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91.
Muhammad Mohsin Iqbal Muhammad Imran Tousif Hussain Muhammad Asif Naeem Abdullah A. Al-Kahtani Ghulam Mustafa Shah Sajjad Ahmad Amjad Farooq Muhammad Rizwan Abdul Majeed Abdul Rehman Khan Shafaqat Ali 《Journal of Saudi Chemical Society》2021,25(2):101176
Widespread application of dyes and disposal of their untreated effluents into water bodies adversely affect the ecosystem due to their complex aromatic structures and persistent nature. The present study aims to utilize the cotton stalks biochar (CSB) and its composite with zinc oxide nanoparticles (CSB/ZnONPs) to evaluate for the decontamination their batch scale potential of Congo red dye from wastewater. The characterization of CSB and CSB/ZnONPs was performed with Fourier-transform infra-red (FTIR) spectroscopy, scanning electron microscopy, energy-dispersive X-ray (EDX) and point of zero charge (PZC) to get insight of their potential for the decontamination of CR. The effects of initial CR concentration (25–500 mg/L), dosage of CSB and CSB/ZnONPs (0.5–2 g/L), solution pH (2–10) and contact time (0–180 min) were evaluated on CR removal at temperature (25 ± 1.5 °C). The results disclosed that CSB/ZnONPs showed excellent adsorption potential (556.6 mg/g) in comparison with CSB (250 mg/g) and most of the other adsorbents previously studies in the literature. The equilibrium experimental data were equally explained with Freundlich and Langmuir isotherm models (R2 > 0.98) while kinetic data demonstrated the best fit with pseudo second order model. The CSB/ZnONPs composite exhibited excellent reusability (89.65%) after five adsorption/desorption cycles for the sequestration of CR from contaminated systems. The present study demonstrated that metallic nanocomposite of CSB (CSB/ZnONPs) is an excellent candidate for the cost effective and environment friendly decontamination of CR from industrial wastewater and is suggested to be considered for the decontamination of other pollutants from the wastewater. 相似文献
92.
Bakhat Ali Muhammad Khalid Sumreen Asim Muhammad Usman Khan Zahid Iqbal Ajaz Hussain Riaz Hussain Sarfraz Ahmed Akbar Ali Amjad Hussain Muhammad Imran Mohammed A. Assiri Muhammad Fayyaz ur Rehman Chenxi Wang Changrui Lu 《Molecules (Basel, Switzerland)》2021,26(9)
Organic materials development, especially in terms of nonlinear optical (NLO) performance, has become progressively more significant owing to their rising and promising applications in potential photonic devices. Organic moieties such as carbazole and quinoline play a vital role in charge transfer applications in optoelectronics. This study reports and characterizes the donor–acceptor–donor–π–acceptor (D–A–D–π–A) configured novel designed compounds, namely, Q3D1–Q3D3, Q4D1–Q1D2, and Q5D1. We further analyze the structure–property relationship between the quinoline–carbazole compounds for which density functional theory (DFT) and time-dependent DFT (TDDFT) calculations were performed at the B3LYP/6-311G(d,p) level to obtain the optimized geometries, natural bonding orbital (NBO), NLO analysis, electronic properties, and absorption spectra of all mentioned compounds. The computed values of λmax, 364, 360, and 361 nm for Q3, Q4, and Q5 show good agreement of their experimental values: 349, 347, and 323 nm, respectively. The designed compounds (Q3D1–Q5D1) exhibited a smaller energy gap with a maximum redshift than the reference molecules (Q3–Q5), which govern their promising NLO behavior. The NBO evaluation revealed that the extended hyperconjugation stabilizes these systems and caused a promising NLO response. The dipole polarizabilities and hyperpolarizability (β) values of Q3D1–Q3D3, Q4D1-Q1D2, and Q5D1 exceed those of the reference Q3, Q4, and Q5 molecules. These data suggest that the NLO active compounds, Q3D1–Q3D3, Q4D1–Q1D2, and Q5D1, may find their place in future hi-tech optical devices. 相似文献
93.
