Synthesis of N-type semiconductor diamonds with sulfur,boron co-doping in FeNiMnCo-C system at high pressure and high temperature

A series of diamonds with boron and sulfur co-doping were synthesized in the Fe Ni Mn Co-C system by temperature gradient growth(TGG) under high pressure and high temperature(HPHT). Because of differences in additives, the resulting diamond crystals were colorless, blue-black, or yellow. Their morphologies were slab, tower, or minaret-like. Analysis of the x-ray photoelectron spectra(XPS) of these diamonds shows the presence of B, S, and N in samples from which N was not eliminated. But only the B dopant was assuredly incorporated in the samples from which N was eliminated. Resistivity and Hall mobility were 8.510 ?·cm and 760.870 cm~2/V·s, respectively, for a P-type diamond sample from which nitrogen was eliminated. Correspondingly, resistivity and Hall mobility were 4.211×10~5 ?·cm and 76.300 cm~2/V·s for an N-type diamond sample from which nitrogen was not eliminated. Large N-type diamonds of type Ib with B–S doping were acquired.     

单架飞机受干扰后飞机路径恢复多项式算法研究

飞机路径恢复是航班调整中保证航班能够运行的必要条件之一,而传统目标下的飞机路径优化问题是NP-hard的。本文针对单架飞机受到干扰后,基于最小最大目标的同机型飞机路径最优化问题,给出了一个新的多项式时间算法。首先基于航空公司调整航班的常用原则,提出把最大航班延误时间最小化作为问题的目标。然后根据问题的一些特点和目标形式,设计出解构造算法,得到飞机路径恢复问题的最优解,并分析出算法的复杂度为O(n²)。相对于一般的最小最大二分图匹配算法(复杂度为O(n³log(n))),该算法具有较小的时间复杂度。最后用实例验证了解构造算法的有效性。该研究结果将为航空公司减少航班延误提供理论和方法支持。     

用于诊断材料微层裂的Asay窗技术

微层裂是冲击波物理领域的重要基础问题,在工程上具有重要应用价值。近年来用于诊断样品多层层裂的传统Asay窗技术被用于诊断微层裂,但对其诊断能力和信号特征认识仍存在严重不足。为此,通过波系分析,揭示出在薄飞片击靶的微层裂实验中样品破碎存在1个“痂片”特征区、2个微层裂特征区以及1个“残体”特征区。实验表明,在样品窗口间隙合适的条件下,Asay窗不仅能够有效区分这些不同特征分区,而且能够灵敏探测样品表面发射的高速微喷粒子,从而实现对样品连续破碎过程的精密诊断。     

高光谱成像技术在彩绘文物分析中的研究综述

彩绘文物是文化遗产研究的重要内容之一。目前,许多的化学、光谱以及数字成像等分析技术应用于彩绘文物研究中,其中,高光谱成像技术集光谱分析与成像技术为一体,具有无损、快速成像以及"图谱合一"的特点。其技术特点使得高光谱成像技术在非接触、无样本的条件下对彩绘文物进行无损研究,既可以获得彩绘文物的整体形貌特征,还可以深入分析彩绘文物的光谱特征,是高光谱成像技术相比于其他彩绘文物研究方法的独特优势。利用高光谱成像技术研究彩绘文物分为数据采集、数据分析以及数据应用三步,其中数据分析与数据应用是研究的主要内容。通过对高光谱成像技术在彩绘文物中的相关研究成果进行总结归纳,其数据处理方法主要包括高光谱数据降维、光谱特征参量化、光谱解混合以及分类方法四个方面,并分别描述了四类处理方法的主要功能、常用方法和已有案例。从具体应用方向上,可归纳为视觉增强、隐含信息挖掘、保护监测和颜料分析四类,具体描述了四类应用方向所涵盖的内容以及所解决的问题。最后对相关研究中存在的挑战和发展前景进行了总结和展望。     

基于CDIO模式的环境化学课程教学改革与实践

在CDIO工程教育理念指导下,改进环境化学课程的教学内容和教学模式,以提升环境工程专业学生的实践能力和创新意识。通过提升课程内容与实际环境问题的相关性,加入典型教学案例,改进设计型实验,利用本地企业进行工程实践,实施多元化考核方法,加强学生工程实践能力,提高其学习主动性,促进教师教学实践能力的提高。实践表明,基于CDIO模式的环境化学课程改革,能够提升学生的工程专业能力和教师的教学效果。     

