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971.
Metallophthalocyanine (MPc) twin-layer thin films on glass substrates, consisting of copper phthalocyanine (CuPc) overlayer and amorphous vanadyl phthalocyanine (VOPc) as well as titanyl phthalocyanine (TiOPc) buffers, were found to have different gas sensing characteristics. These twin-layer thin films were studied using x-ray photoemission spectroscopy. Photoelectrons of either V or Ti core levels were found to be present at the surface, indicating the existence of possible molecular migrations. The stability of the twin-layers under thermal annealing up to a maximum temperature of 250℃ and low-energy Ar ion bombardment was also examined and compared with that of CuPc directly grown on the substrates. We concluded that the twin-layer structures were thermally fairly stable. Ar ion bombardment, however, caused substantial damage to the Pc ligands and a reduction of the valence state of the central Cu atoms. 相似文献
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In this paper by Sobolev imbedding theorem and characterization theorem of generalized operators the existence of P(φ)2 quantum fields as generalized operators is obtained and a rigorous mathematical interpretation of renormalization procedure is given under white noise theory. 相似文献
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977.
Tantalum nitride (TAN) thin films are achieved on Si(111) and SS317L substrates by cathodic vacuum arc technique, which is rarely reported in the literature. The crystal structure, composition and surface morphology of the films are characterized by x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), auger electron spectroscopy, and atomic force microscopy, respectively. The influence of substrate negative bias on crystal structure, composition, surface morphology of the TaN films is systematically studied. At the substrate bias of 0 V and -50 V, the amorphous TaN film is obtained. As the bias increases to -100 V, cubic TaN phase can be found. Stoichiometric TaN with hexagonal lattice preferred (300) orientation is prepared at a bias of -200 V. Combine the XRD and XPS results, the binding energy value of 23.6eV of Ta 4f(7/2) is contributed to hexagonal TaN. Compared to other techniques, TaN thin films fabricated by cathodic vacuum arc at various substrate biases show different microstructures. 相似文献
978.
The influence of Gd doping at La-site on the electrical transport properties and the colossal magnetoresistance of La0.7-xGdxSr0.3MnO3 (x = 0.00, 0.10, 0.15, 0.20, 0.30, 0.40, 0.50, 0.60, and 0.70) is studied. The experimental results indicate that the transport properties exhibit abnormal behavior under high doping condition. For x = 0.50, we find that a transition from metal to insulator occurs after the occurrence of insulator-metal transition near Tc, which seldom occurs in ABO3 structure. For samples x = 0.60 and 0.70, it exhibits insulator behavior far above Tc. These abnormal behaviors are attributed to different magnetic background, i.e. the system undergoes a transition from long range ferromagnetic order to the cluster-spin glass state and further to antiferromagnetic order. 相似文献
979.
In this paper we prove the pathwise uniqueness of a kind of two-parameter Volterra type stochastic differential equations under the coefficients satisfy the non-Lipschitz conditions. We use a martingale formula in stead of Ito formula, which leads to simplicity the process of proof and extends the result to unbounded coefficients case. 相似文献
980.
面向“信息孤岛”数据互操作模型的研究 总被引:2,自引:0,他引:2
文章在介绍“信息孤岛”产生的背景、存在的问题以及国内外主要的解决方法的基础上,提出了基于智能Agent机制的Web环境下分布式“信息孤岛”中数据的互操作模型。该模型以CORBA规范为基准,利用Java技术来解决在电子政务建设过程中产生的“信息孤岛”问题。 相似文献