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991.
H. Alexander 《Mathematische Annalen》1974,209(3):249-256
992.
S. Alexander 《Solid State Communications》1974,14(11):1069-1071
It is demonstrated that phase transitions predicted to be first order by the Landau symmetry arguments can be continuous for a finite range of the physical parameters. For transitions with a rank-two tensor order parameter it is shown that fluctuations in a phase associated with the anisotropy of the tensor result in a renormalization of the cubic term. This leads to continuous transitions when the coefficient of the bare cubic term is small compared to the coefficient of the quartic term. It is shown that the argument can be extended to more general cases when the order parameter belongs to a multidimensional representation of the broken symmetry group. 相似文献
993.
Pionic atom data are refitted in terms of conventional π? nuclear optical potentials, modified to allow for finite range in the underlying p-wave πN interaction. We find that level shifts and widths in light and medium-weight nuclei cannot distinguish between the various ranges tested. In heavy nuclei, and for reasonable choices of neutron radii, the data tend to exclude ranges of order 0.5 fm and larger. 相似文献
994.
G. Alexander L. Criegee H.C. Dehne K. Derikum R. Devenish G. Flügge G. Franke Ch. Gerke E. Hackmack P. Harms G. Horlitz Th. Kahl G. Knies E. Lehmann R. Schmitz U. Timm P. Waloschek K. Wacker 《Physics letters. [Part B]》1978,78(1):162-166
The decay of the heavy lepton τ into πv has been established using the magnetic detector PLUTO. The branching ratio is determined to be BR(τ→πv)=(9.0 ± 2.9)% with an additional systematic uncertainty of 2.5%. This value is in good agreement with the theoretical prediction. 相似文献
995.
Alexander McKillop Alan Henderson Partha S. Ray Carmen Avendano Encarnacion G. Molinero 《Tetrahedron letters》1982,23(33):3357-3360
Ethyl carboethoxyformimidate is shown to be a versatile reagent for the synthesis of a variety of mono- and bicyclic heterocyclic systems. 相似文献
996.
997.
Bicyclo[3.1.0]hexane-2.3.4-trione and its 1.5-dimethyl derivative have been synthesized and investigated by means of photoelectron spectroscopy. 相似文献
998.
Shi W Shafaei-Fallah M Anson CE Rothenberger A 《Dalton transactions (Cambridge, England : 2003)》2005,(24):3909-3912
The investigation presents new synthetic methods for the generation of tripodal P/S ligands by reactions of metal alkoxides and carboxylates with the organoperthiophosphinic acid anhydride Lawesson's reagent. Four new transition-metal complexes containing various tripodal ligand sets were synthesised and characterised. 相似文献
999.
Shapir E Yi J Cohen H Kotlyar AB Cuniberti G Porath D 《The journal of physical chemistry. B》2005,109(30):14270-14274
DNA has been at the center of an imaging effort since the invention of the scanning tunneling microscope (STM). In some of the STM imaging reports the molecules appeared with negative contrast, i.e., "submerged" under the metal background and darker. We demonstrate the phenomenon of contrast inversion in DNA STM imaging by controlled and spontaneous contrast inversions and by the dependence of the DNA apparent height with respect to the surface on the imaging bias voltage. Using these characterizations, we formulate a model explaining the above phenomenon by resonant tunneling through virtual states in the vacuum between the STM tip and the DNA molecule. 相似文献
1000.
Bowker M Morgan C Perkins N Holroyd R Fourre E Grillo F MacDowall A 《The journal of physical chemistry. B》2005,109(6):2377-2386
The interaction of ethene with the Pd(110) surface has been investigated, mainly with a view to understanding the dehydrogenation reactions of the molecule and mainly using a molecular beam reactor. Ethene adsorbs with a high probability over the temperature range 130 to 800 K with the low-coverage sticking probability dropping from 0.8 at 130 K to 0.35 at 800 K. The adsorption is of the precursor type, with a weakly held form of ethene being the intermediate between the gas phase and strong chemisorption. Dehydrogenation begins at approximately 300 K and is fast above 350 K. If adsorption is carried out at temperatures up to approximately 380 K, adsorption saturates after about 0.25 monolayer have adsorbed, but above approximately 450 K, adsorption continues at a high rate with continuous hydrogen evolution and C deposition onto the surface. It appears that, in the intermediate temperature range, the carbonaceous species formed is located in the top layer and thus interferes with adsorption, whereas the C goes subsurface above 450 K, the adsorption is almost unaffected, and the C signal is significantly attenuated in XPS. However, the deposited carbon can easily be removed again by reaction with oxygen, thus implying that the carbon remains in the selvedge, that is, in the immediate subsurface region probably consisting of a few atomic layers. No well-ordered structures are identified in either LEED or STM, though some evidence of a c(2 x 2) structure can be seen. The Pd surface, at least above 450 K, appears to act as a "sponge" for carbon atoms, and this effect is also seen for the adsorption of other hydrocarbons such as acetaldehyde and acetic acid. 相似文献