多尺度局部区域响应累积的非滑窗快速目标检测算法

针对滑动窗口全局搜索检测目标搜索时间长的问题,提出一种多尺度局部区域响应累积的非滑窗快速目标检测算法。首先,提取检测目标多尺度可重叠局部区域作为训练样本,通过学习得到多尺度且具有判别能力的部件集,部件集中每个局部区域与检测目标有明确位置对应关系;然后,根据各投影检测器响应判断目标是否在某一区域出现,并利用多尺度目标局部区域的检测结果和位置约束进行投票,完成目标粗定位;其次,利用HOG特征提取和SVM相结合完成检测目标验证实现准确检测。该方法将多尺度部件模型、统计累积投票思想及分类器判决相结合,实现快速目标检测,大大减少滑动窗口逐像素搜索背景时所消耗时间,提高检测效率。      

Study on electrical defects level in single layer two-dimensional Ta_2O_5

Two-dimensional atomic-layered material is a recent research focus, and single layer Ta_2O_5 used as gate dielectric in field-effect transistors is obtained via assemblies of Ta_2O_5 nanosheets. However, the electrical performance is seriously affected by electronic defects existing in Ta_2O_5. Therefore, spectroscopic ellipsometry is used to calculate the transition energies and corresponding probabilities for two different charged oxygen vacancies, whose existence is revealed by x-ray photoelectron spectroscopy analysis. Spectroscopic ellipsometry fitting also calculates the thickness of single layer Ta_2O_5,exhibiting good agreement with atomic force microscopy measurement. Nondestructive and noncontact spectroscopic ellipsometry is appropriate for detecting the electrical defects level of single layer Ta_2O_5.     

Large single crystal diamond grown in FeNiMnCo-S-C system under high pressure and high temperature conditions

Large diamonds have successfully been synthesized from FeNiMnCo-S-C system at temperatures of 1255-1393 ℃and pressures of 5.3-5.5 GPa.Because of the presence of sulfur additive,the morphology and color of the large diamond crystals change obviously.The content and shape of inclusions change with increasing sulfur additive.It is found that the pressure and temperature conditions required for the synthesis decrease to some extent with the increase of S additive,which results in left down of the V-shape region.The Raman spectra show that the introduction of additive sulfur reduces the quality of the large diamond crystals.The x-ray photoelectron spectroscopy(XPS) spectra show the presence of S in the diamonds.Furthermore,the electrical properties of the large diamond crystals are tested by a four-point probe and the Hall effect method.When sulfur in the cell of diamond is up to 4.0 wt.%,the resistance of the diamond is 9.628×10~5 Ω·cm.It is shown that the large single crystal samples are n type semiconductors.This work is helpful for the further research and application of sulfur-doped semiconductor large diamond.     

Application of long-range correlation and multi-fractal analysis for the depiction of drought risk

By using the multi-fractal detrended fluctuation analysis method, we analyze the nonlinear property of drought in southwestern China. The results indicate that the occurrence of drought in southwestern China is multi-fractal and longrange correlated, and these properties are indifferent to timescales. A power-law decay distribution well describes the return interval of drought events and the auto-correlation. Furthermore, a drought risk exponent based on the multi-fractal property and the long-range correlation is presented. This risk exponent can give useful information about whether the drought may or may not occur in future, and provide a guidance function for preventing disasters and reducing damage.     

含有S,S-二氧-二苯并噻吩和芴酮单元的白光电致发光聚合物的合成与性能

通过Suzuki缩聚反应将发橙红光的2,7-二(2-噻吩基)-9-芴酮(DFT)引入聚芴主链,实现了两元光单分子聚合物白光发射,该聚合物作为发光层的电致发光器件ITO/PEDOT:PSS/PVK/发光层/CsF/Al的最大流明效率为1.0cd/A,色坐标为(0.41,0.36)。再将S,S-二氧-二苯并噻吩(SO)引入聚合物主链中,其电致发光器件的最大流明效率为3.5cd/A,色坐标为(0.34,0.32);此白光器件表现出优异的光谱稳定性。通过将DFT和SO单元引入聚芴主链,可获得有望应用于固态发光与显示的白光电致发光材料。更多还原