一类含临界指数和凹项的非局部问题多重正解的存在性

本文研究一类含临界指数和凹项的非局部问题.利用山路引理及Ekeland变分原理等变分方法,获得了该类型问题至少存在两个正解.     

Fundamental and progress of Bi_2Te_3-based thermoelectric materials

Thermoelectric materials,enabling the directing conversion between heat and electricity,are one of the promising candidates for overcoming environmental pollution and the upcoming energy shortage caused by the over-consumption of fossil fuels.Bi_2Te_3-based alloys are the classical thermoelectric materials working near room temperature.Due to the intensive theoretical investigations and experimental demonstrations,significant progress has been achieved to enhance the thermoelectric performance of Bi_2Te_3-based thermoelectric materials.In this review,we first explored the fundamentals of thermoelectric effect and derived the equations for thermoelectric properties.On this basis,we studied the effect of material parameters on thermoelectric properties.Then,we analyzed the features of Bi_2Te_3-based thermoelectric materials,including the lattice defects,anisotropic behavior and the strong bipolar conduction at relatively high temperature.Then we accordingly summarized the strategies for enhancing the thermoelectric performance,including point defect engineering,texture alignment,and band gap enlargement.Moreover,we highlighted the progress in decreasing thermal conductivity using nanostructures fabricated by solution grown method,ball milling,and melt spinning.Lastly,we employed modeling analysis to uncover the principles of anisotropy behavior and the achieved enhancement in Bi_2Te_3,which will enlighten the enhancement of thermoelectric performance in broader materials     

一种环形栅LDMOS器件的宏模型

提出了一种适用于环形栅LDMOS器件的子电路宏模型。基于对环形栅LDMOS器件结构的分析,将环形栅LDMOS器件分为两个部分,一个是中间的条形栅MOS部分,使用常规的高压MOS模型；另一个是端头部分,为一个圆环形栅极MOS器件,采用了一个单独的模型。基于40 V BCD工艺的N沟道LDMOS器件进行模型提取与验证。结果表明,建立的宏模型具有较强的几何尺寸缩放功能,对于不同尺寸的器件都具有较高的拟合精度,并且模型能够兼容当前主要的商用电路仿真器Hspice和Spectre。     

基于结构方程模型的中国高等教育融资绩效测度研究

高等教育融资规模不足、融资效率不高的问题是长期困扰高校发展的一个难题,加强对各类高等教育融资方式融资绩效的研究,有利于高校在不同发展阶段选择不同的融资方式,不断优化融资组合.高等教育融资绩效的来源可以从成本因素、制度因素、结构因素、能力因素与风险因素等方面加以探讨,并对现阶段不同融资渠道的融资绩效加以检验.首先基于对教...     

弱桥联二聚体丙酮酸异烟酰腙合锡(Ⅳ)配合物[(p-CNC6H4CH2)2Sn(C9H7N3O3)(H2O)]2的合成、表征和晶体结构

Diorganotin(Ⅳ) compound [(p-CNC₆H₄CH₂)₂Sn(C₉H₇N₃O₃)(H₂O)]₂ was synthesized by the reaction of tri-p-cyanobenzyltin chloride with Schiff base ligand pyruvic acid isonicotinyl hydrazone. The compound was characterized by elemental analysis, IR, ¹H NMR. The crystal structure was determined by X-ray single crystal diffraction. The crystal belongs to monoclinic space group C2/c, with a=3.143 1(3) nm, b=0.989 99(10) nm, c=1.785 68(18) nm, β=114.908 0(13)°, V=5.039 6(9) nm³, Z=4, μ=1.054 mm^-1, D_c=1.513 Mg·m^-3, F(000)=2 304, R=0.042 8, wR=0.090 3, GOF=0.997. In this compound, the Sn atom exists in a distorted octahedral coordination environment in which one water molecule, one tridentate pyruvic acid isonicotinyl hydrazone ligand, and two trans p-cyanobenzyl groups coordinate to each Sn center, the angle of the axial C10-Sn1-C18 is 166.1(2)°. Two molecules form a weak-bridged dimmer with weak interactions of Sn…O bonding and hydrogen bonds. CCDC: 270796.     

