全文获取类型
收费全文 | 671篇 |
免费 | 38篇 |
国内免费 | 2篇 |
专业分类
化学 | 541篇 |
晶体学 | 5篇 |
力学 | 10篇 |
数学 | 76篇 |
物理学 | 52篇 |
无线电 | 27篇 |
出版年
2024年 | 1篇 |
2023年 | 9篇 |
2022年 | 21篇 |
2021年 | 48篇 |
2020年 | 25篇 |
2019年 | 24篇 |
2018年 | 21篇 |
2017年 | 24篇 |
2016年 | 35篇 |
2015年 | 33篇 |
2014年 | 27篇 |
2013年 | 49篇 |
2012年 | 49篇 |
2011年 | 64篇 |
2010年 | 25篇 |
2009年 | 32篇 |
2008年 | 30篇 |
2007年 | 37篇 |
2006年 | 26篇 |
2005年 | 28篇 |
2004年 | 25篇 |
2003年 | 19篇 |
2002年 | 17篇 |
2001年 | 9篇 |
2000年 | 3篇 |
1999年 | 4篇 |
1998年 | 4篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1993年 | 2篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1969年 | 1篇 |
1964年 | 1篇 |
排序方式: 共有711条查询结果,搜索用时 515 毫秒
71.
JPC – Journal of Planar Chromatography – Modern TLC - Nicotinic acid (NAC) and its derivatives methyl nicotinate (MN), ethyl nicotinate (EN), isopropyl nicotinate (IPN), butyl... 相似文献
72.
Ming Sun Alina Stetco Erika F Merschrod S 《Langmuir : the ACS journal of surfaces and colloids》2008,24(10):5418-5421
Ordered arrays of collagen microfibrils form rapidly and spontaneously from a solution of monomers deposited onto a mica substrate. These arrays are well-ordered and apparently continuous over the entire substrate. Correlated atomic force microscope images and Laué diffraction patterns indicate that the protein alignment and microfibril formation is controlled by the crystal orientation of the mica substrate rather than fluid flow or drying effects. This surface-induced mechanism allows for immediate, robust, and reproducible pattern formation. 相似文献
73.
Staśkowiak E Dudkowiak A 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(9):2033-2039
The paper deals with some fast and slow processes of excitation energy deactivation in bacteriochlorophyll c and bacteriopheophytin c. The experiments were carried out in the air, and in oxygen or nitrogen atmosphere at different temperatures. The parameters such as fluorescence yield, the yield of triplet state generation and photostability were estimated. On the basis of these parameters an attempt was made to preliminary select the pigments best suited for medical applications. It seems that the photosensitive and highly fluorescent bacteriochlorophyll c could be used as a fluorescence probe for diagnosis, whereas its derivative without the magnesium ion is better suited for the photochemical reactions occurring during therapeutic treatment. 相似文献
74.
It is shown that the number of alternating knots of given genus g>1 grows as a polynomial of degree 6g−4 in the crossing number. The leading coefficient of the polynomial, which depends on the parity of the crossing number, is related to planar trivalent graphs with a Bieulerian path. The rate of growth of the number of such graphs is estimated. 相似文献
75.
We construct triangular hyperbolic polyhedra whose links are generalized 4-gons. The universal cover of such a polyhedron is a hyperbolic building, whose apartments are hyperbolic planes tessellated by regular triangles with angles . The fundamental groups of the polyhedra are hyperbolic, torsion free, with property (T). To cite this article: R. Kangaslampi, A. Vdovina, C. R. Acad. Sci. Paris, Ser. I 342 (2006). 相似文献
76.
A sturdy home-built sheathless CE/ESI-QTOF-MS system was developed and optimized for carbohydrate analysis. The interface and employed methodology provided a simple analytical solution to laborious CE/MS interfacing methods and to problems in characterization of complex carbohydrate mixtures that require high-resolution separation of the components. The CE/ESI interface, feasible in any MS laboratory, consists of a one-piece CE column having the CE terminus in-laboratory shaped as a microsprayer and coated with copper. The CE microsprayer was inserted into an in-house made stainless steel clenching device and the whole assembly was mounted onto a quadrupole TOF mass spectrometer. The analytical potential of the interface in terms of suitability, microsprayer performance, copper coat durability, ionization efficiency, spray stability, and sensitivity was tested first on a simple mixture of standard saccharides, which were separated, resolved, and detected with high separation efficiency. The approach was next assessed for the screening of a biological sample, a complex mixture of O-glycosylated sialylated amino acids from urine of a patient suffering from Schindler disease. Preliminary data allow this method to be considered as one of general applicability in structural glycobiology and glycomics and easy to be implemented for proteomic surveys as well. 相似文献
77.
Two-component laminates made of conductors distributed non-periodically as laminas along one direction are considered in this note. The macroscopic properties of these laminates are described by continuous slowly-varying functions across laminas. In order to analyse heat conduction, the approach, called the tolerance modelling, is used. The aim of this note is to use averaged equations of the tolerance model for transversally graded laminates to analyse stationary heat conduction across laminas. (© 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
78.
79.
Alina Iacob 《代数通讯》2013,41(5):1673-1685
Let R be a left noetherian ring. We show that every complex of left R-modules has a #-injective cover. We use this result to prove that the class of DG-injective complexes is covering if and only if the ring R is regular. 相似文献
80.
Craig M. Anderson Garrett Brown Matthew W. Greenberg David Yu Nellie Bowen Rahma Ahmed Melissa Yost-Bido Alina Wray 《Tetrahedron letters》2019,60(43):151156
Several thiophene-based N^C ligands were synthesized. Strategically, a bromide was incorporated on the 2-position of the thiophene ring. When allowed to react with the platinum tetramethyl dimer, [Pt2Me4(µ-SMe2)2], platinum(IV) platinacycles were formed by oxidative addition of the C(sp2)-X bond. These platinum(IV) compounds were characterized by NMR and HRMS. The platinum (IV) compounds were subsequently subjected to thermolysis. A series of reactions occurred, including selective C-C reduction elimination and selective C-H oxidative addition, giving mixtures of platinum(II) products with varying degrees of regioselectivity. 相似文献