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DMFC用PES/SPEEK共混阻醇质子交换膜 总被引:1,自引:0,他引:1
将磺化聚醚醚酮(SPEEK, 磺化度DS为68.3%)和聚醚砜(PES)两种聚合物共混制得PES/SPEEK共混膜. DSC研究表明两种聚合物之间具有较好的相容性, 因而共混膜均匀致密, 未发生大尺度相分离. PES的混入能有效降低膜的溶胀度及甲醇透过系数. 纯SPEEK 膜40 ℃时在1 mol•L−1甲醇水溶液中溶胀度达到160%, 45 ℃时就完全溶解, 而含30%(w)PES的共混膜在80 ℃时的溶胀度仅有15%. 室温下含20%−30%(w)PES的共混膜的甲醇透过系数为1×10−7 cm2•s−1左右, 比Nafion 115膜的透过系数小一个数量级. 尽管80 ℃下30%(w)PES/SPEEK共混膜的电导率与Nafion 115膜相当, 但由于共混膜的厚度比Nafion 115膜小1/3左右, 膜电阻较小, 因而其电池性能比Nafion 115膜的好. 相似文献
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对量子遗传算法进行了研究。量子遗传算法只使用一个最优染色体来指导种群的进化,极易陷入局部最优,本文对此进行了改进,提出使用多个精英染色体来指导整个种群的进化。讨论了精英染色体的产生、维护与作用,并在此基础之上提出了一种基于精英组的量子遗传算法(elite groupbased quantum genetic algorithm,EQGA)。最后,将EQGA应用到无线多媒体传感器网络的覆盖优化问题中。对比测试表明,EQGA求出的解比遗传算法和量子遗传算法求出的解都要好。 相似文献
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Graphene is a new promising candidate for application in radio-frequency(RF) electronics due to its excellent electronic properties such as ultrahigh carrier mobility, large threshold current density, and high saturation velocity. Recently,much progress has been made in the graphene-based RF field-effect transistors(RF-FETs). Here we present for the first time the high-performance top-gated RF transistors using millimeter-scale single graphene domain on a SiO2/Si substrate through a conventional microfabrication process. A maximum cut-off frequency of 178 GHz and a peak maximum oscillation frequency of 35 GHz are achieved in the graphene-domain-based FET with a gate length of 50 nm and 150 nm,respectively. This work shows that the millimeter-scale single graphene domain has great potential applications in RF devices and circuits. 相似文献