CaCl_2添加对热解煤中汞析出规律影响的实验研究

在程序升温热解反应装置上,研究了低氯煤中添加不同氯含量(质量分数0.1%、0.3%、0.5%)的CaCl2对煤热解过程中汞析出规律的影响。实验结果表明,温度是影响汞析出的关键因素;随着氯添加量的增加,Hg2+析出比例呈上升趋势,且汞的最佳析出温度降低,汞的释放率也有所降低;随着热解气氛中O2比例的增加,Hg2+比例也略有增加;较高的升温速率能加快汞的释放,也能提高Hg2+的比例。低氯煤中添加氯化钙能够强化单质汞的氧化。     

Compact efficient optical parametric generator internal to a Q-switched Nd:YVO4 laser with periodically poled MgO:LiNbO3

This paper demonstrates a compact efficient optical parametric generator internal to a Q-switched diode-end-pumped Nd:YVOquasi-phase-matching, intracavity optical parametric generator, periodically poled MgO-doped lithium niobate (PPMgLN)Project supported by the National Natural Science Foundation of China (Grant Nos 10474071 and 60671036).4265K, 4260F, 4270This paper demonstrates a compact efficient optical parametric generator internal to a Q-switched diode-end-pumped Nd:YVOquasi-phase-matching, intracavity optical parametric generator, periodically poled MgO-doped lithium niobate (PPMgLN)Project supported by the National Natural Science Foundation of China (Grant Nos 10474071 and 60671036).4265K, 4260F, 4270This paper demonstrates a compact efficient optical parametric generator internal to a Q-switched diode-end-pumped Nd:YVOquasi-phase-matching, intracavity optical parametric generator, periodically poled MgO-doped lithium niobate (PPMgLN)Project supported by the National Natural Science Foundation of China (Grant Nos 10474071 and 60671036).4265K, 4260F, 4270This paper demonstrates a compact efficient optical parametric generator internal to a Q-switched diode-end-pumped Nd:YVOquasi-phase-matching, intracavity optical parametric generator, periodically poled MgO-doped lithium niobate (PPMgLN)Project supported by the National Natural Science Foundation of China (Grant Nos 10474071 and 60671036).4265K, 4260F, 4270This paper demonstrates a compact efficient optical parametric generator internal to a Q-switched diode-end-pumped Nd:YVOquasi-phase-matching, intracavity optical parametric generator, periodically poled MgO-doped lithium niobate (PPMgLN)Project supported by the National Natural Science Foundation of China (Grant Nos 10474071 and 60671036).4265K, 4260F, 4270This paper demonstrates a compact efficient optical parametric generator internal to a Q-switched diode-end-pumped Nd:YVO$_{4}$ laser with periodically poled MgO:LiNbO₃(PPMgLN). With the Q-switch set at a repetition rate of 25kHz and the PPMgLN crystal operated at room temperature (25\du\,), the intracavity optical parametric generator threshold was reached as a diode pump power of 0.9\,W. A maximum signal output power of 0.34W with a pulse width of 25\,ns and a beam quality factor of 1.4 was obtained at an incident diode power of 3.4\,W, leading to a conversion efficiency of 10{\%} with a slope efficiency of 14.4{\%}. By varying the crystal temperature from 25 to 200\du, the output signal wavelengths were tuned in range of 1506--1565\,nm. Over a 30-minutes interval, the instability of the signal power was measured to be less than 1{\%}. In addition, the threshold pump intensity for the intracavity optical parametric generator is theoretically investigated, and the obtained result is in good agreement with the experimental results.     

一维非自治经典谐振子的精确解析解

一维时间相关的经典谐振子是一个SU(1,1) 非自治经典系统,物理上十分有用,而数学上难于得到其精确解析解. 首次把新颖的代数动力学方法用于经典动力学系统,得到了这个模型的一般精确解;当时间相关的弹性系数为某些初等函数时,给出了精确解的解析形式. 这是关于这一问题的重要结果. 从精确解出发,推导出最近文献中提出的"解析近似解",并指出该近似解的适用条件.     

