全文获取类型
收费全文 | 317篇 |
免费 | 7篇 |
国内免费 | 1篇 |
专业分类
化学 | 152篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 47篇 |
物理学 | 103篇 |
无线电 | 20篇 |
出版年
2022年 | 5篇 |
2021年 | 12篇 |
2020年 | 4篇 |
2018年 | 2篇 |
2017年 | 6篇 |
2016年 | 2篇 |
2015年 | 6篇 |
2014年 | 4篇 |
2013年 | 20篇 |
2012年 | 14篇 |
2011年 | 23篇 |
2010年 | 11篇 |
2009年 | 14篇 |
2008年 | 14篇 |
2007年 | 12篇 |
2006年 | 18篇 |
2005年 | 18篇 |
2004年 | 7篇 |
2003年 | 17篇 |
2002年 | 20篇 |
2001年 | 8篇 |
2000年 | 7篇 |
1999年 | 3篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 4篇 |
1989年 | 3篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1976年 | 5篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1972年 | 3篇 |
1969年 | 1篇 |
1968年 | 2篇 |
1966年 | 1篇 |
1961年 | 1篇 |
1956年 | 2篇 |
1955年 | 1篇 |
1940年 | 1篇 |
1937年 | 1篇 |
1928年 | 1篇 |
排序方式: 共有325条查询结果,搜索用时 15 毫秒
1.
Minh Lequan Rose Marie Lequan Kathleen Chane-ching Anne-claude Callier Marguerite Barzoukas Alain Fort 《Advanced functional materials》1992,1(5):243-247
Samples of {4-(dimethylamino) stilben Z & E 4'-yl} dimesityl borane (BNS) were synthesised and investigated for their non-linear optical properties. The results show that the quadratic hyperpolarisability of the Z-isomer is smaller than that of the E-isomer, the beta value found for the latter being as high as 60 × 10?30 esu. 相似文献
2.
Ada Bottaro Aruffo 《Annali di Matematica Pura ed Applicata》1986,145(1):211-263
Summary
In this work we consider the problem ()of the minimum for integral functionals I
f
of the Calculus of Variations, where we don't suppose any hypothesis of convexity on the integrand and in which the state takes values in a Suslin metric space, while the last variable of the integrand is in a separable reflexive Banach space. We study two different types of relaxed problems, associated to (),and we prove that the infima of the three functionals considered are the same, that (),one of the relaxed problems, has solution and that the accumulation points of the minimizing sequences for ()are the only solutions of ().
Lavoro eseguito nell'ambito dell'Istituto per la Matematica Applicata del C.N.R., Genova. 相似文献
Lavoro eseguito nell'ambito dell'Istituto per la Matematica Applicata del C.N.R., Genova. 相似文献
3.
Polyethylene glycols (PEG) are fair solvents for inorganic salts and organic substrates; their use in some organic reactions is described. 相似文献
4.
Sergio Auricchio Ada M. Truscello Mirvana Lauria Stefano V. Meille 《Tetrahedron》2012,68(36):7441-7449
2H-Azirines were found to react with imines, enaminones and enaminoesters in the presence of metal salts. Imidazoles, pyrroles and new pyrrolinones derivatives are isolated in good overall yields. The role of metal salts was investigated as they can act as Lewis acids or electron donors. Mechanisms are proposed suggesting that imidazoles arise from addition of azirine to imines via radical or ionic mechanism; pyrroles and pyrrolinones are obtained from azirines with enamino derivatives when the salt acts as a Lewis acid. In the latter case the properties of the metallic compound influence the reaction regioselectivity. 相似文献
5.
Dr. Benoît Bertrand Dr. Candice Botuha Jérémy Forté Dr. Héloïse Dossmann Dr. Michèle Salmain 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(56):12846-12861
The two independent and coordination sites of a newly synthesized bis[2-(hydroxyphenyl)-1,2,4-triazole] platform have been exploited to prepare four monometallic neutral ()PtII complexes carrying DMSO, pyridine, triphenylphosphine, or N-heterocyclic carbene as the fourth ligand. Then, the second coordination site was used to introduce an IR-active rhenium tricarbonyl entity, affording the four corresponding heterobimetallic neutral PtII/ReI complexes, as well as a cationic PtII/ReI derivative. X-ray crystallographic studies showed that distortion of the organic platform occurred to accommodate the coordination geometry of both metal centers. No ligand exchange or transchelation occurred upon incubation of the PtII complexes in aqueous environment or in the presence of FeIII, respectively. The antiproliferative activity of the ligand and complexes was first screened on the triple-negative breast cancer cell line MDA-MB-231. Then, the IC50 values of the most active candidates were determined on a wider panel of human cancer cells (MDA-MB-231, MCF-7, and A2780), as well as on a nontumorigenic cell line (MCF-10A). Low micromolar activities were reached for the complexes carrying a DMSO ligand, making them the first examples of highly active, but hydrolytically stable, PtII complexes. Finally, the characteristic mid-IR signature of the {Re(CO)3} fragment in the Pt/Re heterobimetallic complexes was used to quantify their uptake in breast cancer cells. 相似文献
6.
