含氟双环内酯反应中间体及产物的 NMR研究

利用NMR 核磁共振技术对含氟双环内酯反应过程中的中间体及其产物进行了结构确定,为反应机理的研究提供了有力的依据.     

IRFPA图像采集系统的设计与实现

介绍了基于USB2.0的高速红外图像采集系统的总体设计思想.用CPLD实现IRFPA探测器和FIFO的时序控制驱动电路、奇偶数据整合,采用FIFO作为数据缓存,达到了系统结构简化和性能优化的目的.研制出一套完整的红外焦平面高速图像采集系统.结果表明:该系统能够满足使用要求.     

PERVAPORATION OF ETHANOL/WATER MIXTURES WITH HIGH FLUX BY ZEOLITE-FILLED PDMS/PVDF COMPOSITE MEMBRANES

Thin-film zeolite-filled silicone/PVDF composite membranes were fabricated by incorporating zeolite particles into PDMS(poly(dimethylsiloxane)) membranes.The morphology of zeolite particles and zeolite filled silicone composite membranes were characterized by SEM.The zeolite-filled PDMS/PVDF composite membranes were applied for the pervaporation of ethanol/water mixtures and showed higher flux compared with that reported in literatures.The effect of zeolite loading and Si/Al ratio of zeolite particles on...     

A new flavonoid glucoside from Cassia angustifolia

A new flavonoid glucoside with a known one was isolated from the leaves of Cassia angustifolia.Based on the spectral analysis, including MS,~1H NMR,~(13)C NMR,DEPT,~1H-~1HCOSY,HMQC,HMBC and NOSEY,their chemical structures were determined as kaempferol-3-O-[(6′′′-O-trans-sinnapoyl)-β-D-glucopyranosyl(1→)]-β-D-glucopyranoside 1 and apigenin-6,8-di-C-glycoside 2.     

Characterization and Anti-tumor Activity of Glycopeptides from Ganoderma sinensis

The water-soluble part(GS) of Ganoderma sinense Zhao,Xu et Zhang was divided into high molecu-lar(GS-H) and low molecular(GS-L) parts by Cellulose Super Filtration,and GS was also fractionated into four frac-tions,GS-1,2,3,and 4 by ethanol precipitation according to their molecular weights.Chemical analysis shows that GS and GS-1,2,3,4 were complexes of polysaccharide and peptide.The fractions with molecular weights over 4000,GS-1,2,3,and GS-H show anti-tumor activities,however,the fractions with molecular ...     

Synthesis and Biological Activity of Novel 2,3-Dihydro-2-phenylsulfonylhydrazono-3-(2′,3′,4′,6′-tetra-O-acetyl-β-D-glucopyranosyl)thiazoles

A series of novel 2,3-dihydro-2-phenylsulfonylhydrazono-3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl) thiazoles were designed and synthesized via the reaction of thiosemicarbazide with chloroaldehyde.Their chemical structures were characterized by 1H and 13C NMR spectroscopy and elemental analysis.The bioassay results indicate that some of these compounds exhibit moderate fungicidal and herbicidal activities.     

Measurement of Atrazine Adsorption onto Surficial Sediments (Natural Surface Coatings)——New Evidence for the Importance of Fe Oxides

To reveal the relative contribution of the components, Fe, Mn oxides or organic materials(OMs) in the surficial sediments(SSs), and the natural surface coating samples(NSCSs) to adsorbing atrazine(AT), a selective chemical extraction technique was employed, to remove the different components, and the adsorption characteristics of AT on the SSs and the NSCSs were investigated. The observed adsorptions of AT on the original and extracted SSs and NSCSs were analyzed by nonlinear least squares fitting(NLSF) to estimate the relative contribution of the com-ponents. The results showed that the maximum adsorption of AT on the NSCSs was greater than that in the SSs, be-fore and after extraction treatments, implying that the NSCSs were more dominant than the SSs for organic pollutant adsorption. It was also found that the Fe oxides, OMs, and residues in SSs(NSCSs) facilitated the adsorption of AT, but Mn oxides directly or indirectly restrained the interaction of AT with SSs(NSCSs) particles. The contribution of the Fe oxides to AT adsorption was more than that of OMs; the greatest contribution to AT adsorption on a molar ba-sis was from the Fe oxides in the nonresidual fractions, indicating that the Fe oxides played an important role in con-trolling the environmental behavior of AT in an aquatic environment.     

叶下珠荧光物质的分离和性质研究

目的：研究叶下珠药材中的荧光活性物质及性质,为光敏剂的筛选提供资料。方法：采用50％乙醇提取、乙酸乙酯萃取,对叶下珠植物提取分离：采用荧光扫描确定提取液激发波长和发射波长。提取液经硅胶柱层析,氯仿：甲醇：磷酸（85：14：1）洗脱。结果：提取液最小激发波长和最大发射波长分别为418nm和667nm。硅胶柱层析获得6种组分,其中一种组分,经418nm光激发后,在667nm处具有较强的荧光发射峰。pH酸性、提高温度和光照均可提高其荧光强度,碱件条件会导致其荧光猝灭。通过液质测定,推断其为珠子草素。结论：该成分具有光敏剂开发前景。     

组合轴扭转角的"整体化"求解方法

针对材料力学中常见的一种组合轴扭转角的求解问题,提出了一种方便、快捷的整体化解法,避免了将其视为静不定问题的传统求解方法的繁琐,文章最后讨论了该方法的可行性依据与适用范围.     

MULTIPLE AND SIGN-CHANGING SOLUTIONS FOR NONLINEAR ELLIPTIC EQUATION WITH CRITICAL POTENTIAL AND CRITICAL PARAMETER

Some embedding inequalities in Hardy-Sobolev space are proved.Furthermore,by the improved inequalities and the linking theorem,in a new k-order Sobolev-Hardy space,we obtain the existence of sign-changing solutions for the nonlinear elliptic equation {-△(k)u:=-△u-(((N-2)2)/4)U/︱X︱2-1/4 sum from i=1 to(k-1) u/(︱x︱2(In(i)R/︱x︱2))=f(x,u),x ∈Ω,u=0,x ∈Ω,where 0 ∈ΩBa(0)RN,N≥3,ln(i)=i éj=1 ln(j),and R=ae(k-1),where e(0)=1,e(j) = ee(j-1) for j≥1,ln(1)=ln,ln(j)=ln ln(j-1) for j≥2.Besides,positive andnegative solutions are obtained by a variant mountain pass theorem.