多光子激发相干态的Wigner函数

Wigner函数的负性是非经典量子态的重要判据之一.利用Fock态表象下Wigner函数的一般表达式,重构了相干态｜z〉的k光子激发态｜+k,z〉～a^－k｜z〉（k≥1）的Wigner函数,并根据其数值结果讨论了该量子态的非经典特性（这里a^－1为Bose湮没算符的逆算符,其作用相当于Bose产生算符）.结果表明,不论k取奇数还是偶数,相干态的这些k光子激发态都具有非经典特性;而且k的取值越大,这些量子态的非经典特性越明显. 关键词： 非经典量子态 激发相干态 Wigner函数 非经典特性     

含新结构单元[Co3(SS)3(PR3)3]的钴化合物的磁性研究

通过含新结构单元钴化合物:Co₃(bdt)₃(PBu₃)₃(Ⅰ),Co₃(tdt)₃(PBu₃)₃(Ⅱ),[Co₃(bdt)₃(PPh₃)₃][CoBr₃(dmf)](Ⅲ)和[Co₃(edt)₃(PEtB)₃]₂[Co₂Cl₄(Et₂SO₂)₂](Ⅳ)(bdt=1,2-S₂C₆H₄^2-,tdt=4-Me-1,2-S₂C₆H₃^2-,edt=SCH₂CH₂S^2-)的磁极矩和¹H NMR等研究表明:它们均具顺磁性,钴原子之间存在着反铁磁偶合作用,同时还讨论了它们的磁学性质和分子结构之间关系。     

串列加速器放射性次级束流线上的核天体物理反应研究

通过在串列加速器次级束流线上开展反应等的研究,导出天体物理S因子;通过反应的研究,探索核的内部结构.初步得出反应的渐进归一化常数平方为3.5±1.5,表明直接反应的贡献不可忽略.     

F离子掺杂TiO2的性能研究

以NH₄F为掺杂剂,采用溶胶-凝胶法制备F离子掺杂型TiO₂光催化剂,对其进行XRD、XPS和PL表征,结果表明,F离子掺杂TiO₂由于Ti-F配位体的形成而能抑制金红石相的生成,同时F离子掺杂能增加TiO₂表面缺陷浓度并降低Ti_2P键的结合能,另外,由于F离子能取代Ti-OH配位体而降低了表面羟基氧浓度.光催化研究结果表明,F离子掺杂提高了TiO₂光催化活性近1.5倍.     

紫外光还原法制备铂填充硅钛复合纳米管及其光催化性能

以SiO2包覆的TiO2纳米管(TiNT@@SiO2)为载体,以H2PtCl6为前驱体,采用紫外光还原法制备了Pt纳米粒子填充的TiNT@@SiO2材料(Pt-TiNT@@SiO2).并采用透射电镜、场发射扫描电镜、电子能谱和X射线衍射等手段对材料样品进行了表征,考察了制备时紫外光照时间和强度以及Pt填充量对其形貌的影...     

Cobalt(Ⅱ) and Cadimium(Ⅱ) Metal-organic Frameworks Supported by a Multicarboxylate Ligand

Two metal-organic frameworks(MOFs) of formulae [Co_7(L)_3(4,4?-BPy)_2(OH)_2(H_2O)_6]·-4 H_2O(1) and [Cd_2(L)(2,2?-BPy)2]n(2, H_4L = 5-(3,5-dicarboxybenzyloxy)-isophthalic acid,2,2?-BPy = 2,2?-bipyridine, 4,4?-BPy = 4,4?-bipyridine) were synthesized under solvothermal conditions. The structures of 1 and 2 were characterized by X-ray single-crystal diffraction analysis.In complex 1, six cobalt atoms were connected by oxygen atoms to form a defect dicubane structure. The defect dicubane structures were further linked by Co(4,4?-BPy) units to generate a3-D network structure. Compound 2 displays a 2-D chain structure. The photoluminescent property of complex 2 is investigated. The results show the exclusive luminescence emission bands being originated from intraligand π-π* transitions.     

玉米亚正常籽粒生活力近红外光谱判别方法研究

应用近红外光谱分析技术,针对玉米诱导过程中产生的亚正常种子,发展亚正常种子的单籽粒生活力判别方法。该研究应用了一种基于Kolmogorov-Smirnov检验的方法(KS法)对近红外光谱进行特征提取,并比较了十种采用不同预处理数据和特征提取方法建立的模型的判别性能,每种模型试验了1134种参数组合,并对采用多种方法和参数组合建立的模型进行交叉验证。结果表明,采用矢量归一化预处理,KS法提取特征波长,并去除低信噪比区域的数据建立的模型判别效果最好。发芽籽粒和不发芽籽粒的平均正确识别率分别达到92.20%和84.86%。该方法将发芽籽粒的筛选准确率由随机筛选的不足40%提高至85%以上,可显著提高筛选效率。     

Evaluation of the 1077 keV γ-ray emission probability from 6SGa decay

6SGa decays to the excited states of aSzn through the electron capture decay mode. New recommended values for the emission probability of 1077 keV γ-ray given by the ENSDF and DDEP databases all use data from absolute measurements. In 2011, JIANG Li-Yang deduced a new value for 1077 keV γ-ray emission probability by measuring the 69Ga（n,2n） 6SGa reaction cross section. The new value is about 20% lower than values obtained from previous absolute measurements and evaluations. In this paper, the discrepancies among the measurements and evaluations are analyzed carefully and the new values are re-recommended. Our recommended value for the emission probability of 1077 keV γ-ray is （2.72±0.16）%.     

云教学在化学师范生数字化实验课中的应用研究*

结合本校化学教学论实验的教学现状,融合云教学及翻转课堂理念对教学进行重构,设计并实施以“蓝墨云班课”云平台为师生互动桥梁的翻转课堂云教学。以中学化学数字化实验教学为例,让化学师范生以“学习者”和“未来教师”的双重角色体验翻转课堂云教学的学习过程,并利用SERVQUAL模型评价法对云教学进行数据分析、反馈完善。通过进一步问卷分析,了解到学生不仅熟练地掌握了所学知识内容,而且对翻转课堂模式与实施细节有了更为深刻的理解,最后对翻转课堂云教学及师范生教学提出了几点建议。     

First-Principles Calculation of Electronic Structure and Optical Properties of Sb-Doped ZnO

The geometric structure, electronic structure, optical properties and the formation energy of Sb-doped ZnO with the wurtzite structure are investigated using the first-principles ultra-soft pseudo-potential approach of plane wave based upon the density functional theory. The calculated results indicate that the volume of ZnO doped with Sb becomes larger, and the doping system yields the lowest formation energy of Sb on the interstitial site and the oxygen site. Furthermore, Sb dopant first occupies the octahedral oxygen sites of the wurtzite structure. It is found that Sb substituting on oxygen site behaves as a deep acceptor and shows the p-type degenerate semiconductor character. After doping, the electron density difference demonstrates the considerable electron charge density redistribution, which induces the effect of Sb-doped ZnO to increase the charge overlap between atoms. The density of states move towards lower energy and the optical band gap is broadened. Our culated results are in agreement with other experimental results and could make more precise monitoring and controlling possible during the growth of ZnO p-type materials.