全文获取类型
收费全文 | 10028篇 |
免费 | 1866篇 |
国内免费 | 1742篇 |
专业分类
化学 | 4835篇 |
晶体学 | 163篇 |
力学 | 442篇 |
综合类 | 85篇 |
数学 | 609篇 |
物理学 | 3066篇 |
无线电 | 4436篇 |
出版年
2024年 | 57篇 |
2023年 | 212篇 |
2022年 | 333篇 |
2021年 | 416篇 |
2020年 | 396篇 |
2019年 | 414篇 |
2018年 | 316篇 |
2017年 | 397篇 |
2016年 | 506篇 |
2015年 | 573篇 |
2014年 | 651篇 |
2013年 | 779篇 |
2012年 | 878篇 |
2011年 | 858篇 |
2010年 | 721篇 |
2009年 | 756篇 |
2008年 | 753篇 |
2007年 | 761篇 |
2006年 | 685篇 |
2005年 | 579篇 |
2004年 | 437篇 |
2003年 | 336篇 |
2002年 | 319篇 |
2001年 | 291篇 |
2000年 | 247篇 |
1999年 | 182篇 |
1998年 | 115篇 |
1997年 | 87篇 |
1996年 | 100篇 |
1995年 | 66篇 |
1994年 | 67篇 |
1993年 | 58篇 |
1992年 | 63篇 |
1991年 | 43篇 |
1990年 | 44篇 |
1989年 | 35篇 |
1988年 | 16篇 |
1987年 | 13篇 |
1986年 | 19篇 |
1985年 | 7篇 |
1984年 | 6篇 |
1983年 | 7篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1979年 | 5篇 |
1978年 | 5篇 |
1977年 | 4篇 |
1974年 | 2篇 |
1971年 | 2篇 |
1964年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
41.
介绍了EV-DO RevB技术两个阶段的不同特点和优势,阐述了在EV-DO RevB网络升级的策略,并针对热点、室内、郊区等不同的场景提出了Ev-DO RevB进行网络部署的组网建议. 相似文献
42.
43.
本文首先对过欠压保护器硬件进行了设计,包括电源电路、采集电路和磁保持单线圈继电器驱动电路。随后用IAR visualSTATE状态机软件对整个系统软件进行了设计,编写了输入输出相关事件和动作的API接口函数代码。IAR visualSTATE可以自行产生代码,ROM、RAM消耗量小,非常适宜嵌入式应用,开发完成后可以生成相关文档,便于日后软件维护和升级,大大缩小产品上市时间。 相似文献
44.
Hankun Zhou Si Chen Ning Gan Tianhua Li Yuting Cao Qianli Jiang 《Electroanalysis》2013,25(10):2384-2393
A novel sandwich‐type electrochemiluminescence (ECL) immunosensor was developed to enable the sensitive detection of HIV‐1 antibodies. This system incorporated mesoporous silica (mSiO2) complexed with quantum dots (QDs) and nano‐gold particles, which were assembled to enhance signal detection. Magnetic beads were used by immobilizing the secondary anti‐IgG antibody. This was first employed to capture HIV‐1 antibody (Ab) to form a Fe3O4/anti‐IgG/Ab complex. A high loading and signal‐enhanced nanocomposite (hereafter referred to as Au‐mSiO2‐CdTe) was used as a HIV‐1 antigen label. The Au‐mSiO2‐CdTe nanocomposite was conjugated with the Fe3O4/anti‐IgG/Ab complex to form an immunocomplex (hereafter referred to as Fe3O4/anti‐IgG/Ab/HIV‐1/CdTe‐mSiO2‐Au). This complex could be further separated by an external magnetic field to produce ECL signals. Due to the large specific surface area and pore volume of mSiO2, the loading of the CdTe QDs was markedly increased. Thus, the loaded QDs released a powerful chemiluminescent signal with a concordantly increased sensitivity of the immunosensor. The immunosensor was highly sensitive, and displayed a linear range of responses for HIV‐1 antibody across a dilution range of 1 : 1500 through 1 : 50 with the detection limit of 1 : 4500. The immunoassay can be a promising candidate in early diagnosis of HIV infection. 相似文献
45.
Ya Gao Nan Chen Weiwu Hu Chuanping Feng Baogang Zhang Qian Ning Bin Xu 《Journal of solution chemistry》2013,42(4):691-704
Adsorption is an effective treatment process for removing phosphorus and thus controlling eutrophication. In this study, a clay composite material called Al–dolomite–montmorillonite (Al–DM) was prepared and characterized. Al–DM performed well with respect to phosphate removal, with its performance depending on the Al–DM loading, contact time, initial phosphorus concentration and initial solution pH. Adsorption mechanisms were investigated by conducting batch tests on phosphate adsorption using the Al–DM. The adsorption process fitted both the pseudo-second-order kinetics model and the intra-particle diffusion model. The Langmuir, Freundlich and BET models all adequately described the adsorption isotherm data. Thermodynamic studies showed that the adsorption process was endothermic and spontaneous in nature. Al–DM is an effective adsorbent for phosphate removal mainly due to its hierarchical porous structures as shown by characterization with SEM and EDS. Chemical changes occurring before and after adsorption in a water environment indicated that Al–DM had little negative effect on water quality. 相似文献
46.
