沸石的包结作用提高分子内萘蒽的交叉光加成

萘与萘、蒽与蒽的光二聚反应已经被广泛研究,但萘与蒽的交叉光二聚反应报道不多。我们合成了两末端分别以萘和蒽标记的聚醚化合物,利用NaY沸石的孔腔作为纳米反应器,将此化合物置于孔腔中,通过光反应得到分子内的萘和蒽交叉二聚体。     

Probing the structure of multi-center molecules with odd–even high harmonics

We study high-order harmonic generation(HHG) from multi-center asymmetric linear molecules numerically and analytically. Our simulations show that odd and even HHG spectra of the asymmetric multi-center system respond differently to the change of the molecular structure. Specifically, when the internuclear distances between these nuclei of the molecule have a small change, the odd spectra usually do not change basically, but the even spectra differ remarkably. Based on this phenomenon, a simple procedure is proposed to probe the positions of these nuclei with odd–even HHG. Our results shed light on attosecond probing of the structure of multi-center molecules using HHG.     

p-幂零群的一个判定准则（英文）

设G是一个有限群,P是G的一个Sylow p-子群.在N_G(P)为p-幂零的假设下,通过假定P的一个特殊的子群在G中满足覆盖远离性,本文给出了G为p-幂零群的一个判定准则.     

像面干涉成像光谱技术中的复原方法

与传统的干涉成像光谱技术相比,像面干涉成像光谱技术具有高光通量、高光谱分辨率、高目标分辨率等优点。在介绍像面干涉成像光谱技术的基本原理基础上,提出了通过推扫横向剪切分束器对目标进行探测的方法,省去了传统推扫方法中提取物点干涉信息时的图像配准过程。研究了信息处理中去直流项、切趾等预处理问题,分析了相位误差校正方法及各种方法的优缺点。搭建Sagnac型像面干涉成像光谱实验装置进行了光谱重构实验,复原了被测光源的光谱曲线,并复原了探测目标在各个谱段的光谱图像。     

免费入侵检测系统在Solaris9下的实现

目前IDS的来源有两种，一种是付费的IDS(商业化产品)。近年来，国内的IDS商业产品如雨后春笋般蓬勃发展起来，如启明星辰的天阗入侵产品和北方计算机中心的NIDS detector等。同时一批国外产品也进入了国内市场，如Cisco的NetRanger、ISS公司的Realsecure等。还有一种就是免费的来源，主要由一些著名的大学和安全公司的人员编写的。特点是短小精悍，     

一个有效的任意四边形薄板弯曲单元

本文给出了拟协调任意四边形薄板弯曲单元QCQ单元,该单元通过常应变分片试验,近似通过线性应变分片试验,退化成矩形时,通过线性分片试验。单元刚度矩阵计算简单,不需要作数值积分。算例表明,QCQ单元精度高,收敛快,本文讨论了拟协调元的载荷项,提出了拟一致载荷的概念。     

化妆品中氯胺T的超声辅助水解/液相色谱检测及质谱确证

建立了化妆品中氯胺T的超声辅助水解/高效液相色谱分析方法,并采用液相色谱-串联质谱进行确证.将不同类型(膏霜、水剂、散粉、香波、牙膏)化妆品样品分散于盐酸溶液中,超声波辅助提取并水解氯胺T,水解液用乙醚萃取后,采用高效液相色谱分离分析,以Agilent Extend C18 (4.6 mm×250 mm,5μm)为色谱...     

Parameter study of RF excited diffusively cooled all-metal slab waveguide CO_2 laser

In this paper, we have investigated some parameters of a radio frequency (RF) excited diffusively cooled all-metal slab waveguide CO2 laser based on the modified Rigrod theory by introducing a waveguide coupling efficiency which designates the coupling between the waveguide and the resonator mirrors. The parameters of the laser small signal gain go, saturation intensity Is, and waveguide coupling efficiency ηare studied theoretically and experimentally. In the experiments, three sets of output coupling flat mirrors with the different transitivities were used, and a maximum laser power output of 150 W was obtained from a gas discharge region of 2-mm height, 20-mm width, and 386-mm length coupled with a CASE-I optical waveguide resonator.     

锡焊及防止环境污染措施

随着地球环境保护的呼声日益高涨，迄今所使用的材料有些是有害的。即使焊锡也是如此。其中有氟里昂额定量，铅额定量、VOC（挥发性有机化合物）额定量等限制问题。因此，采取对应措施问题已迫在眉捷。本文详细叙述焊剂、焊膏克清洗、无铅焊锡的开发动向，适于VOC的焊剂等。一、焊剂、焊喜的免清洗1免清洗存在的问题及采取的相应措施锡焊后的基板清洗，其目的如下：（1）防止由焊剂残渣造成的绝缘电阻下降及接触不良。（2）防止由焊剂残渣造成的迁移。（3）为使检测管脚和连接器的接触电阻变佳。（4）除去焊球。（5）使外观良好。（6）去…     

980-nm all-fiber mode-locked Yb-doped phosphate fiber oscillator based on semiconductor saturable absorber mirror and its amplifier

A 980-nm semiconductor saturable absorber mirror(SESAM) mode-locked Yb-doped phosphate fiber laser is demonstrated by using an all-fiber linear cavity configuration. Two different kinds of cavity lengths are introduced into the oscillator to obtain a robust and stable mode-locked seed source. When the cavity length is chosen to be 6 m, the oscillator generates an average output power of 3.5 m W and a pulse width of 76.27 ps with a repetition rate of 17.08 MHz. As the cavity length is optimized to short, 4.4-m W maximum output power and 61.15-ps pulse width are produced at a repetition rate of 20.96 MHz. The output spectrum is centered at 980 nm with a narrow spectral bandwidth of 0.13 nm. In the experiment, no undesired amplified spontaneous emission(ASE) nor harmful oscillation around 1030 nm is observed. Moreover,through a two-stage all-fiber-integrated amplifier, an output power of 740 m W is generated with a pulse width of 200 ps.