Nisar Jan Nasir Umar Ali Ghulam Shah Afzal Farooqi Zahoor Hussain Iqbal Munawar Shah Muhammad Raza 《Cellulose (London, England)》2021,28(12):7593-7607
Cellulose - In this work we have attempted to use biomass as energy source which is abundantly available throughout the world. The work is focused on pyrolysis of sugarcane bagasse in a... 相似文献
94.
Miller DH Sanghi B Shipsey IP Xin B Adams GS Anderson M Cummings JP Danko I Ge JY Hu D Moziak B Napolitano J He Q Insler J Muramatsu H Park CS Thorndike EH Yang F Artuso M Blusk S Khalil S Li J Menaa N Mountain R Nisar S Randrianarivony K Sia R Skwarnicki T Stone S Wang JC Bonvicini G Cinabro D Dubrovin M Lincoln A Asner DM Edwards KW Naik P Briere RA Ferguson T Tatishvili G Vogel H Watkins ME Rosner JL Adam NE Alexander JP Cassel DG Duboscq JE Ehrlich R Fields L Gibbons L Gray R Gray SW 《Physical review letters》2007,99(12):122002
We measure the mass of the eta meson using psi(2S) --> etaJ/psi events acquired with the CLEO-c detector operating at the CESR e(+)e(-) collider. Using the four decay modes eta --> gamma gamma, 3pi(0), pi(+)pi(-)pi(0), and pi(+)pi(-)gamma, we find M(eta) = 547.785 +/- 0.017 +/- 0.057 MeV, in which the first uncertainty is statistical and the second systematic. This result has an uncertainty comparable to the two most precise previous measurements and is consistent with that of NA48, but is inconsistent at the level of 6.5 sigma with the much smaller mass obtained by GEM. 相似文献
95.
Asmahani Awang S.K. Ghoshal M.R. Sahar M. Reza Dousti Raja J. Amjad Fakhra Nawaz 《Current Applied Physics》2013,13(8):1813-1818
Glasses with composition 70TeO2–20ZnO–10Na2O–0.5Er2O3–(x)Au are synthesized by melt-quenching technique. Their spectroscopic and optical characterizations are made. The presence of gold nanoparticles (Au NPs) with average size ~9 nm is confirmed from TEM micrograph. The value of Edir is found to lie between 3.082 and 3.073 eV, while Eindir lies within 2.765 to 2.724 eV. The observed visible up-conversion (UC) emission under 779 nm excitation wavelength exhibits two bands centered at 546 nm (green) and 637 nm (red) in all samples. The glass with 0.4 mol% Au NPs shows dominant enhancement in the UC emission intensity of the order of 3.5 times for the green band (4S3/2 → 4I15/2) and a weaker enhancement for the red (4F9/2 → 4I15/2) band. The optical properties of the system are affirmed to depend strongly on the Au concentration in the dielectric medium. The absorption spectra consist of six bands attributed to absorption from ground state (4I15/2) to 4I13/2, 4I11/2, 4I9/2, 4F9/2, 2H11/2, and 4F7/2 excited states. The structural reveals that the types of bonding and difference in electro-negativity can be manipulated by the presence of metallic NPs in glass matrix. Judd–Ofelt analysis asserts the increase in Ω2 and Ω6 parameters with the addition of Au NPs and the enhancement of green and red emissions. The enhancement is mainly attributed to large plasmonic effect of Au NPs. The proposed glasses can be nominated as potential materials for solid state laser developments. 相似文献
96.
Laser irradiation effects on surface, structural and mechanical properties of Al–Cu–Mg alloy (Al–Cu alloy 2024) have been investigated. The specimens were irradiated for various fluences ranging from 3.8 to 5.5 J/cm2 using an Excimer (KrF) laser (248 nm, 18 ns, 30 Hz) under vacuum environment. The surface and structural modifications of the irradiated targets have been investigated by scanning electron microscope (SEM) and X-ray diffractometer (XRD), respectively. SEM analysis reveals the formation of micro-sized craters along the growth of periodic surface structures (ripples) at their peripheries. The size of the craters initially increases and then decreases by increasing the laser fluence. XRD analysis shows an anomalous trend in the peak intensity and crystallite size of the specimen irradiated for various fluences. A universal tensile testing machine and Vickers microhardness tester were employed in order to investigate the mechanical properties of the irradiated targets. The changes in yield strength, ultimate tensile strength and microhardness were found to be anomalous with increasing laser fluences. The changes in the surface and structural properties of Al–Cu alloy 2024 after laser irradiation have been associated with the changes in mechanical properties. 相似文献
97.
