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51.
52.
Mustafa Tombul Kutalmis Guven Orhan Büyükgüngr Huseyin Aktas Tahsin Nuri Durlu 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(9):m430-m432
In the title compound, poly[(μ3‐boric acid)‐μ4‐maleato‐dipotassium], [K2(C4H2O4){B(OH)3}]n, there are two independent K+ cations, one bonded to seven O atoms (three from boric acid and four from maleate), and the other eight‐coordinate via three boric acid and four maleate O atoms and a weak η1‐type coordination to the C=C bond of the maleate central C atoms. Hydrogen bonding links the boric acid ligands and maleate dianions, completing the packing structure. 相似文献
53.
Aytac Guven 《国际流体数值方法杂志》2011,66(11):1371-1382
In this study, support vector machine (SVM) is proposed as a new predictive model for pressure fluctuations beneath free jump occurring on sloping channels. The proposed model reproduces the pressure fluctuation intensity C′p in terms of normalized flow and channel section characteristics. The model variables were derived from dimensional analysis. The proposed model is calibrated and validated by using a wide range of experimental data. The SVM predicted C′p with a correlation of coefficient (CC) of 0.989 and a root mean square error (RMSE) of 0.004. Also, linear and nonlinear regression analyses are applied on the same experimental data set, and the SVM model is compared to the equations obtained from these regression analyses. CC, RMSE and average absolute deviation (Di) are used in the evaluation of performance of each model. The SVM model predicted the measured pressure fluctuations better than conventional regression equations. The results of this study reveal that the proposed SVM model can be effectively used in predicting the pressure fluctuation beneath free jump. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
54.
55.
İlke Taşçıoğlu Adem Tataroğlu Akif Özbay Şemsettin Altındal 《Radiation Physics and Chemistry》2010,79(4):457-461
The effect of γ-ray exposure on the metal–insulator–semiconductor (MIS) structures has been investigated using the electrical characteristics at room temperature. The MIS structures are irradiated with 60Co γ-ray source. The energy distribution of interface states was determined from the forward bias I–V characteristics by taking into account the bias dependence of the effective barrier height and ideality factor. The value of series resistance decreases with increasing dose. Experimental results confirmed that γ-ray irradiation have a significant effect on electrical characteristics of MIS structures. 相似文献
56.
Serap Beli Simon J. Coles Derya Davarc David B. Davies Michael B. Hursthouse Adem Kl 《Polyhedron》2007,26(18):5283-5292
Reaction of cyclophosphazene, N3P3Cl6 (1), with the sodium derivative of the fluorinated diol, 2,2,3,3,4,4-hexafluoropentane-1,5-diol (2), in THF solution at room temperature afforded five isolated products, whose structures have been characterised by X-ray crystallography and 1H, 19F and 31P NMR spectroscopy: the mono-spiro compound, N3P3Cl4(OCH2CF2CF2CF2CH2O) (3), its ansa isomer (4), a di-spiro derivative N3P3Cl2(OCH2CF2CF2CF2CH2O)2 (5), its spiro-ansa (6) isomer and the tri-spiro compound N3P3(OCH2CF2CF2CF2CH2O)3 (7). Quantitative 31P NMR measurements of the soluble portion of the reaction mixture show that in the reaction of (1) with the sodium derivative of the fluorinated pentanediol (2) there is a small preference for spiro compounds compared to ansa compounds (ratio ca. 1.3:1), similar to the analogous reaction of (1) with the sodium derivative of the fluorinated butanediol where there is a slightly greater proportion of spiro compared to ansa compounds (ratio ca. 1.5:1). The relative proportions of spiro and ansa compounds is likely to depend on the fine balance in stabilities of the different medium-sized rings in the fluorinated pentanediol (spiro, 8- and ansa, 10-membered rings) compared to the fluorinated butanediol (spiro, 7- and ansa, nine-membered rings) derivatives of cyclophosphazene. 相似文献
57.
