激光切割碳纤维复合材料的实验研究

为了获得激光切割参量对碳纤维复合材料的影响规律,利用额定功率为500W的毫秒脉冲Nd:YAG激光器,分别进行了在空气中和水下切割碳纤维复合材料(CFRP)的实验研究。采用单因素实验法,考察了脉冲能量、频率、切割速度与气体压力等激光参量对切割质量的影响,获得了激光参量对切割CFRP材料切口的切缝宽度、正面纤维拔出长度、背面纤维拔出长度与锥角的影响规律,并对激光切割机理进行了分析研究。结果表明,水下切割能有效地减小激光切割产生的热影响区。这为继续开展激光水下切割CFRP的研究提供了参考。     

Recent Advances in Organic Reactions Catalyzed by Lanthanide（Ⅲ） Complexes

Lanthanide compounds have been attracting much attention in organic synthesis.Chiral Ln-substituted BINOL have been widely studied in several asymmetric organic reactions.LnCl3 and Ln(OTf)3 have been expected to serve as Lewis acide and have been applied to many important synthetic reactions in a one-pot manner,Ln(O-i-Pr)3 exhibits some basic characters,which also can be utilized in some special organic transformation.This article deals with some lanthanides(Ⅲ）complexes promoted organic reactios,which we have recently developed.     

新型双锂盐络合物的合成及其单晶结构的测定

报道了一种新的双锂盐络合物的合成及其X衍射单晶结构，该络合物含有2个 Li原子、一个（i-Pr2C6H3)2-dad配体及2个DME分子[triclinic,P-1,α=1.3478(4) ,b=1.5158(3),c=1.0730(3)nm,α=100.668(3)°,β=113.416(3)°，γ=97.128(3) °,Ⅴ=1.790(1)nm^3,Dc=1.06g/cm^3,Z=2,R/Rω=0.058/0.057]。