This paper presents a general fullwave analysis for the problem of shielded coplanar stripline (CPS) discontinuities. The analysis is based on the electric field space domain integral equation (SDIE) approach. The Green's functions pertinent to the problem are formulated to take into consideration any number of planar stratified dielectric layers. The method of moments is applied to numerically solve the SDIE for the unknown current distribution over the CPS conductor surface. Numerical results for CPS open-end, series-gap, CPS resonator, and straight CPS series stubs are presented. Most of the included SDIE results are compared with quasi-transverse electromagnetic results, finite difference time domain results, or complex image technique results 相似文献
98.
Ahmed N Shirinfar B Youn IS Bist A Suresh V Kim KS 《Chemical communications (Cambridge, England)》2012,48(21):2662-2664
A new water-soluble and fluorescent imidazolium-anthracene cyclophane 1 effectively recognizes and differentiates the biologically important GTP and ATP in 100% aqueous solution of physiological pH 7.4. Fluorescence, (1)H-NMR spectra and ab initio calculations demonstrate that excimer formation and fluorescence enhancement occur upon GTP and ATP binding, respectively, through (C-H)(+)···A(-) hydrogen bond interactions. 相似文献
99.
Nisar J Pathak B Wang B Kang TW Ahuja R 《Physical chemistry chemical physics : PCCP》2012,14(14):4891-4897
The band gap reduction and effective utilization of visible solar light are possible by introducing the anionic hole-hole mediated coupling in Sr(2)Nb(2)O(7). By using the first principles calculations, we have investigated the mono- and co-anionic doping (S, N and C) in layered perovskite Sr(2)Nb(2)O(7) for the visible-light photocatalysis. Our electronic structure and optical absorption study shows that the mono- (N and S) and co-anionic doped (N-N and C-S) Sr(2)Nb(2)O(7) systems are promising materials for the visible light photocatalysis. The calculated binding energies show that if the hole-hole mediated coupling could be introduced, the co-doped systems would be more stable than their respective mono-doped systems. Optical absorption curves indicate that doping S, (N-N) and (C-S) in Sr(2)Nb(2)O(7) can harvest a longer wavelength of the visible light spectrum as compared to the pure Sr(2)Nb(2)O(7) for efficient photocatalysis. 相似文献
100.
Anwar Ali Shadma Tasneem Priyanka Bidhuri Vidiksha Bhushan Nisar Ahmad Malik 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2012,86(13):1923-1929
Conductivities, densities and ultrasonic speeds measurements of hexadecyltrimethylammonium bromide (HTAB) in aqueous solutions of glycine (Gly) and glycylglycine (Gly-Gly) have been made at various temperatures. The critical micelle concentration (CMC), the degree of ionization (??) of the micelles, standard free energy, enthalpy, and entropy of the micellization process (??G m ° , ??H m ° , and ??S m ° ) for the present systems were estimated at different temperatures. The CMC values of HTAB in aqueous Gly and Gly-Gly were also evaluated by density and ultrasonic speed measurements. Apparent molar volumes, (V ?), apparent molar volumes at infinite dilution, (V ? ° ), apparent molar compressibilities, (K ?), of HTAB in the pre- and post-micellar regions, and volume change on micellization (??V ? m ) were also estimated. Large positive values of T??S m ° and small negative values of ??H m ° suggest that micellization process is driven primarily by entropy increase. The increase in ??V ? m and K ? with rise in temperature is indicative of less compact micellar structure of HTAB in presence of amino acid additives. These data suggest that amino acids are solubilised probably in the palisade layer of the micelle. 相似文献