Protein unfolding events were studied by differential scanning calorimetry (DSC) for bovine serum albumin (BSA) aqueous solutions
exposed to radio-frequency radiation. No immediate effect of this radiation on thermal unfolding of BSA was observed. The
differences between irradiated and control samples have appeared during the storage of BSA solution. The irradiated samples
changed faster than non-irradiated. Our results indicated that the age-related changes were stronger for 3.5 and 5 MHz than
for 247 MHz frequency and dependent on energy power of radiation. Deconvolution of DSC traces allowed to study the effect
of radio-frequency radiation on each component transition.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
Rich polymorphism of ethosuximide compound (ETX) is described in detail using complementary thermal analysis methods. The paper shows as well the results of differential scanning calorimetry (DSC), of polarizing microscope observations (POM) and of X-ray diffraction (XRD) measurements taken using horizontal rotating capillary method. Molecular structure of ethosuximide favors appearance of a conformationally disordered (CONDIS) crystal phase CrI in its polymorphism. Ethosuximide is a good glass former, and glass of the CrI phase was observed even for 5 °C min?1 rate of cooling. Moreover, monotropic plastic crystal CrII phase was observed during heating above the CrI temperature range. 相似文献
Journal of Thermal Analysis and Calorimetry - Composite material with a gradient concentration of the metallic phase was prepared by the novel gel-centrifugal casting method. This method combines... 相似文献
Studies on the separation of calcium and neodymium ions by using ethylenediaminetetraacetic acid (H4EDTA) as a complexing agent were performed. This research was undertaken due to the possibility of H4EDTA applying to isolate rare earth elements from the solution after acidic leaching of phosphogypsum, and because of the similarity of coordination properties of calcium and lanthanides ions. The experiment was carried out in model systems containing Ca2+ and Nd3+ ions in hydrochloric or sulphuric acid. The content of calcium and neodymium metals, phase composition and thermal behaviour of the obtained products were determined by ICP-OES, FTIR, XRD and TG/DTA techniques. During the separation process, the precipitates of a light pink colour were obtained. The obtained results show that the neodymium ethylenediaminetetraacetate has been successfully formed and that the isolation of neodymium ions was more efficient in chloride medium. The precipitate included 72.2 and 3.9% of the starting amount of neodymium and calcium used in the experiment, respectively. However, in sulphates medium, these amounts were equal to 73.8 and 53.5%, respectively. Moreover, the obtained powder was polluted with sulphates. The addition of the EDTA in an excess (15%) contributed only to an increase in calcium content in the complex.
The contents of 17 elements in thirteen strawberry cultivars grown in the five districts of Southern Serbia were determined using inductively coupled plasma optical emission spectrometry (ICP-OES). The most abundant elements are K (875–1148 mg?·?kg?1 fresh weight), P (307–664 mg?·?kg?1 fresh weight), Ca (192–256 mg?·?kg?1 fresh weight), and Mg (111–189 mg?·?kg?1 fresh weight) in all samples. Strawberries were also found to be a good source of Sr (8.05–18.6 mg?·?kg?1 fresh weight) and Fe (3.09–10.4 mg?·?kg?1 fresh weight). The contents of As and Cd were below the detection limit (0.0828 mg?·?kg?1 and 0.0205 mg?·?kg?1, respectively) in all strawberry samples, while the contents of Ni, Cr, and Cu were below the recommended tolerable levels proposed by Joint Food and Agriculture Organization of the United Nations and World Health Organization Expert Committee on Food Additives, and did not a pose a health risk for the consumer. The application of Duncan’s test showed significant differences between contents of analyzed elements in all strawberry cultivars. The highest mean levels of analyzed elements were detected in strawberries grown in the Topli?ki, Jablani?ki, and P?injski districts. The spike recovery test was used to verify the accuracy of the method, and the spike recovery was in the range 93.8–107.8%. The contents of the metals in strawberry samples were also comparable with values previously reported in the literature. 相似文献
Grain boundaries in lead halide perovskite films lead to increased recombination losses and decreased device stability under illumination due to defect‐mediated ion migration. The effect of a conjugated polymer additive, poly(bithiophene imide) (PBTI), is investigated in the antisolvent treatment step in the perovskite film deposition by comprehensive characterization of perovskite film properties and the performance of inverted planar perovskite solar cells (PSCs). PBTI is found to be incorporated within grain boundaries, which results in an improvement in perovskite film crystallinity and reduced defects. The successful defect passivation by PBTI yields reduces recombination losses and consequently increases power conversion efficiency (PCE). In addition, it gives rise to improved photoluminescence stability and improved PSC stability under illumination which can be attributed to reduced ion migration. The optimal devices exhibit a PCE of 20.67% compared to 18.89% of control devices without PBTI, while they retain over 70% of the initial efficiency after 600 h under 1 sun illumination compared to 56% for the control devices. 相似文献
The initiating ability of 2-cyano-2-propyl hydroperoxide in the oxidation reaction of cumene by molecular oxygen has been investigated and compared with the initiating ability of cumene hydroperoxide.
Die Initiierungseigenschaften von 2-Cyano-2-propyl-hydroperoxid bei Oxydations-prozessen
Zusammenfassung Es wurde die Initiierungsfähigkeit des 2-Cyan-2-hydroperoxypropans in der Oxidation von Cumol mit molekularem Sauerstoff untersucht und mit der Initiierungsfähigkeit des Cumolhydroperoxids verglichen.
Thermal treatment and the addition of lithium influence the surface area of the oxides SiO2, Al2O3 and MgO. A calcination temperature 1073 K causes a significant decrease of the surface area of SiO2 and Al2O3; the same is not observed in case of MgO. Systems Li/MgO and Li/SiO2 are characterized by a much smaller specific surface area than pure oxides thermally treated at the same temperature. 相似文献
The Schiffbases 1,9-bis(2-pyrrolyl)-2,5,8-triazanona-1,8-diene (H2L1), 1,10-bis(2-pyrrolyl)-2,5,9-triazaundeca-l,9-diene (H2L2), and 1,11-bis(2-pyrrolyl)-6-methyl-2,6,10-triazaundeca-l,10-diene (H2L4) react with copper(II) nitrate or nickel(II) perchlorate in the presence of triethylamine to give new complexes [Cu(HL1,2,4)]NO3 and [Ni(HL1,2,4)]ClO4. The crystal structures of [Cu(HL2)]NO3 and [Ni(HL2)]CIO4 have been determined from single crystal diffractometer data and refined to finalR factors of 5.09 and 5.3%, respectively. Crystallographic data: [Cu(HL2)]NO3: monoclinic,P21/c,a=10.036(2),b=14.500(2),c=13.317(2) Å,=108.14(1)°,Z=4, anddc=11.427 Mg m–3; [Ni(HL2)]ClO4: monoclinic,P21/n,a=10.578(3),b=13.953(3),c=12.394(4) Å,=93.78(2)°,Z=4, anddc=1.549 Mg m–3. In both the structures the potentially pentadentate ligand (HL2)– acts as a tetradentate one leaving one pyrrole group uncoordinated. Interesting is the metal dependent sequence of the three chelate rings. While the Ni (II) ion coordinates the (HL2)– ligand to form a 5-5-6-membered ring system, the ring arrangement in the copper complex is of the 5-6-5 type. 相似文献