3,7-二硝基亚氨基-2,4-二氮杂双环[3,3,0]辛烷的放热分解反应动力学

在程序升温条件下 ,用DSC研究了标题化合物的放热分解反应动力学 .用线性最小二乘法、迭代法以及二分法与最小二乘法相结合的方法 ,以积分方程、微分方程和放热速率方程拟合DSC数据 .在逻辑选择建立了微分和积分机理函数的最可几一般表达式后 ,用放热速率方程得到相应的表观活化能 (Ea)、指前因子 (A)和反应级数 (n)的值 .结果表明 :该反应的微分形式的经验动力学模式函数、Ea 和A值分别为 (1-α) 0 .44、2 30 .4kJ/mol和 10 18.16s-1.借助加热速率和所得动力学参数值 ,提出了标题化合物放热分解反应的动力学方程 .该化合物的热爆炸临界温度为 30 2 .6℃ .上述动力学参数对分析、评价标题化合物的稳定性和热变化规律十分有用 .     

PREPARATION AND CATALYTIC ACTIVITY OF BIOACTIVE FIBERS

Two kinds of water-soluble metallophthalocyanines, binuclear cobalt phthalocyanine （Co2Pc2） and binuclear ferric phthalocyanine （Fe2Pc2）, were synthesized through phenylanhydride-urea route and characterized by elemental analysis and FT-IR spectra. Binuclear metallophthalocyanine derivatives （Mt2Pc2） were immobilized on silk fibers and modified viscose fibers to construct bioactive fibers of mimic enzyme. Mt2Pc2 was used as the active center of bioactive fibers, viscose and silk fibers as the microenvironments. The catalytic oxidation ability of bioactive fibers on the malodors of methanthiol and hydrogen sulfide was investigated at room temperature. The experimental results indicated that the catalytic activity of such bioactive fibers was closely correlative to the types ofbioactive fibers and substrates.     

Full Complex Amplitude Digital Holograms： Design, Fabrication and Optical Characterization

Diffractive optical elements have a large number of industrial applications, such as beam shaping and optical filtering. Traditionally, these elements modulate the phase of the incoming light or its amplitude, but not both. To overcome this limitation, full complex-amplitude modulation diffractive optical elements were developed. Well-established integrated circuit fabrication steps were employed to fabricate the devices with high precision. Using this approach, the new element‘s optical performances are improved also for near field operations. With this device it is possible to obtain 100% efficient spatial filtering and low noise reconstructed images.     

MPEG—4标准

两类重要的技术领域已经出现，它们正在改变着人们与信息的关系，其一是由ＭＰＥＧ－２标准所实现的无线电／电视，而另一个则是因特网创造而独立于信息基础设施的具有连接各种网络能力之可能性，虽然，这两类技术领域在颇大程度上是相辅相成的，但是，它们在很大程度上仍然是对立的（尽管做了很多努力来促进两者的汇合）１９９８年１０月，ＭＰＥＧ标准族中的一个新标准ＭＰＥＧ－４，将由ＭＰＥＧ委员会颁布。该标准已经设计为能够     

在曲面上图嵌入的唯一性

在本文中，证明了图嵌入在一个已知曲面上的唯一性充分条件，这个条件比「４」中要弱些。     

一种简易的话音保密装置

本文介绍了一种具有实用价值的、高效、经济的话音保密通信装置,它适用于标准音频信道。该装置采用标准电子元器件,其中包括一块完成实时处理的微处理器。早先的模拟通信技术已经不那么安全可靠了;尽管数字技术通常能给出高的保密度,但其输出的数字式数据与一般公用的话音信道不相容。这里所采用的一种独特的混合式方法,是将高保密度的数字处理技术与话带的模拟输出相结合;这样就只需一般短的密钥,并通过一种高级算法,有效地使密钥长得到成倍的扩展,而保密度则接近于较复杂的数字方式。我们的最终目的是要将该装置配备于公安人员的手持式无线电收发信机。     

Hilbert Space of Probability Density Functions Based on Aitchison Geometry

The set of probability functions is a convex subset of L1 and it does not have a linear space structure when using ordinary sum and multiplication by real constants. Moreover, difficulties arise when dealing with distances between densities. The crucial point is that usual distances are not invariant under relevant transformations of densities. To overcome these limitations, Aitchison＇s ideas on compositional data analysis are used, generalizing perturbation and power transformation, as well as the Aitchison inner product, to operations on probability density functions with support on a finite interval. With these operations at hand, it is shown that the set of bounded probability density functions on finite intervals is a pre-Hilbert space. A Hilbert space of densities, whose logarithm is square-integrable, is obtained as the natural completion of the pre-Hilbert space.     

掺杂铁电纳米粉的液晶的电光特性

铁电纳米粒子悬浮在向列相液晶母体中，增强介电各向异性，而且对施加的电场信号敏感。本文也展示了纳米粒子对所述复合材料可实现的总的相变的作用。这种方法也许可应用于设计新型显示材料。     

布里兹曼法碲镉汞（Hg1—xCdxTe）晶体生长过程热场的数值分析

用控制容积法对布里兹曼碲镉汞（Ｈｇ１－ｘＣｄｘＴｅ）晶体生长过程热场分布进行了计算。介绍了控制容积公式的推导和边界条件的处理，并对所得结果进行了分析。虽然碲镉汞晶体生长时热场受系统的影响情况错综复杂，但从本文的研究结果中仍可看出一些明显的规律，可供从事该方面研究工作时参考。