建立体积排阻色谱-电感耦合等离子体质谱(SEC-HPLC-ICP-MS)联用技术分析富硒大米含硒蛋白组成方法。通过水提、盐提、碱提和醇提方法提取,并用丙酮沉淀蛋白,硒的回收率分别为9.6%,16.8%,48.2%和14.9%,纯化后的蛋白结合硒的量由大到小依次为碱溶谷蛋白>球蛋白>醇溶蛋白>清蛋白。蛋白液经SEC-HPLC-ICP-MS检测,通过蛋白色谱峰(λ=280 nm)和ICP-MS硒峰(78Se)对比分析,利用分子量标准曲线测定出4类蛋白中含硒蛋白的分子量。结果表明,富硒大米中清蛋白和醇溶蛋白并不是硒的主要存在蛋白。硒主要存在于>7 kDa的碱溶谷蛋白和球蛋白,其中碱溶含硒蛋白主要组分F1分子量为199.8 kDa。 相似文献
47.
Conghui Tang Ning Jiao 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(25):6646-6650
A novel copper‐catalyzed aerobic oxidative C(CO) C(alkyl) bond cleavage reaction of aryl alkyl ketones for C N bond formation is described. A series of acetophenone derivatives as well as more challenging aryl ketones with long‐chain alkyl substituents could be selectively cleaved and converted into the corresponding amides, which are frequently found in biologically active compounds and pharmaceuticals. 相似文献
48.
Jia-chang Zhuang Yi-Hua Zhang Ning Song Yu-hui Tan Yun-zhi Tang Yan-Le Huang Hao Zhang Yu-kong Li 《化学:亚洲杂志》2022,17(1):e202101134
Cyclic organic amines are emerging as excellent building blocks to assemble organic–inorganic hybrid phase transition materials due to their flexible cyclic structure. Here, we have assembled a 1D organic-inorganic hybrid dielectric material C5H6NOPbBr3 ( 1 ) by alloying the cyclic organic amine 3-hydroxypyridine. 1 displays a remarkable switchable dielectric response induced by an order-disorder transformation of the organic moiety, this transformation behaviour is confirmed by DSC and Hirshfeld surface measurements. More interestingly, 1 has a narrowband emission (FWHM=4.64 nm) at 590 nm; FWHM is a major quality figure for narrowband photodetectors. In addition, 1 exhibits semiconducting properties with an indirect bandgap of 2.78 eV by the analysis of the UV-Vis absorption results. 相似文献
49.
Ning Liang Yuk-Man Li Zouyan He Wangjun Hao Yimin Zhao Jianhui Liu Hanyue Zhu Erika Kwek Ka-Ying Ma Wen-Sen He Zhen-Yu Chen 《Molecules (Basel, Switzerland)》2021,26(12)
Rutin (R) and quercetin (Q) are two widespread dietary flavonoids. Previous studies regarding the plasma cholesterol-lowering activity of R and Q generated inconsistent results. The present study was therefore carried out to investigate the effects of R and Q on cholesterol metabolism in both HepG2 cells and hypercholesterolemia hamsters. Results from HepG2 cell experiments demonstrate that both R and Q decreased cholesterol at doses of 5 and 10 µM. R and Q up-regulated both the mRNA and protein expression of sterol regulatory element binding protein 2 (SREBP2), low-density lipoprotein receptor (LDLR), and liver X receptor alpha (LXRα). The immunofluorescence study revealed that R and Q increased the LDLR expression, while only Q improved LDL-C uptake in HepG2 cells. Results from hypercholesterolemia hamsters fed diets containing R (5.5 g/kg diet) and Q (2.5 g/kg diet) for 8 weeks demonstrate that both R and Q had no effect on plasma total cholesterol. In the liver, only Q reduced cholesterol significantly. The discrepancy between the in vitro and in vivo studies was probably due to a poor bioavailability of flavonoids in the intestine. It was therefore concluded that R and Q were effective in reducing cholesterol in HepG2 cells in vitro, whereas in vivo, the oral administration of the two flavonoids had little effect on plasma cholesterol in hamsters. 相似文献
50.
Dr. Xinghai Ning Dr. Wonewoo Seo Dr. Seungjun Lee Dr. Kiyoko Takemiya Dr. Mohammad Rafi Dr. Xuli Feng Dr. Daiana Weiss Dr. Xiaojian Wang Larry Williams Vernon M. Camp Malveaux Eugene Prof. W. Robert Taylor Prof. Mark Goodman Prof. Niren Murthy 《Angewandte Chemie (International ed. in English)》2014,53(51):14096-14101
A positron emission tomography (PET) tracer composed of 18F‐labeled maltohexaose (MH18F) can image bacteria in vivo with a sensitivity and specificity that are orders of magnitude higher than those of fluorodeoxyglucose (18FDG). MH18F can detect early‐stage infections composed of as few as 105 E. coli colony‐forming units (CFUs), and can identify drug resistance in bacteria in vivo. MH18F has the potential to improve the diagnosis of bacterial infections given its unique combination of high specificity and sensitivity for bacteria. 相似文献