Energy‐efficient multi‐level and distance‐aware clustering mechanism for WSNs

Most sensor networks are deployed at hostile environments to sense and gather specific information. As sensor nodes have battery constraints, therefore, the research community is trying to propose energy‐efficient solutions for wireless sensor networks (WSNs) to prolong the lifetime of the network. In this paper, we propose an energy‐efficient multi‐level and distance‐aware clustering (EEMDC) mechanism for WSNs. In this mechanism, the area of the network is divided into three logical layers, which depends upon the hop‐count‐based distance from the base station. The simulation outcomes show that EEMDC is more energy efficient than other existing conventional approaches. Copyright © 2013 John Wiley & Sons, Ltd.     

Slow Relaxation of Magnetization in an Isostructural Series of Zinc–Lanthanide Complexes: An Integrated EPR and AC Susceptibility Study

We report the synthesis, structure, and spectroscopic and dynamic magnetic properties of a series of heterodinuclear complexes, [ZnLn(LH₄)₂](NO₃)₃ ? 6 H₂O (Ln=Nd, Tb, Dy, Ho, Er, and Yb), with the singly deprotonated form of a new compartmentalized Schiff‐base ligand, LH₅. The Ln^III ions in these systems show a distorted square‐antiprism geometry with an LnO₈ coordination sphere. EPR spectroscopy and DC magnetic studies have shown that the anisotropic nature of the complexes is far more complicated than predicted on the basis of a simple electrostatic model. Among the investigated systems, only the Dy^III derivative showed single‐ion magnet behavior, in zero and an applied magnetic field, both in pure polycrystalline samples and in a series of polycrystalline samples with different degrees of dilution at the single‐crystal level in the isostructural Y^III derivative. The rich dynamics observed as functions of frequency, field, and temperature reveals that multiple relaxation mechanisms are at play, resulting in a barrier of 189 cm^?1, which is among the highest reported for a dinuclear Zn–Dy system. Analysis of the dynamic behavior as a function of dilution degree further evidenced the persistence of non‐negligible intermolecular interactions, even at the lowest concentration of 1 %.     

A Regularity Result for the Incompressible Euler Equation with a Free Interface

We address the local existence of solutions of the 2D and 3D water wave problems. For the space dimension three, we consider the irrotational datum u ₀ and prove that the local in time existence holds for initial velocities belonging to H ^2.5+δ , where δ>0 is arbitrary. For the space dimension two, the data does not need to be irrotational. We prove the local in time existence when u ₀ belongs to H ^2+δ and $\operatorname{curl}u_{0}$ to H ^1.5+δ , where δ>0 is arbitrary.     

Tailoring the donor moieties in TPA-based organic dyes for efficient photovoltaic,optical and nonlinear optical response properties

The current study reports tailoring the electronic donor structures of organic dyes to modify their optical and nonlinear optical (NLO) response properties. Five (5) tri-phenyl amine (TPA) based Donor-π-Acceptor (D-π-A) organic dyes with the codes ICAA1 , ICAA2 , ICAA3 , ICAA4 , and ICAA5 were designed and investigated for their optical and NLO properties using quantum chemical methods. Optical and NLO properties of these dyes were studied by CAM-B3LYP method and 6-311G* basis set. The focus has been on the impact of adding secondary donors and shifting their substitutions at ortho (o), meta (m) and para (p) positions. Among all designed compounds, ICAA4 showed the highest amplitude of average third-order NLO polarizability <γ>, which is calculated to be 1316 × 10⁻³⁶ esu. Time-dependent Density Functional Theory (TD-DFT) method was used to determine how a change in the position of the donor affected the excitation energy (E_g) and NLO response properties. The findings showed that changing the position of the secondary donor results in a red shift among absorption spectra as well as the increase in their NLO responses. Complete process of intramolecular charge transfer (ICT) has been investigated in terms of different optical parameters such as frontier molecular orbitals (FMOs), molecular electrostatic potentials (MEPs), transition density matrix (TDMs), density of states (DOS), electron density difference (EDD), and natural bond orbital (NBO) analysis. Our calculations for study of ICT process indicate that p-position of methoxy group performs better among all other positions and even it has better NLO response properties than the compound with three collective methoxy groups. The calculated V_oc values of all designed molecules range from 1.09 to 1.30, all of them are positive while their ΔG_inject is found to be in the range of −0.87 to −1.79 eV indicating their decent potential for photovoltaic applications. The studied optical, NLO and photovoltaic parameters illustrated that ICAA1 to ICAA5 are appropriate molecules not only for NLO applications but also for efficient photovoltaic purposes.     

Weyl,curvature, ricci,and metric tensor symmetries

Weyl symmetries for some specific spherically symmetric static spacetimes are derived and compared with metric, Ricci, and curvature tensor symmetries.     