寓辩证唯物主义教育于物理教学之中

提高学生的认识水平和分析能力 ,要以培养辩证唯物主义观点为基础 .在物理教学中与之有关的内容很多 ,现仅就以下三点谈些看法 .1　注意物质的客观属性时间、空间和物质的客观属性是决定物质运动的三个因素 .物质的客观属性起着推动运动内因的作用 ,即物质的客观属性决定了运动     

Bend-Induced Distortion in Large Mode Area Holey Fibre

A simplified scheme of bend-induced mode distortion is introduced into bent holey fibres, the distorted mode distribution and mode effective area reduction are investigated using the finite difference method. Numerical results show that the modes of bent holey fibres with small bend radius shift away from the core and are deformed greatly, and the mode areas drop significantly as the bend radius decreases, which severely affects the fibre laser performance. The propagation characteristics of bent holey fibres at given wavelength are determined by fill factor and normalized bend radius. Finally, the transition normalized bend radius that represents the location of the mode area beginning to fall off is obtained.     

无过渡金属参与的异腈与芳基硼酸双插入偶联反应高效构建双芳基甲胺衍生物

双芳基甲胺作为一类重要砌块广泛存在于生物活性分子、药物载体和有机配体中(图1),因而对该类骨架化合物的合成备受关注[1].传统构建该类骨架的方法包括羰基还原胺化[2]、亲核取代和亚胺的亲核加成[3]等,然而以上策略通常存在合成效率不高、底物范围受限等问题.近年来,过渡金属催化的转移氢化[4]和酰胺的还原偶联反应[5]相...     

钯催化的烯烃异构化反应

烯烃异构反应可以从简单烯烃出发,通过对碳碳双键立体选择性或者位置选择性调控,实现内烯烃化合物尤其其他方法难以构建的多取代烯烃的高效合成,原子经济性高.详细介绍了钯催化烯烃异构化反应的反应机制,系统总结了钯催化的烯烃顺反异构和位置选择性异构反应,以及其在药物分子和天然产物合成中的应用.     

用于高性能锂-硫电池的氮化硼纳米片/碳纤维改性隔膜

通过静电纺丝、热亚胺化和碳化过程,将氮化硼纳米片(BNNSs)负载在碳纤维(CFs)表面,组成用于修饰商业聚丙烯(PP)隔膜的氮化硼纳米片/碳复合纤维(BNNSs/CFs)复合材料。BNNSs和CFs的协同作用为电池提供了额外的导电路径,并将可溶性多硫化锂固定在正极区域。结果表明,采用10BNNSs/CFs-PP隔膜的电池在0.05C下的初始放电容量高达1 295.7 mAh·g^-1,当电流密度增加到1C时,以10BNNSs/CFs-PP为隔膜的电池也具有良好的长期循环稳定性,在400次循环后最终容量高达568.1mAh·g^-1,每次循环容量衰减0.073%。     

光电发射光谱法分析钛合金中的主要合金元素

依据光电发射光谱仪光源激发机理,结合钛合金的材料性能,选用火花放电激励光源和时间分解脉冲分布测光法,绘制钛合金中主要合金元素的工作曲线,对A l、V、Fe、S i、C、Mn、Cu、Mo、Sn、Zr、N i、Cr等元素进行光谱直接测定。测定结果与化学法测定结果基本一致,测定结果的相对标准偏差为0.72%~4.27%(n=11)。     

高速通用数字调制器的设计与实现

为了提高调制器的灵活性和可扩展性,设计了一个中心频率和符号速率可调,且支持多种调制体制的高速通用数字调制器方案,并能产生中频为80MHz,带宽为7.9365MHz的正交相移键控（QPSK）信号和16QAM（正交幅度调制）信号。集中论述基于软件无线电的通用调制算法、符号映射原理和高速成形滤波模块的具体实现。测试结果表明,该方案开放性好,结构简单,体积小,具有一定的实用性和通用性。