光度法同时测定铂和钯

水溶性试剂N-间甲苯基-N’-(对氨基苯磺酸钠)硫脲(MMPT)在HAc-NaAc缓冲介质和CTMAB(溴化十六烷基三甲胺)存在下,与铂(Ⅳ)和钯(Ⅱ)反应形成绿色和褐色水溶性络合物,其最大吸收波长分别为754.4和304.6 nm。符合比尔定律的浓度范围分别为0～32 μg·(25 mL)-1, 0～25 μg·25(mL)-1,摩尔吸光系数为εPt_754.4=8.6×104 L·mol-1·cm-1和εPd304.6=7.4×104 L·mol-1·cm-1。在754.4和304.6 nm波长测定铂,钯混合液的吸光度,换算出铂、钯的含量。50种共存离子中, 仅有Cu2+和Co2+ 对钯的测定有干扰。该法选择性好,用于合成样品、矿石和催化剂样品中铂、钯含量的测定, 其相对标准偏差RSD小于2.0%;回收实验回收率是96%～104%。由于试剂铂、钯形成的络合物都易溶于水、不需予先分离同时测定,操作简便,快速,且环境友好。     

基于位移和应力灵敏度的结构拓扑优化设计

针对仅有应力约束以及含位移和应力约束的重量最小结构拓扑优化问题,基于ICM(独立、连续、映射)方法和渐进结构优化方法的思路,提出了一种结构拓扑优化方法. 在优化迭代循环的每一轮子循环迭代求解开始时,通过形成和引进新的位移和应力约束限, 自动构建设计变量移动限.将结构应力约束归并为几个最可能的有效应力约束,大大减少了应力灵敏度的分析量. 另外,建立了单元删除阈值和几轮迭代循环的单元删除策略. 为了确保优化迭代中结构非奇异和方法具有增添单元的功能,在结构孔洞和边界周围引入了一层人工材料单元,构建了其等效的优化模型. 结合位移和应力灵敏度分析,形成了一种新的连续体结构的拓扑优化方法. 给出的算例验证了该方法的正确性和有效性.      

对氨基苯胂酸电化学合成的研究

研究优化电解还原对硝基苯胂酸(p-A)合成对氨基苯胂酸(p-ASA)的工艺条件.实验表明:硫酸浓度、添加剂量、反应温度、投料量等工艺参数对合成产率有显著影响.初步得出比较适宜的电解合成条件为:硫酸浓度10%(bymass,下同)、添加剂量1%(bymass)NaCl、反应温度80℃、投料量71.4g/L、电流密度10A·dm-2.在上述工艺条件下,电解合成产率可达65.8%.     

CdSe/CdS/SiO2复合纳米球的制备及发光性能

采用两相法合成了CdSe/CdS核-壳结构的量子点, 用氨水催化水解正硅酸乙酯制得复合结构的CdSe/CdS/SiO₂发光纳米球. 通过对量子点用量、氨水用量、反应时间及溶剂比例等实验条件的调节, 得到了单分散性较好, 尺寸在23~145 nm的复合发光纳米球. 利用紫外-可见吸收光谱和荧光发射光谱对其发光性能进行了研究, 同时利用透射电镜(TEM)观察复合纳米球的形貌. 结果表明, 复合发光纳米球样品的最高荧光量子产率可达8%.     

Experimental studies of plasma sheath near meshes of different transmissivity

<正>The measurements of the potential distributions in the boundary layer near meshes with different mesh spacing were conducted in weakly collisional plasmas using a fine-structured emissive probe and the results of the sheath thickness and electric field at the sheath-presheath edge were compared with theoretical models of collisional presheath and collisionless sheath.It was shown that,because the meshes are partially transparent to ions,the sheath is thinner and the electric field is stronger for the mesh of higher transmissivity,owing to the increased ion density in the sheath contributed from the ions transmitted from the other side of the mesh.However,the potential profiles in the presheath remain almost the same for different meshes except for the shift of the sheath-presheath edge.The thickness of the sheath decreases while the electric field at the edge increases with the increase of the neutral gas pressure.Furthermore, depending on the pressure,the measured electric fields at the edge are close to that from the models of a transition region.     

New finite-gap solutions for the coupled Burgers equations engendered by the Neumann systems

On the tangent bundle TS^N-1 of the unit sphere S^N-1, this paper reduces the coupled Burgers equations to two Neumann systems by using the nonlinearization of the Lax pair, whose Liouville integrability is displayed in the scheme of the r-matrix technique. Based on the Lax matrix of the Neumann systems, the Abel--Jacobi coordinates are appropriately chosen to straighten out the restricted Neumann flows on the complex torus, from which the new finite-gap solutions expressed by Riemann theta functions for the coupled Burgers equations are given in view of the Jacobi inversion.     

Difference-frequency ultrasound generation from microbubbles under dual-frequency excitation

The difference-frequency (DF) ultrasound generated by using parametric effect promises to improve detection depth owing to its low attenuation, which is beneficial for deep tissue imaging. With ultrasound contrast agents infusion, the harmonic components scattered from the microbubbles, including DF, can be generated due to the nonlinear vibration. A theoretical study on the DF generation from microbubbles under the dual-frequency excitation is proposed in formula based on the solution of the RPNNP equation. The optimisation of the DF generation is discussed associated with the applied acoustic pressure, frequency, and the microbubble size. Experiments are performed to validate the theoretical predictions by using a dual-frequency signal to excite microbubbles. Both the numerical and experimental results demonstrate that the optimised DF ultrasound can be achieved as the difference frequency is close to the resonance frequency of the microbubble and improve the contrast-to-tissue ratio in imaging.     

快速传递对准用联合强跟踪Kalman滤波器设计与仿真

针对用于快速传递对准的卡尔曼滤波器阶数高,计算量大,滤波更新率低,鲁棒性差及对准精度不高等问题,提出采用联合强跟踪Kalman滤波器进行快速传递对准。文中设计了联合强跟踪Kalman滤波器的结构和算法,同时利用改进的Elman网络进行信息分配系数的自适应调节,以实现融合信息在各子系统中的自适应分配。仿真结果表明,该滤波器不仅提高了解算速度,而且提高了系统鲁棒性和对准精度。     

动力松弛方法中Rayleigh阻尼参数取值分析

论文阐述了动力松弛法计算静力问题的原理,分析了Rayleigh阻尼对计算的影响,提出了一种对质量阻尼和刚度阻尼参数取值的新方法。这种取值方法可以避免计算结果的振荡和过塑性的问题,并利用实例计算进行了对比分析,验证了本文中Rayleigh阻尼取值的合理性。     

1.3μm InGaAsP/InP应变多量子阱部分增益耦合DFB激光器

本文在国内首次报道了采用直接刻蚀有源区技术在应变多量子阱有源区结构基础上制作了１．３μｍＩｎＧａＡｓＰ／ＩｎＰ部分增益耦合ＤＦＢ激光器，器件采用全ＭＯＶＰＥ生长，阈值电流１０ｍＡ，边模抑制比（ＳＭＳＲ）大于３５ｄＢ，在端面未镀膜情况下器件单纵模成品率较高