Synthesis and Crystal Structure of a 1D Chained Coordination Polymer Containing One-dimensional Egg-like Channels： {[Cu2（C2O4）2（inta）4]（inta）}n （inta = Isonicotinamide）

A new one-dimensional copper coordination polymer chain has been prepared and fully characterized by single-crystal X-ray diffraction,elemental analyses and IR spectroscopy. The compound {[Cu2(C2O4)2(inta)4](inta)}n1 crystallizes in the triclinic system,space group P1,with a=8.4722(5),b=10.9825(6),c=11.6128(6),α=104.8050(10),β=102.5740(10),γ= 109.6890(10)o,V=927.18(9)3,Mr=929.79,Z=1,Dc=1.665 g/cm3,F(000)=475,μ=1.231 mm-1,R=0.0453 and wR=0.1185 for 3290 observed reflections (I > 2σ(I)). Of the compound,the Cu center is octahedrally coordinated with oxalate acting as a tetra-dentate ligand coordinated to the copper atom and each inta serving as a terminal ligand by employing only one N-donor to coordinate with the Cu center. An infinite {Cu2(C2O4)2}∞ chain is formed along the c axis. Furthermore,the 1D chains are held together via extensive hydrogen-bonding interactions to generate a three-dimensional network with 1D channels (ca. 5.491×11.507) where inta molecules are filled.     

回归函数改良核估计的渐近分布

设(X1,Y1),…,(Xn,Yn)是来自二元总体(X,Y)的样本,若EY＜∞,则回归函数m(x)＝E(Y｜X＝x)存在。在本文中,考虑m(x)的改良核估计     

移动通信20年:做强产业惠及全球——访信息产业部电信研究院副院长曹淑敏

中国移动通信业走过20个春秋,如今,这个正值青春花季的朝阳产业的成长和发展,也吸引了业界的普遍关注。回首20年的跨越式发展,我国移动通信业可谓迅速崛起、硕果累累,在用户规模、业务收入、通信能力、技术层次、服务水平等方面都发生了质的飞跃。移动通信     

烽火通信面向3G综合传送网解决方案

本文将对3G不同制式不同版本的网络结构、接口、容量等进行分析,介绍烽火通信的3G传送网解决方案。     

三苯基膦参与的三氟甲烷磺酰氯对吲哚嗪和吡咯的直接三氟甲硫基化反应（英文）

发展了一种三苯基膦参与的三氟甲烷磺酰氯对吲哚嗪和吡咯的直接三氟甲硫基化反应.由于该反应无金属参与,试剂廉价易得,所以容易进行放大.     

移动通信传输网络安全性探讨

移动通信传输网络的安全影响到网络用户的切身利益,逐渐成为人们重点关注的对象。随着科学技术的迅速发展,移动通信传输网络也在不断地更新与改善。根据调查研究结果,结合目前移动通信传输网络的发展现状,本文将从移动通信传输网络的发展历史、移动通信传输网络的安全性现状以及移动通信传输网络安全性的影响因素和有效的应对措施三个方面做出详细的分析和探究。     

In situ study of calcite-III dimorphism using dynamic diamond anvil cell

The phase transitions among the high-pressure polymorphic forms of CaCO₃ (cc-I, cc-II, cc-III, and cc-IIIb) are investigated by dynamic diamond anvil cell (dDAC) and in situ Raman spectroscopy. Experiments are carried out at room temperature and high pressures up to 12.8 GPa with the pressurizing rate varying from 0.006 GPa/s to 0.056 GPa/s. In situ observation shows that with the increase of pressure, calcite transforms from cc-I to cc-II at ～ 1.5 GPa and from cc-II to cc-III at ～ 2.5 GPa, and transitions are independent of the pressurizing rate. Further, as the pressure continues to increase, the cc-IIIb begins to appear and coexists with cc-III within a pressure range that is inversely proportional to the pressurizing rate. At the pressurizing rates of 0.006, 0.012, 0.021, and 0.056 GPa/s, the coexistence pressure ranges of cc-III and cc-IIIb are 2.8 GPa-9.8 GPa, 3.1 GPa-6.9 GPa, 2.7 GPa-6.0 GPa, and 2.8 GPa-4.5 GPa, respectively. The dependence of the coexistence on the pressurizing rate may result from the influence of pressurizing rate on the activation process of transition by reducing the energy barrier. The higher the pressurizing rate, the lower the energy barrier is, and the easier it is to pull the system out of the coexistence state. The results of this in situ study provide new insights into the understanding of the phase transition of calcite.     

全球制造业发展特点及对我国的启示

<正>统计数据显示,全球制造业在2022年实现了3.2%的增长,成为经济发展的重要驱动力,但也面临成本上升、需求疲软等多种挑战。我国制造业在全球工业经济体中的重要性稳步提升,下一步,仍需从全球视角把握创新与融合趋势,加速先进数字技术的应用,扎实推进新型工业化重点任务,进一步提升我国制造业在全球的竞争力。     

重金属Pb2+对玉米苗生长的影响

以水栽培的玉米幼苗为材料，用不同浓度的醋酸铅溶液处理后，分别在第10天、第20天、第30天对玉米苗的根、茎、叶分别进行Pb^2＋含量测定。分析结果：Pb^2＋在玉米体内的分布表现为根〉叶〉茎；玉米中的叶绿素含量均降低；随着Pb^2＋浓度的增大，玉米细胞的膜透性表现根〉叶〉茎依次升高；Pb^2＋对玉米的伤害率的大小表现为根〉叶〉茎。该实验为进一步研究农作物对重金属Pb^2＋的耐性和重金属Pb^2＋在农作物体内的分布提供了可参考的数据。     

Gd掺杂对Bi2Sr2Ca1-xGdxCu2Oy单晶载流子浓度和各向异性电阻率的影响

系统地研究了Gd掺杂对Bi2Sr2Ca1-xGdxCu2Oy单晶超导电性及各向异性电阻率的影响.Tc满足Tc/Tc,max=1-82.6(ax+b)2,并随Gd含量的增加而下降,这是由于Gd掺杂引起载流子浓度减小所导致.在x≥0.19时,ρab(T)在Tc附近有类半导体行为,dρab/dT随Gd含量增大而增大.ρc(T)呈半导体行为,并可用唯象公式ρc(T)=(a/T)exp(Δ/T)+bT+c加以描述.电阻率各向异性ρc/ρab随掺杂浓度增大而增大.