排序方式: 共有27条查询结果,搜索用时 359 毫秒
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通过"人工光合成"过程,将太阳能转化成氢能的形式加以存储和利用,是替代传统化石能源的清洁能源的制备有效途径.其中,光电化学分解水是氢能制备的最有潜力的路径之一.n型BiVO4由于具有丰富的储量、较窄的带隙以及合适的能带位置,被称为光电化学领域的研究热点.然而,未修饰的BiVO4光阳极性能并不理想,主要原因在于载流子复合严重、导电性差以及表面催化动力学低等性质的制约.科研工作者们针对这些方面已进行了非常多的研究,例如与电子传输层的复合、产氧电催化剂的担载以及异质结的构建等.其中表面动力学和电荷分离的同时提升是更理想的改善BiVO4光阳极性能的方法.我们在上述研究基础上,采用光化学沉积法在纳米多孔BiVO4电极表面担载无定形氧化铁层,将电极在1.23 V vs.RHE电位下的光电流提升至2.52 mA/cm2,是初始光电化学性能的3倍.采用间歇光照计时电流(i-t)测试,电化学交流阻抗谱(EIS),X射线光电子能谱(XPS),原位和非原位的X射线精细结构能谱(in-situ and ex-situ XAFS)等表征手段研究了无定形氧化铁层的成分和光电化学反应过程中的价态变化,从而分析出光电化学性能提升的原因.间歇光照i-t测试和EIS测试结果表明,无定形氧化铁沉积在BiVO4使电荷累积减少,复合率降低.XPS测试结果发现无定形氧化铁层存在少量的二价铁成分.通过原位XAFS测试发现,BiVO4/FeOx电极中Fe原子的价态在光照和施加外加偏压条件下会有价态的升高,而撤去光照和偏压后Fe原子的价态状态与最初非原位的测试结果重合.这样的结果证明了无定型氧化铁层在光电化学反应过程中由于二价铁成分的存在,能够很好的通过价态改变实现空穴的吸附和传输,即吸附空穴,被空穴氧化成三价或四价,同时结合自身电催化活性,促进表面分解水反应的进行.而水的氧化反应结束时,则伴随着二价铁离子的再生成.这种反应机理为开发更高效的电催化剂,匹配光电极使用,有着重大的指导意义. 相似文献
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An Encryption-Decryption Method Using XOR Gate Based on the XPM between O-Band and C-Band Light Waves
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An all-optical encryption-decryption method using an exclusive-or gate based on the cross-phase modulation between O-band and C-band light waves is proposed. The feasibility of the encryptionecryption technique is verified by handling binary signals at 2.5 Gbps, with less than 3dB penalty of extinction ratio and i dB polarization dependent loss. 相似文献
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Generalized Principal-State-of-Polarization Analysis and Matrix Model for Piezoelectric Polarization Controllers
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We introduce a generalized concept of principal state of polarization (PSP) to analyse the piezoelectric polarization controller (PPC) and find each PPC unit can be described by a rotation matrix determined by the PSP. Our PPC has three components, each made of a jaw and a piezoelectric actuator with the squeezing direction tilted 0°, 45° and 0°, which are driven by a tunable power supply. We demonstrate that all the polarization rotation angles are linear to driving voltages and the PSP of unit 2 is nearly orthogonal to others which are almost equal. Taking some approximate treatments we obtain the matrix model of our PPC with respect to three driving voltages. The average error of our theoretical model is 1.51°, and the polarization response time is 〈50 μs, which is promising to realize an open-loop control of polarization. 相似文献
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Mueller matrix analysis for all optical fiber co-existence of birefringence-polarization dependent gain-mode coupling at a single wavelength
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Birefringence (polarization-related phase-shift), polarization dependent gain (PDG) and mode coupling are three factors that may synchronously influence the transmission of single-wavelength polarized light in optical fibers. This paper obtains a new Mueller matrix analysis, which can be used under conditions that all these three factors are existing and changing. According to our transmission model, the state of polarization (SOP) changes along an optical microstructure fiber with co-existence of birefringence-PDG-mode coupling were simulated. The simulated results, which show the phenomena of SOP constringency, are in good agreement with previous theoretical analyses. 相似文献
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受限于环境、通信频度和通信容量等因素,基于北斗的人防警报控制系统存在数据发送延迟高、排队较长和丢包等问题,无法保证警报控制的实时性和可靠性。为此,提出了一种实现北斗三号短报文可靠传输的方法。在北斗人防通信协议中增加“丢包率控制”字段,减少发送图片/语音等长数据时不必要的丢包重传次数,减少传输时间;在此基础上,利用北斗三号指挥型用户机阵列实现轮询发送人防统控通信数据,有效解决北斗通信频度的限制因素,提高人防系统数据传输的通信效率。通过采用差异化可靠通信机制,在不影响用户体验的条件下,极大地提高了消息的实时性和可靠性。对比实验结果表明,该方法可以有效提升人防统控系统的可靠性和传输效率。 相似文献