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21.
22.
M. C. Jones 《Annals of the Institute of Statistical Mathematics》2004,56(4):733-742
A simple new family of distributions is proposed which has support the unit disc in two dimensions. The density functions
of the family are unimodal, monotonic or uniantimodal. The bivariate symmetric beta distributions, which include the uniform
distribution, are special cases, but many members of the family are skew. The distributions have three parameters, one controlling
orientation, one controlling degree of concentration and the third controlling skewness, or more precisely off-centredness.
Importantly, these parameters are globally orthogonal. An illustrative example of fitting the model to data is given. Conditional
and marginal distributions are considered. The new distributions are compared favourably with an earlier suggestion of the
same author. 相似文献
23.
N. A. A. Rossi R. G. Jones S. J. Holder 《Journal of polymer science. Part A, Polymer chemistry》2003,41(1):30-40
ABA block copolymers of methyl methacrylate and methylphenylsilane were synthesized with a methodology based on atom transfer radical polymerization (ATRP). The reaction of samples of α,ω‐dihalopoly(methylphenylsilane) with 2‐hydroxyethyl‐2‐methyl‐2‐bromoproprionate gave suitable macroinitiators for the ATRP of methyl methacrylate. The latter procedure was carried out at 95 °C in a xylene solution with CuBr and 2,2‐bipyridine as the initiating system. The rate of the polymerization was first‐order with respect to monomer conversion. The block copolymers were characterized with 1H NMR and 13C NMR spectroscopy and size exclusion chromatography, and differential scanning calorimetry was used to obtain preliminary evidence of phase separation in the copolymer products. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 30–40, 2003 相似文献
24.
A comparison of a theoretical model for quasi-statically and dynamically induced environmental vibration from trains with measurements 总被引:1,自引:0,他引:1
This paper presents comparisons between a theoretical ground vibration model and measured data at three sites. The model, which is briefly outlined here, encompasses both the quasi-static and dynamic mechanisms of excitation. The vertical dynamics of a number of vehicles travelling at a constant speed on an infinite track are coupled to a semi-analytical model for a three-dimensional layered ground. This model is also used to demonstrate the roles of the two components of vibration at different frequencies and for train speeds below and above the lowest ground wave speed. It is found that, in most practical cases, the dynamic component gives rise to the higher level of vibration. 相似文献
25.
26.
The proportional-bandwidth and constant-bandwidth time-frequency signal decompositions of the wavelet, Gabor, and Wilson orthonormal bases have attracted substantial interest for representing nonstationary signals. However, these representations are limited in that they are based on rectangular tessellations of the time-frequency plane. While much effort has gone into methods for designing nice wavelet and window functions for these frameworks, little consideration has been given to methods for constructing orthonormal bases employing nonrectangular time-frequency tilings. The authors take a first step in this direction by deriving two new families of orthonormal bases and frames employing elements that shear, or chirp, in the time-frequency plane, in addition to translate and scale. The new scale-shear fan bases and shift-shear chevron bases are obtained by operating on an existing: wavelet, Gabor (1946), or Wilson basis set with two special unitary warping transformations. In addition to the theoretical benefit of broadening the class of valid time-frequency plane tilings, these new bases could possibly also be useful for representing certain types of signals, such as chirping and dispersed signals 相似文献
27.
A fundamental research of structural defects induced upon post-growth processing of ZnSe/GaAs epilayers grown on (100) GaAs
was done by identifying defect-related reflections in the transmission electron diffraction (TED) patterns of ZnSe. Structural
artifacts, other than the as-grown defects, on this material system could be excluded according to our results. Four types
of abnormal reflections have been observed in addition to primary reflections. These extra reflections are sensitive to the
post-growth processing of ZnSe epilayers and may arise from various external effects, rather than epitaxy growth, such as
irradiation damage, surface oxidation, and surface contamination. By mapping these reflections at several major zone axes
using TED patterns, we found that the reciprocal lattice for a ZnSe crystal with structural defects consists of two distinct
types of extra reflections associated with irradiation damage. The first type of extra reflections is ±1/3{111} and the other
is ±1/2{111} corresponding to pure-edge and non-edge dislocation loops, respectively. For (100) oriented wafers, the ±1/3{111}
and ±1/2{111} reflections were observed only on two of the four possible 〈111〉 variants (i.e. [111]Zn and [111]Zn)and this phenomenon was attributed to the anisotropy of defect distribution. Extra reflections associated with surface oxidation
and contamination are also observed. The orientation relationships between a surface hexagonal ZnO and a cubic ZnSe film are
[0001]ZnO//[−111]ZnSe, and [01−11]ZnO//[011]ZnSe. The origin, characterization, and elimination of these induced reflections are discussed. With the knowledge about these
extra effects on structural defect formation, we have shown the real microstructure of ZnSe epilayers. 相似文献
28.