丙酮酸异烟酰腙四核有机锡配合物的合成、表征及{[nBu2Sn(C9H8N3O3)O]SnBu3n}2的晶体结构

The tetranuclear alkyltin(Ⅳ) compounds {[R2Sn(C9H8N3O3)O]SnR3}2 [R=n-Bu (1), 4-CNC6H4CH2 (2),C6H5CH2 (3), 4-ClC6H4CH2 (4)] were prepared by the reaction of Schiff base ligand pyruvic acid isonicotinyl hydrazone with (R3Sn)2O in the corresponding molar ratio of 1:1. All compounds have been characterized by elemental analysis, IR and ^1H NMR spectra. The crystal structure of compound 1 was determined by X-ray single crystal diffractional analysis. This compound exhibits a dimeric structure containing distannoxane units with two types of the tin atoms. For the first tin atom, it appears to be seven-coordinated with a distorted pentagonal bipyramid geometry, and the other is five-coordinated with a distorted trigonal bipyramidal geometry. The molecules are packed in the unit cell in two-dimensional network structure through an interaction between the N atoms of the pyridine and the tin atoms of an adjacent molecule.     

基于纳米材料的表面辅助激光解吸离子化质谱研究

基质辅助激光解吸离子化质谱(MALDI-MS)作为一种常规的分析表征方法主要用于生物大分子的分析,如蛋白质、多肽、多糖及核酸等.然而,MALDI-MS中使用的有机小分子基质在低分子量区会产生背景干扰,很难分析小分子量化合物(m/z < 700).最近,基于纳米材料的免有机基质的激光解吸离子化质谱(又称为表面辅助激光解吸离子化质谱,SALDI-MS)有效解决了上述问题.SALDI-MS分析中使用的起到能量转移作用的纳米材料在低分子量区间不会产生背景干扰峰,可以将分析对象由大分子扩展到小分子.另外,SALDI-MS还具有许多其他优点,如样品制备简单、信噪比高、耐盐性好、基底表面信号重复性好及可实现样品的定量分析等,显示了较好的应用前景.本文综述了研究较多的四大类纳米材料在SALDI-MS分析、检测及成像方面的应用,包括碳纳米材料(富勒烯、碳纳米管、石墨烯及氧化石墨烯)、硅纳米材料(多孔硅、硅纳米纤维、硅纳米粒子)、其他材料纳米粒子(包括金属纳米粒子、金属氧化物纳米粒子、无机盐纳米粒子及量子点等)及纳米杂化多孔材料,详细介绍了最近的一些研究进展;并讨论了纳米材料在SALDI-MS应用中的能量转移机理.最后,讨论了该领域未来的研究内容和方向以及亟待研究的重要问题.     

应用于柔性电子的超薄硅基芯片研究进展北大核心

柔性电子技术在近些年得到了快速发展，越来越多的柔性电子系统需要柔性、高性能的集成电路来实现数据处理和通信。通过减薄硅基芯片可以获得高性能的柔性集成电路，但是硅基芯片减薄之后的性能有可能发生变化，并且在制备、转移、封装的过程中极易产生缺陷或者破碎，导致芯片性能退化甚至失效。因此，超薄硅基芯片的制备工艺和柔性封装技术对于制备高可靠性的柔性硅基芯片十分关键。在此背景下，文章综述了柔性硅基芯片的力学和电学特性研究进展，介绍了几种超薄硅基芯片的减薄工艺和柔性封装前沿技术，并对超薄硅基芯片在柔性电子领域的应用和发展进行了总结和展望，为柔性硅基芯片技术的进一步研究提供参考。