Nature of the stable oxide layer formed on an aluminum surface by work function measurements

The interaction of oxygen with clean aluminum results in formation of a stable oxide layer on the surface of the metal. This stable layer has a lower work function than that of clean aluminum. The nature of this stable layer is studied by measurement of work function changes. Heating of the stable layer, formed at room temperature and low oxygen pressures' (~10^?8 torr), in ultra-high vacuum resulted in a further decrease in the work function. The extent of this additional decrease was a function of temperature and the changes in work function caused by heating were irreversible in nature. At high oxygen pressures (p_O2 > 10^?2 torr) the effect of growth of incorporated oxide on the net limiting work function change appears to be small and the reversible changes in the work function are mainly a result of the variation in the amount of surface oxide. At 250°C, the contribution of incorporated oxide to net limiting work function change was dependent on oxygen pressure when it was formed at low oxygen pressures (P < 10^?7 torr). However, when the incorporated oxide was formed at oxygen pressures above 10^?7 torr, its contribution to the limiting work function change and, perhaps, the structure of the incorporated oxide itself were nearly independent of oxygen pressure. The difference in limiting work function change at various oxygen pressures was mainly because of the difference in the limiting amounts of surface oxide. Similar behavior is expected at room temperature.     

Saturated-absorption spectroscopy with low-power difference-frequency radiation

We report high-resolution saturated-absorption spectra recorded by use of a few microwatts of radiation generated in a single pass by difference-frequency mixing. These results were obtained without the use of buildup cavities for the nonlinear mixing or for the saturation spectroscopy. We show high-quality saturated-absorption signals for the fundamental rovibrational band of CO(2) near 4.3 mum. Convenient sources and frequency-conversion devices open new possibilities for sub-Doppler spectroscopy in the infrared.     

Regenerative chemical biology: current challenges and future potential

The enthusiasm surrounding the clinical potential of embryonic stem cells (ESCs) and induced pluripotent stem cells (iPSCs) is tempered by the fact that key issues regarding their safety, efficacy, and long-term benefits have thus far been suboptimal. Small molecules can potentially relieve these problems at major junctions of stem cell biology and regenerative therapy. In this review we will introduce recent advances in these important areas and the first generation of small molecules used in the regenerative context. Current chemical biology studies will provide the archetype for future interdisciplinary collaborations and improve clinical benefits of cell-based therapies.     

1H, 13C and 15N NMR spectral assignments of adenosine derivatives with different amino substituents at C6-position

The complete (1)H, (13)C and (15)N NMR signals assignment of adenosine derivatives differently substituted at C(6)-position was achieved using one- and two-dimensional experiments (gs-COSY, gs-NOESY, gs-HSQC and gs-HMBC).     

Synthesis of highly stable silver nanoparticles by photoreduction and their size fractionation by phase transfer method

In this report we demonstrate a green chemical approach for the synthesis of stable silver nanoparticles in aqueous medium using tyrosine as an efficient photoreducing agent. A narrow size distribution of silver nanoparticles can be achieved by this simple photoirradiation method without using any additional stabilizing agents or surfactants. Two different irradiation sources have been explored resulting in a different particle size distribution pattern in each case. Further, we show that starting from a polydisperse tyrosine synthesized silver nanoparticles sample, it is also possible to fractionate them into different size ranges. The size fractionation was achieved by a 2 stage phase transfer method employing different organic solvents. The nanoparticles synthesized were characterized using UV-vis spectroscopy, Transmission electron microscopy (TEM) and X-ray diffraction (XRD) techniques.     

A single machine scheduling problem with availability constraints and sequence-dependent setup costs

We study a single machine scheduling problem with availability constraints and sequence-dependent setup costs, with the aim of minimizing the makespan. To the authors’ knowledge, this problem has not been treated as such in the operations research literature. We derive in this paper a mixed integer programming model to deal with such scheduling problem. Computational tests showed that commercial solvers are capable of solving only small instances of the problem. Therefore, we propose two ways for reducing the execution time, namely a valid inequality that strengthen the linear relaxation and an efficient heuristic procedure that provides a starting feasible solution to the solver. A substantial gain is achieved both in terms of the linear programming relaxation bound and in terms of the time to obtain an integer optimum when we use the enhanced model in conjunction with providing to the solver the solution obtained by the proposed heuristic.     

Representations of MV‐algebras by sheaves

In this paper, inspired by methods of Bigard, Keimel, and Wolfenstein ([2]), we develop an approach to sheaf representations of MV‐algebras which combines two techniques for the representation of MV‐algebras devised by Filipoiu and Georgescu ([18]) and by Dubuc and Poveda ([16]). Following Davey approach ([12]), we use a subdirect representation of MV‐algebras that is based on local MV‐algebras. This allowed us to obtain: (a) a representation of any MV‐algebras as MV‐algebra of all global sections of a sheaf of local MV‐algebras on the spectruum of its prime ideals; (b) a representation of MV‐algebras, having the space of minimal prime ideals compact, as MV‐algebra of all global sections of a Hausdorff sheaf of MV‐chains on the space of minimal prime ideals, which is a Stone space; (c) an adjunction between the category of all MV‐algebras and the category of MV‐algebraic spaces, where an MV‐algebraic space is a pair (X, F), where X is a compact topological space and F is a sheaf of MV‐algebras with stalks that are local (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)