Simultaneous voltammetric determination of ascorbic acid and dopamine at the surface of electrodes modified with self-assembled gold nanoparticle films

Gold nanoparticles (GNs) could be efficiently immobilized on binary mixed self-assembled monolayers (SAMs) on a gold surface composed of 1,6-hexanedithiol and 1-octanethiol (nano-Au/SAMs gold electrode). This GN chemically modified electrode was used for electrochemical determination of ascorbic acid (AA) and dopamine (DA) in aqueous media. The result showed that the GN-modified electrode could clearly resolve the oxidation peaks of AA and DA, with a peak-to-peak separation (∆E _p) of 110 mV enabling determination of AA and DA in the presence of each other. The linear analytical curves were obtained in the ranges of 0.3–1.4 mM for AA and 0.2–1.2 mM for DA concentrations using differential pulse voltammetry. The detection limits (3σ) were 9.0 × 10⁻⁵ M for AA and 9.0 × 10⁻⁵ M for DA.     

Fuzzy pricing,marketing and service planning in a fuzzy inventory model: A geometric programming approach

In the real world markets, demand is influenced by different parameters. Recently, many researchers have been interested in integrated production and marketing planning strategies in inventory models where demand depends on different parameters such as price and/or marketing expenditure. The quality of services that are offered to customers of a product is one of the most important parameters that affects demand in the real markets and has not been considered in development of inventory models. On the other hand, the cost parameters in real inventory systems and other parameters such as price, marketing and service elasticity to demand are imprecise and uncertain in nature. So, the notion of fuzziness can be applied to cope with this uncertainty. In this paper, a new fuzzy profit maximization inventory model with shortages is proposed. The demand is considered as a power function of price, marketing expenditure and service expenditure. Furthermore, unit cost is determined as a power function of order quantity. Since the proposed model is in a fuzzy environment, a fuzzy decision should be made to meet the decision criteria, and the results should be fuzzy. Therefore, the proposed model is formulated and solved using geometric programming and fuzzy optimization techniques to derive an approximation of the results’ membership functions. The model is illustrated with a numerical example and finally a case study is provided for evaluation and validation of the results of model.     

One‐Pot stereoselective synthesis of trans‐4,5‐dialkoxy‐1,3‐bis (2‐pyrimidinyl)imidazolidines through a three‐component reaction

Stoichiometric reaction of 2‐aminopyrimidine with formaldehyde in the presence of formic acid catalyst in water gave N,N′‐bis(2‐pyrimidinyl)methanediamine ( 5 ). Subsequent cyclocondensation of 5 with glyoxal in alcohol (MeOH, EtOH, PrOH and i‐PrOH) under reflux conditions led to the formation of the corresponding 4,5‐dialkoxy‐1,3‐bis(2‐pyrimidinyl)imidazolidines ( 6a‐d ). 4,5‐Dihydroxy‐1,3‐bis(2‐pyrimidinyl) imidazolidine ( 6e ) was obtained when the reaction was carried out in acetonitrile. Based on ¹H NMR analysis, it was found that the trans‐dialkoxyimidazolidines ( 6 ) were selectively obtained in these cyclocondensation reactions.     

Wide range pH measurements using a single H(+)-selective chromoionophore and a time-based flow method

A hydrophilic transparent triacetyl cellulose membrane was adopted as a pH optode by immobilizing highly selective and sensitive Nile blue indicator on the membrane. Contrary to the common procedure for determinations using optodes, in which a steady state response is measured, a new approach is introduced in which the dynamic response of the optode is used as the analytical signal. While in common procedures, pH optodes exhibit limited linear dynamic range (often 2–4 pH units only), it is shown that in a time-based flow method, an optode with only one acid-base indicator can be used for measurement in the pH range of 0–10. The procedure is simple, inexpensive and rapid.     

Modeling and Stimulating Node Cooperation in Wireless Ad Hoc Networks

In wireless networks, cooperation is necessary for many protocols, such as routing, clock synchronization, and security. It is known that cooperator nodes suffer greatly from problems such as increasing energy consumption. Therefore, rational nodes have no incentive to cooperatively forward traffic for others. A rational node is different from a malicious node. It is a node that makes the best decision in each state (cooperate or non‐cooperate). In this paper, game theory is used to analyze the cooperation between nodes. An evolutionary game has been investigated using two nodes, and their strategies have been compared to find the best one. Subsequently, two approaches, one based on a genetic algorithm (GA) and the other on learning automata (LA), are presented to incite nodes for cooperating in a noisy environment. As you will see later, the GA strategy is able to disable the effect of noise by using a big enough chromosome; however, it cannot persuade nodes to cooperate in a noise‐free environment. Unlike the GA strategy, the LA strategy shows good results in a noise‐free environment because it has good agreement in cooperation‐based strategies in both types of environment (noise‐free and noisy).     

Solvent- and Catalyst-Free Synthesis of New Unsymmetrical Multidentate Thio-bis-aminophenol Ligands by Mannich Condensation

A one-pot, three-component, Mannich condensation of electron-rich aromatic compounds such as 5-methyl-2-hydroxyphenyl sulfide, 2-aminopyrimidine, and various aromatic aldehydes were used to prepare a series of new unsymmetrical multidentate aminophenol ligands. These compounds were synthesized in solvent-free conditions as a fast, simple, convenient, and uncatalyzed method. Details of the reaction conditions are discussed.     

High electrochemical stability of polyvinylidene fluoride (PVDF) porous membranes using phase inversion methods for lithium-ion batteries

Journal of Solid State Electrochemistry - Polyvinylidene fluoride (PVDF) porous membranes were prepared by non-solvent-induced phase separation (NIPS) method. The membranes were made by different...     

Simple and Efficient Procedure for the Synthesis of Symmetrical Bis-Schiff Bases of 5,5′-Methylenebis(2-aminothiazole) Under Solvent-Free Conditions

A simple and efficient procedure for the synthesis of symmetrical bis-Schiff bases has been described that employs a condensation reaction of symmetrical primary bis-amine of 5,5′-methylenebis(2-aminothiazole) with a series of aromatic aldehyde derivatives under solvent-free conditions at elevated temperature. The advantages of these reactions are simplicity of the reaction procedure, short reaction times, simple workup, catalyst-free conditions, and pure products in good to excellent yields. Details of the reaction conditions are discussed.