Investigation of the stability of metal species with respect to liquid chromatographic separations

Summary For accurate speciation analyses it is important to know the stability of the respective species, especially in the case of metal complexes. Factors affecting the chromatographic stability of such metal species are investigated. By using thermodynamic models for complex formation and chromatographic retention equilibria the influence of species concentration, stoichiometry and excess of ligand is calculated and compared with experimental results for iron complexes (lactate, gluconate and citrate species). Iron citrate is the only species, that is chromatographed as 1:2 complex (metal: ligand), while iron lactate and gluconate are transformed to 1:1 species. Problems resulting from the coelution of different species are discussed.Dedicated to Professor Dr. Wilhelm Fresenius on the occasion of his 80th birthday     

Physical wavelets and radar: a variational approach to remotesensing

Physical wavelets are acoustic or electromagnetic waves, resulting from the emission of a time signal by a localized acoustic or electromagnetic source moving along an arbitrary trajectory in space. Thus, they are localized solutions of the wave equation or Maxwell's equations. Under suitable conditions, such wavelets can be used as “basis” functions, to construct general acoustic or electromagnetic waves. This gives a local alternative to the construction of such waves in terms of (nonlocal) plane waves, via Fourier transforms. We give a brief, self-contained introduction to physical wavelets, and apply them to remote sensing. We define the ambiguity functional, generalization of the radar and sonar ambiguity functions, which applies not only to wideband signals, but also to targets and radar platforms executing arbitrary nonlinear motions     

Pyrolysis of tertiarybutylphosphine at low pressure

The pyrolysis of tertiarybutylphosphine (TBP) has been studied in the low pressure conditions used for chemical beam epitaxy (CBE). The pyrolysis studies were carried out in low pressure reactors of two different configurations, one of which is a cracker cell designed for use in a CBE system. The reaction products were studied using a quadrupole mass spectrometer. The products observed are accounted for by a reaction mechanism involving homolysis of the parent TBP molecule to produce PH₂ and C₄H₉ radicals. These undergo subsequent reactions to form the stable products C₄H₈, PH₃ and H₂, with smaller amounts of P and P₂ being produced. The production of the sub-hydride PH₂ using this cracker cell design indicates that the use of partially cracked TBP may be a promising technique for reducing the amount of carbon incorporated into the growing epitaxial layer.     

TLC-screening of important pharmaceutical substances using fluorescence detection

Summary Observation of fluorescence reactions on TLC plates is a valuable additional tool within the scope of screening procedures for many toxicologically relevant substances commonly encountered in clinical- and forensic-toxicological analysis. The reactions are based on native fluorescence without any treatment and on reactions obtained with an approved derivatization procedure. Due to the enormous sensitivity of the fluorescence detection, the method is also applicable to very low concentrations and small amounts of biological materials. The procedures described in this article have proven their high pragmatic usefulness in many practical cases.Dedicated to Professor Dr. Wilhelm Fresenius on the occasion of his 80th birthday     

Structure of thin block copolymer films studied by X-ray reflectivity

Summary X-ray reflectivity may be used to determine the internal structure of thin polymer films. An electron density difference of 10% for polystyrene and polyisoprene is sufficient to distinguish between a random distribution of lamellae, complete orientation parallel to the substrate surface and a surface induced formation of lamellae. The disappearance of the lamellar Bragg-peaks, with heating of the film, shows the transition into the disordered state.     

Wind energy systems

Wind energy has matured to a level of development where it is ready to become a generally accepted utility generation technology. A brief discussion of this development is presented, and the operating and design principles are discussed. Alternative designs for wind turbines and the tradeoffs that must be considered are briefly compared. Development of a wind energy system and the impacts on the utility network including frequency stability, voltage stability, and power quality are discussed. The assessment of wind power station economics and the key economic factors that determine the economic viability of a wind power plant are presented     

Determination of best shortened linear codes

The quality of a block code is determined by its capability to protect data against undetectable errors and by the number of check bits that are required for that purpose. For a given number of check bits there are codes with optimum bit error detecting capability in shortened block lengths. These codes are determined and tabulated. The residual error characteristics of some of the tabulated codes are compared with those specified in ISO/CCITT or IEC standard data transmission protocols. For block lengths and bit error rates that are typical in process control applications, the residual error rate of the determined codes is more than six orders of magnitude smaller than that of codes specified by widely used standard transmission protocols     

A high-current and high-temperature 6H-SiC thyristor

A 6H-SiC thyristor has been fabricated and characterized. A forward breakover voltage close to 100 V and a pulse switched current density of 5200 A/cm² have been demonstrated. The thyristor is shown to operate under pulse gate triggering for turn-on and turn-off, with a rise time of 43 ns and a fall time of less than 100 ns. The forward breakover voltage is found to decrease by only 4% when the operating temperature is increased from room temperature to 300°C. It is found that anode ohmic contact resistance dominates the device forward drop at high current densities     

Pulsed-current duty cycle dependence of electromigration-inducedstress generation in aluminum conductors

The effect of duty cycle of pulsed dc currents on the critical length-current density product, (jl_c), was measured using the Blech-Kinsbron edge-displacement technique [Thin Solid Films 25, 327 (1975)]. Unencapsulated Al edge-displacement segments mere stressed at various duty cycles and the critical lengths, the so-called “Blech lengths”, were measured. It was found that jl_c increased with decreasing duty cycle. We measured a factor of 2.6 increase in jl_c for the 25% duty cycle as compared to dc. This duty cycle dependence of Blech length implies that electromigration resistance for an integrated circuit would be increased for small duty cycle operation by increasing the fraction of interconnects which are sub-Blech-length and are not susceptible to EM damage     

Frequency transfer function of an opto-pneumatic detector

An example of an opto-pneumatic detector's (OPD) frequency transfer function is presented for the development of an opto-pneumatic interface. The theoretical model is tested through experiments in the laboratory on a real OPD prototype. In this way many of the model's parameters are studied and evaluated, such as the dimensions of the gas chamber, the thickness of the absorbent body, and the load of the OPD. The results obtained are good and show the utility of the studies described here.