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191.
Huayang Zhu Robert J. Kee Jeffrey R. Engel David T. Wickham 《Proceedings of the Combustion Institute》2007,31(2):1965-1972
This paper reports the results of experimental and modeling efforts to characterize partial oxidation of methane to produce synthesis gas (H2 and CO) using metal-substituted hexaaluminate catalysts in short-contact-time reactors. Hexaaluminate catalysts offer excellent high-temperature stability compared to the equivalent metal-based catalysts. The hexaaluminates are synthesized by a metal-exchange process using alumoxane precursors that enable a wide range of metal substitutions. Of all the combinations tested, RhSr-substituted hexaaluminates yielded the best performance. The catalysts are supported on alumina porous-foam structures, which are positioned within a tube furnace to control the operating temperature. Two-stage combinations of RhSr- and Ni-substituted hexaaluminates are shown to improve conversion activity and selectivity compared to a single-catalyst system. 相似文献
192.
François Loiseau Jean-Mary Simone David Carcache Pavel Bobal Reinhard Neier 《Monatshefte für Chemie / Chemical Monthly》2007,138(2):121-129
Summary. Free radical couplings from furan, as cheap starting material, were studied in view of developing a rapid strategy en route to the synthesis of derivatives of nonactin. The chain containing the alcohol function was introduced in one or two steps
in 86% yield. For the introduction of the second chain with the ester function two different coupling methods were tested.
Starting from the advanced intermediates obtained nonactin derivatives can be prepared by catalytic hydrogenation of the furan
ring. 相似文献
193.
David Worthington 《The Journal of the Operational Research Society》1991,42(10):833-843
This paper describes work carried out with hospital consultants in Lancaster District Health Authority to develop and use computerized waiting list management models. The ‘what if?’ models produced have been found to be a very useful tool in the constructive debate about problems faced by consultants and managers, and of the options available to them. 相似文献
194.
195.
Hong-Ming Yin 《NoDEA : Nonlinear Differential Equations and Applications》2007,13(5-6):735-757
In this paper we study a phase-change problem arising from induction heating. The mathematical model consists of time-harmonic
Maxwell’s system in a quasi-stationary field coupled with nonlinear heat conduction. The enthalpy form is used to characterize
the phase-change in the material. It is shown that the problem has a global solution. Moreover, it is shown that the solution
is unique and regular in one-space dimension even with an unbounded resistivity.
This work is supported in part by a NSF grant: DMS-0102261 相似文献
196.
We analyze an infinite horizon, single product, continuous review model in which pricing and inventory decisions are made simultaneously and ordering cost includes a fixed cost. We show that there exists a stationary (s,S) inventory policy maximizing the expected discounted or expected average profit under general conditions. 相似文献
197.
David L. Applegate 《Operations Research Letters》2007,35(6):693-699
The use of floating-point calculations limits the accuracy of solutions obtained by standard LP software. We present a simplex-based algorithm that returns exact rational solutions, taking advantage of the speed of floating-point calculations and attempting to minimize the operations performed in rational arithmetic. Extensive computational results are presented. 相似文献
198.
I. Bretos J. Ricote R.J. Jiménez-Riobóo L. Pardo M.L. Calzada 《Applied Physics A: Materials Science & Processing》2007,89(4):967-973
A novel method to investigate the early formation stages of polycrystalline (Pb1-xCax)TiO3 (PCT) perovskite films by means of traditional Brillouin and micro-Brillouin spectroscopy (BS, mBS) is described in the present
work. The films were prepared by chemical solution deposition (CSD) onto oxidized (100)Si substrates and treated at temperatures
between 350–650 °C by rapid thermal processing (RTP). The elastic instability observed by Brillouin spectroscopy at the nano-structured
state of the PCT films was used here to determine their crystallization temperatures. Coexistence of different nanocrystalline
phases (e.g., pyrochlore, perovskite) in the films could also be detected by this technique. The reliability of these results
is demonstrated by complementary information obtained by X-ray diffraction (XRD) and scanning force microscopy (SFM). The
effects of the annealing temperature and of the Ca2+ content on the crystallization process of these films are also discussed.
PACS 78.35.+c; 77.84.-s; 61.82.Rx 相似文献
199.
We give a new independent self-dual 3-basis for the trivial variety with two binary operations.
Received October 24, 2006; accepted in final form January 25, 2007. 相似文献
200.
The use of phase-Doppler anemometry (PDA) to characterize the detail in-flight plasma sprayed particle behavior has been demonstrated
previously [Ma et al. Plasma Chem Plasma Process 24(1):85; 25(1):56] The present articles shows further that a direct relationship
may exist between the PDA measured particle volume flux and the coating microstructure and deposition efficiency (DE). In
the situation when the precise particle temperature information is not available, the PDA measured particle volume flux may
provide an alternative to predict quantitatively the variation of the coating microstructure and the DE. By monitoring the
in-flight particle volume flux variations, instead of the particle velocity, size and temperature individually and simultaneously,
the optimal settings of the plasma spraying parameters may also be determined conveniently. However, it is noted that the
effective applications of such approach depend largely on the particle surface morphology and the pre-determination of the
particle size range. 相似文献