Evolutionary non‐cooperative spectrum sharing game: long‐term coexistence for collocated cognitive radio networks

Collocated cognitive radio networks (CRNs) employ coexistence protocols to share the spectrum when it is not being used by the licensed primary users. These protocols work under the assumption that all spectrum bands provide the same level of quality of service, which is somewhat simplistic because channel conditions as well as the licensee's usage of allocated channels can vary significantly with time and space. These circumstances dictate that some channels may be considered better than others; therefore, CRNs are expected to have a preference over the choice of available channels. Because all CRNs are assumed to be rational and select the best available channels, it can lead to an imbalance in contention for disparate channels, degraded quality of service, and an overall inefficient utilization of spectrum resource. In this paper, we analyze this situation from a game theoretic perspective and model the coexistence of CRNs with heterogeneous spectrum as an evolutionary anti‐coordination spectrum‐sharing game. We derive the evolutionarily stable strategy (ESS) of the game by proving that it cannot be invaded by a greedy strategy. We also derive the replicator dynamics of the proposed evolutionary game, a mechanism with which players can learn from their payoff outcomes of strategic interactions and modify their strategies at every stage of the game and subsequently converge to ESS. Because all CRNs approach ESS based solely upon the common knowledge payoff observations, the evolutionary game can be implemented in a distributed manner. Finally, we analyze the game from the perspective of fairness using Jain's fairness index under selfish behavior from CRNs. Copyright © 2016 John Wiley & Sons, Ltd.     

Tensile,Electrical Conductivity,and Morphological Properties of Carbon Black–Filled Epoxy Composites

This work investigates the effect of carbon black content on the tensile, electrical, and morphological properties of epoxy matrix. Carbon black–filled epoxy composites were obtained by mixing the desired amount of carbon black from bamboo stem (BS-CB), oil palm empty fruit bunch (EFB-CB), and coconut shell (CNS-CB) with the epoxy resin. Tensile and electrical properties of carbon black from three different sources (BS-CB, EFB-CB, and CNS-CB) used to fill epoxy composite with 5% filler loading were measured and the results indicated improvement in tensile and electrical properties. The diffraction patterns of X-ray diffraction (XRD) indicated nonlinear crystalline amorphous structure of the CB.     

Sorption studies of metal ions on napthol blue–black modified Amberlite IR-400 anion exchange resin: Separation and determination of metal ion contents of pharmaceutical preparation

Anion exchange resin Amberlite IR-400 has been modified with napthol blue–black. Effect of concentration, time, pH and temperature on the sorption of dye has been studied. The uptake sequence of various metal ions in a number of solvents has been determined. On the basis of distribution coefficients (K_d) in a number of solvent systems, some important binary separations of metal ions of analytical interest have been exploited. The practical applicability of the modified material has been demonstrated in the analysis of synthetic and commercially available antacid and antioxidant formulations namely digene and I-Vit.     

Identification of human calculi with time‐of‐flight secondary ion mass spectrometry

Time‐of‐flight secondary ion mass spectrometry was used to study four human calculi and to compare the results with those from twelve commercially available urinary calculi minerals including three organic compounds (L‐cystine, uric acid and sodium urate). Phase identification of calcium phosphate compounds was carried out by considering the relative ion abundances of [Ca₂O]⁺ and [CaPO₂]⁺. Deprotonated [M–H]^? and protonated [M+H]⁺ uric acid were detected and used for component recognition in pure uric acid and in the mixed samples of struvite, calcium oxalate and uric acid. Iodine related to the medical history of a patient was also detected. Copyright © 2009 John Wiley & Sons, Ltd.     

Drug impurity profiling by capillary electrophoresis/mass spectrometry using various ionization techniques

Capillary electrophoresis/mass spectrometry (CE/MS) is predominantly carried out using electrospray ionization (ESI). Recently, atmospheric pressure chemical ionization (APCI) and atmospheric pressure photoionization (APPI) have become available for CE/MS. With the VUV lamp turned off, the APPI source may also be used for CE/MS by thermospray ionization (TSI). In the present study the suitability of ESI, APCI, APPI and TSI for drug impurity profiling by CE/MS in the positive ion mode is evaluated. The drugs carbachol, lidocaine and proguanil and their potential impurities were used as test compounds, representing different molecular polarities. A background electrolyte of 100 mM acetic acid (pH 4.5) provided baseline separation of nearly all impurities from the respective drugs. APPI yielded both even‐ and odd‐electron ions, whereas the other ionization techniques produced even‐electron ions only. In‐source fragmentation was more pronounced with APCI and APPI than with ESI and TSI, which was most obvious for proguanil and its impurities. In general, ESI and TSI appeared the most efficient ionization techniques for impurities that are charged in solution achieving detection limits of 100 ng/mL (full‐scan mode). APPI and APCI showed a lower efficiency, but allowed ionization of low and high polarity analytes, although quaternary ammonium compounds (e.g. carbachol) could not be detected. Largely neutral compounds, such as the lidocaine impurity 2,6‐dimethylaniline, could not be detected by TSI, and yielded similar detection limits (500 ng/mL) for ESI, APPI and APCI. In many cases, impurity detection at the 0.1% (w/w) level was possible when 1 mg/mL of parent drug was injected with at least one of the CE/MS systems. Overall, the tested CE/MS systems provide complementary information as illustrated by the detection and identification of an unknown impurity in carbachol. Copyright © 2009 John Wiley & Sons, Ltd.