Eylem Turan Adem Zengi̇n Tuncer Caykara 《Journal of polymer science. Part A, Polymer chemistry》2011,49(23):5116-5123
The single‐electron transfer living radical polymerization (SET‐LRP) method in the presence of chain transfer agent was used to synthesize poly(N‐isopropylacrylamide) [poly(NIPAM)] with a low molecular weight and a low polydispersity index. This was achieved using Cu(I)/2,2′‐bipyridine as the catalyst, 2‐bromopropionyl bromide as the initiator, 2‐mercaptoethanol as the chain transfer agent (TH), and N,N‐dimethylformamide (DMF) as the solvent at 90 °C. The copper nanoparticles with diameters of 16 ± 3 nm were obtained in situ by the disproportionation of Cu(I) to Cu(0) and Cu(II) species in DMF at 22 °C for 24 h. The molecular weights of poly(NIPAM) produced were significantly higher than the theoretical values, and the polydispersities were less than 1.18. The chain transfer constant (Ctr) was found to be 0.051. Although the kinetic analysis of SET‐LRP in the presence of TH corroborated the characteristics of controlled/living polymerization with pseudo‐first‐order kinetic behavior, the polymerization also exhibited a retardation period (k > ktr). The influence of molecular weight on lower critical solution temperature (LCST) was investigated by refractometry. Our experimental results explicitly elucidate that the LCST values increase slightly with decreasing molecular weight. Reversibility of solubility and collapse in response to temperature well correlated with increased molecular weight of poly(NIPAM). © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
58.
Focusing properties of an acoustic lens based on a modified triangular sonic crystal slab whose columns are aligned on concentric
arcs of equal radial distance are investigated. Capability of focusing normally-incident plane waves is demonstrated by means
of Finite Element Method. Focusing mechanisms are discussed on the basis of band structures and equifrequency contours considering
a model where triangular lattice is elongated along ΓK direction. Focusing behavior of the proposed lens is argued to arise
from negative refractions at the air-lens interfaces accompanied by index guiding in its interiors. Wavelength-order confinement
in the transverse direction is observed. Double focusing is attributed to geometrical effects and contribution of self guiding
is discussed. Possibility of occurrence of birefraction at the input face of the lens together with positive refraction at
the output face is also discussed. 相似文献
59.
Adem Zengin Ugur Tamer Tuncer Caykara 《Journal of polymer science. Part A, Polymer chemistry》2013,51(16):3420-3428
A reversible addition‐fragmentation chain transfer (RAFT) agent was directly anchored onto superparamagnetic Fe3O4 nanoparticles (SPNPs) in a simple procedure using a ligand exchange reaction of 2‐[(dodecylsulfanylcarbonylthiolsulfanyl) propionic acid] (DCPA) with oleic acid initially present on the surface of Fe3O4 nanoparticles. The DCPA‐modified SPNPs were then used for the surface‐mediated RAFT polymerization of di(ethylene glycol) ethyl ether acrylate and (oligoethylene glycol) methyl ether acrylate to fabricate structurally well‐defined hybrid SPNPs with temperature‐responsive poly[di(ethylene glycol) ethyl ether acrylate‐co‐(oligoethylene glycol) methyl ether acrylate] shell and magnetic Fe3O4 core. Evidence of a well‐controlled surface‐mediated RAFT polymerization was gained from a linear increase of number‐average molecular weight with overall monomer conversions and relatively narrow polydispersity indices of the copolymers grown from the SPNPs. The resultant hybrid nanoparticles exhibited superparamagnetic property with a saturation magnetization of 55.1–19.4 emu/g and showed a temperature‐responsive phenomenon as the temperature changed between 25 and 40 °C. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 3420–3428 相似文献
60.
Anderson T. Guven I. Madenci E. Gustafsson G. 《Components and Packaging Technologies, IEEE Transactions on》2000,23(3):516-520
There are several different constitutive relations for describing the creep behavior of solder to predict the fatigue life of a solder joint. The differences among these constitutive relations for fatigue life prediction of electronic packages are unknown because analysts using finite element programs such as ABAQUS or ANSI'S are generally limited to specific built-in material models. The objective of this study is to implement a procedure that allows the use of various creep models in the analysis of electronic packages using ANSYS. Special user routines are developed so the user can incorporate virtually any creep relation and determine the inelastic strain energy density developed in the three-dimensional solid elements. Comparisons are performed for the modified creep routines and the viscoplastic formulation of Anand's model in ANSYS. It is found that the scheme used by ANSYS to determine plastic work density is incorrect and will be remedied in a future release. The implications of this revision to ANSYS are critical because a change in scheme will make comparisons with past studies and analyses difficult. The value of the empirical parameters based on previous analyses, which are widely used in the prediction of package fatigue life, will have to be reexamined 相似文献