J. A. Ratto Paul T. Inglefield R. A. Rutowski K.-L. Li Alan Anthony Jones Ajoy K. Roy 《Journal of Polymer Science.Polymer Physics》1987,25(7):1419-1430
Carbon-13 and proton spin-lattice relaxation times were measured at two field strengths on solutions 10% by weight of two polycarbonates in C2D2Cl4 from ?20 to +120°C. The first polycarbonate is an asymmetrically substituted form with one chlorine on one of the two phenylene aromatic rings of the bisphenol unit, whereas the second polycarbonate is symmetrically substituted with two chlorines on each of the two rings. The nuclear spin relaxation data are interpreted in terms of several local motions likely in these polymers. Segmental motion was described by the Hall–Helfand correlation function. Segmental motion in the monosubstituted polycarbonate is somewhat slower than in unsubstituted polycarbonate, whereas segmental motion in the tetrasubstituted polycarbonate is considerably slower. Phenylene ring rotation is observed in unsubstituted polycarbonate and in the monosubstituted polycarbonate above 40°C. Below 40°C in the monosubstituted species, and at all temperatures in the tetrasubstituted species, ring rotation is replaced by ring libration as the predominant motion contributing to spin lattice relaxation. In addition, the rotational motion of the two types of rings in the asymmetric monosubstituted form are very similar although not identical. The substituted ring is slightly less mobile than the rings of unsubstituted polycarbonate. This indicates a strong coupling of ring motion, although the coupling leads to less than synchronous motion. Methyl group rotation is present in both polymers and is little affected by the various structural modifications. 相似文献
29.
Muon irradiation of pure liquid 3‐chloropropene, CH2=CH-CH2Cl, yields a primary radical, \dot\mboxCH2-CHMu-CH2Cl, and a secondary radical, MuCH2-\rm\dot\mboxCH-CH2Cl. 2‐methyl‐3‐chloropropene yields only the tertiary radical, MuCH2-\rm\dot\mboxC(CH3)-CH2Cl. These three chloroalkyl radicals have been characterized by μSR and μLCR, and the hyperfine coupling constants (hfcs)
have been determined over a range of temperatures, either in the pure liquid precursor or in concentrated solution. The temperature
variation of the hfcs has been analyzed to obtain estimates of the barrier to internal rotation about the C_\alpha-C_\beta
axis for various alkyl groups, and also their minimum energy conformations, i.e. their orientations with respect to the axis
of the 2p_z orbital of the unpaired electron. The tertiary radical is particularly interesting because all three methyl‐like
groups, -CH3,-CH2Cl and -CH2Mu, are represented. The results can be compared to electron spin resonance data for analogous radicals, to provide information
on the effects of Mu substitution for H.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
30.
This study reports on the effect of input power to hexamethyldisiloxane (HMDSO) plasmas. The power dependence of the plasma-phase species and of the surface chemistry (of the deposits) has been investigated. Neutral and positive molecular species were detected within the plasma using mass spectrometry (MS). Secondary ion mass spectrometry (SIMS) was used to probe the molecular structure of the deposits. The elemental composition of the surface was determined by XPS and the deposition rate was monitored using a vibrating quartz crystal microbalance. Neutral and cationic molecules of mass greater than HMDSO were detected in the plasma. Their formation through ion-molecule reactions is proposed. Changes in the relative concentration of plasma-phase species follow those seen in molecular species detected at the deposit surface. Thus, we believe that the molecular structure of the deposits can be related to the species present in the plasma. While traditionally the dominant mechanism in deposit formation is assumed to be free radical combinations, we propose other possibilities involving cations with the aim of putting forward a new perspective on plasma polymerization mechanisms and thereby stimulating discussion. 相似文献