Brown SD Strange P Bouchenoire L Zarychta B Thompson PB Mannix D Stockton SJ Horne M Arola E Ebert H Szotek Z Temmerman WM Fort D 《Physical review letters》2007,99(24):247401
We report measured dipolar asymmetry ratios at the LIII edges of the heavy rare-earth metals. The results are compared with a first-principles calculation and excellent agreement is found. A simple model of the scattering is developed, enabling us to reinterpret the resonant x-ray scattering in these materials and to identify the peaks in the asymmetry ratios with features in the spin and orbital moment densities. 相似文献
7.
T. Solouki R. C. Fort A. Alomary A. Fattahi 《Journal of the American Society for Mass Spectrometry》2001,12(12):1409-1285
We utilized gas phase hydrogen/deuterium (H/D) exchange reactions and ab initio calculations to investigate the complexation between a model peptide (Arg-Gly-AspRGD) with various alkali metal ions. The peptide conformation is drastically altered upon alkali metal ion complexation. The associated conformational changes depend on both the number and type of complexing alkali metal ions. Sodium has a smaller ionic diameter and prefers a multidentate interaction that involves all three amino acids of the peptide. Conversely, potassium and cesium form different types of complexes with the RGD. The [RGD + 2Cs − H]+ species exhibit the slowest H/D exchange reactivity (reaction rate constant of 6 × 10−13 cm3molecule−1s−1 for the fastest exchanging labile hydrogen with ND3). The reaction rate constant of the protonated RGD is two orders of magnitude faster than that of the [RGD + 2Cs − H]+. Addition of the first cesium to the RGD reduces the H/D exchange reaction rate constant (i.e., D0) by a factor of seven whereas sodium reduces this value by a factor of thirty. Conversely, addition of the second alkali metal ions has the opposite effect; the rate of D0 disappearance for all [RGD + 2Met − H]+ species (MetNa, K, and Cs) decreases with the alkali metal ion size. 相似文献
8.
The use of an in situ generated Ni(0) catalyst associated with 2,2'-bipyridine or N,N'-bis(2,6-diisopropylphenyl)dihydroimidazol-2-ylidene (SIPr) as a ligand and NaO-t-Bu as the base for the intramolecular coupling of aryl chlorides with amines is described. The procedure has been applied to the formation of five-, six-, and seven-membered rings. [reaction: see text] 相似文献
9.
Fort S Birikaki L Dubois MP Antoine T Samain E Driguez H 《Chemical communications (Cambridge, England)》2005,(20):2558-2560
Oligosaccharidic moieties of GM(2) and GM(3) gangliosides bearing an allyl or a propargyl aglycon, are efficiently biosynthesized on the gram scale by growing metabolically engineered Escherichia coli cells in the presence of the corresponding lactoside acceptors and sialic acid. 相似文献
10.
Dr. Nguyet Trang Thanh Chau Maxime Meyer Dr. Shinsuke Komagawa Dr. Floris Chevallier Prof. Yves Fort Prof. Masanobu Uchiyama Prof. Florence Mongin Dr. Philippe C. Gros 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(41):12425-12433
Homoleptic lithium tri‐ and tetraalkyl zincates were reacted with a set of bromopyridines. Efficient and chemoselective bromine–metal exchanges were realized at room temperature with a substoichiometric amount of nBu4ZnLi2?TMEDA reagent (1/3 equiv; TMEDA=N,N,N′,N′‐tetramethylethylenediamine). This reactivity contrasted with that of tBu4ZnLi2?TMEDA, which was inefficient below one equivalent. DFT calculations allowed us to rationalize the formation of N???Li stabilized polypyridyl zincates in the reaction. The one‐pot difunctionalization of dibromopyridines was also realized using the reagent stoichiometrically. The direct creation of C? Zn bonds in bromopyridines enabled us to perform efficient Negishi‐type cross‐couplings. 相似文献