复杂矿样中锡钨的联合测定

砷、锑、铜、氟等对锡的碘量法和钨的硫氰酸盐比色法均有干扰,当分析上述元素含量较高的矿样时,需要预先分离。为此进行加硫酸铵焙烧除砷的试验,並用含磷酸钠或EDTA而适当提高碱度的浸出液浸出以减少铁、钙、镁对锡、钨的吸附和有利于锡转化为锡酸钠于溶液中。试样经焙烧后砷、锑、氟等被驱除,再碱熔水浸则使铁、钙、镁、钛、锰、锆、钡、银、金、铋、镉、钴、汞、镍、钍、铌、钽和稀土元素,以及绝大部份铜进入沉淀,只有铝、锌、钼、铬     

新一代宽带数字电缆的研发

介绍6类、7类数字通信电缆的设计要领、结构特点,阐述其工艺控制及设备要求,并指出6类、7类电缆的巨大市场潜力。     

非晶态As2S8薄膜波导光阻断效应切断过程研究

采用真空镀膜技术在石英基板上制备了纯As2 S8以及掺杂As2 S8平面波导,通过棱镜耦合技术观察了光阻断效应.结合S和As的外层电子构型,分析了样品内部的化学键结构,利用电子能带结构理论和杂化轨道理论,建立了光阻断效应的动力学方程,并对切断过程进行了数值分析,分析结果与实验数据十分符合,得出该模型能很好地解释光阻断效...     

中医用高精度阵列脉搏传感器的设计

提出了一种可以把脉搏压力信号直接转换为电流信号输出的高精度阵列脉搏传感器.采用牺牲层法加工晶体管的栅极与CMOS工艺具有良好的兼容性.对传感器栅电容和输出电流进行测试,在1.5～9.5kPa的动态范围,传感器电容的灵敏度约为0.5fF/hPa;传感器输出电流与压力呈现较好的线性和指数特性.分析结果表明MOS栅面积的改变对压力-电流响应曲线的线性度有一定影响.     

Eu(DBM)_3Phen掺杂聚甲基丙烯酸甲酯静电纺丝荧光纤维

通过静电纺丝技术获得直径约为700 nm,均匀且随机取向的亚微米级Eu(DBM)3Phen/PMMA纤维。在紫外光辐射下,亚微米级荧光纤维发出明亮的红色荧光。其激发光谱表明,荧光纤维有效激发波长范围为200~400 nm。利用积分球配以CCD探测器,在367 nm长波紫外LED激发下对荧光纤维开展绝对光谱功率测试。当LED泵浦功率为535.76#W时,厚度80#m的Eu(DBM)3Phen/PMMA纤维薄层对紫外辐射的吸收率高达89%,350~850 nm范围内发射的总绝对光谱功率、总光子数和总荧光量子产率分别为36.56#W、11.46×10~(13)cps和12.94%。亚微米级Eu(DBM)_3Phen/PMMA纤维薄层中,Eu~(3+)较高的跃迁发射几率及较大的发射截面使得纤维可以高效吸收紫外辐射并转变为可见光,在提高太阳能电池光电转换效率方面具有潜在应用价值。     

Thermoelectric properties of lower concentration K-doped Ca_3Co_4O_9 ceramics

The tuning of electron and phonon by ion doping is an effective method of improving the performances of thermoelectric materials. A series of lower concentration K-doped Ca_(3-x)K_xCo_4O_9(x = 0, 0.05, 0.10, 0.15) polycrystalline ceramic samples are prepared by combining citrate acid sol-gel method with cold-pressing sintering method. The single-phase compositions and plate-like grain morphologies of all samples are confirmed by x-ray diffraction and field emission scanning electron microscope. The effects of lower concentration K doping on the thermoelectric properties of the material are evaluated systematically at high temperatures(300–1026 K). Low concentration K doping causes electrical conductivity to increase up to 23% with little effect on the Seebeck coefficient. Simultaneously, the thermal conductivity of K-doped sample is lower than that of the undoped sample, and the total thermal conductivity reaches a minimum value of approximately1.30 W·m~(-1)·K~(-1), which may be suppressed mainly by the phonon thermal conduction confinement. The dimensionless figure-of-merit ZT of Ca_(2.95)K_(0.05)Co_4O_9 is close to 0.22 at 1026 K, representing an improvement of about 36% compared with that of Ca_3Co_4O_9, suggesting that lower concentration K-doped Ca_3Co_4O_9 series materials are promising thermoelectric oxides for high-temperature applications.     

A Lattice Boltzmann Model for Fluid-Solid Coupling Heat Transfer in Fractal Porous Media

We report a lattice Boltzmann model that can be used to simulate fluid-solid coupling heat transfer in fractal porous media. A numerical simulation is conducted to investigate the temperature evolution under different ratios of thermal conductivity of solid matrix of porous media to that of fluid. The accordance of our simulation results with the solutions from the conventional CFD method indicates the feasibility and the reliability for the developed lattice Boltzmann model to reveal the phenomena and rules of fluid-solid coupling heat transfer in complex porous structures.     

饱和液氮爆发沸腾实验与传热机理分析

瞬态高热流加热下饱和液氮会发生爆发沸腾,而对于该过程的特殊传热机理因素,目前还没有相关的深入研究和分析。本文基于实验,在总结沸腾传热机理研究成果的基础上,重点分析了饱和液氮爆发沸腾过程中以汽泡群形态实现热量传递的特殊之处,并进行了理论模拟验证。结果表明,汽泡群内部众多汽泡所发生的破裂收缩行为,会释放潜热并形成热流,成为爆发沸腾独特的传热机理影响因素。     

掺杂As2S8非晶态薄膜波导的光阻断效应

实验研究了未掺杂和低浓度掺锡和掺磷的As₂S₈薄膜波导的光阻断效应,提供了三种样品的光阻断响应曲线、室温退激实验数据和光谱测试数据. 结果表明,掺锡样品可以明显提升毫秒级响应的快过程恢复作用,同时还具有减少残留传输损耗的效果,掺磷的效果则相反. 结合实验结果给出了分析讨论. 关键词： 光波导技术 硫属化合物玻璃 光阻断效应 掺杂     

IKAROS太阳帆第一阶段展开过程的动力学行为分析

空间结构的在轨展开涉及到复杂的高维强非线性动力学问题,这些动力学问题的建模及仿真技术是航天动力学领域的难题,也是对在轨展开过程施加控制的前提条件。本研究以IKAROS太阳帆在轨第一阶段展开过程为例,基于哈密顿变分原理,建立中心刚体-主动伸长柔性梁耦合动力学模型;采用保结构分析方法,关注动力学系统的局部动力学行为,在恒定转矩驱动和恒定功率驱动两种工况条件下,对IKAROS太阳帆第一阶段展开过程进行仿真;发现两种工况条件下的中心刚体转动角速度演化规律差别显著,恒定转矩做功将导致中心刚体的转动稳定性变差,同时,恒定功率驱动工况下,IKAROS太阳帆第一展开阶段节能效果较好。