond, stretching, bending, and repulsive force constants and the L-J potential constants. A limited type of central force assumption is applied. Values of Young and shear moduli are obtained along the three axes. The value along the chain compares with the experimentally determined and calculated values for oriented polyethylene. Young's modulus along the lateral direction is of the order of Young's modulus of bulk polyethylene, showing that intermo-lecular forces are the ones that determine the Young modulus of bulk polyethylene.     

A thermo-mechanically-coupled theory accounting for hydrogen diffusion and large elastic–viscoplastic deformations of metals

In this paper we develop a thermodynamically-consistent coupled-theory which accounts for diffusion of hydrogen, diffusion of heat, and large elastic–viscoplastic deformations of metals. The theory should be of utility in the analysis of hydrogen diffusion in elastic–plastically-deforming solids, an analysis which is an essential prerequisite for theoretical and numerical efforts aimed at modeling the integrity of structural components used for hydrogen gas storage and distribution.     

Stereoselective and facile total synthesis of (+)-goniodiol,a styryllactone from carbohydrates

The stereoselective synthesis of (+)-goniodiol, a cytotoxic styryllactone, has been accomplished in 10 steps starting from inexpensive and readily available d-manitol and δ-gluconolactone involving the direct and straightforward reaction conditions of Grignard addition, chain elongation, and hydroboration, thus making the synthesis simple and convenient.