金属酞菁化合物在TiO2表面的分散研究

Dispersion of copper(Ⅱ) phthalocyanine (CuPc), copper(Ⅱ) phthalocyaninesulfonate (CuPcS) and cobalt(Ⅱ)phthalocyaninetetrasulfonate (CoPcTS) on the surface of titanium dioxide was investigated by XRD, XPS, FT-IR and UV-Vis techniques. Results show that interaction between CuPc and TiO2 was very weak and CuPc was difficult to disperse on the surface of the support. While partly sulfurized CuPcS could be dispersed on the surface of support through sulfo-groups and its dispersion capacity was determined to be 0.085 g CuPcS/g TiO2. Completely sulfurlzed CoPcTS could also be dispersed on the surface of TiO2 as a monolayer and its dispersion capacity was 0.12 g CoPcTS/g TiO2. Interactions of the sulfo-groups as well as the electrons of CoPcTS with the surface of TiO2 could be evidenced by FT-IR characterization. Therefore, it was suggested that CoPcTS molecules be adsorbed on the surface of TiO2 in a flat-lying mode while CuPcS in a slanting one. UV-Vis spectra show that the dispersed CuPcS and CoPcTS molecules exist in both forms of monomers and dimers.     

硫化物纳米级粒子化膜的形成与气相性质的影响

采用偏振光反光度、紫外及可见光谱、电子显微镜形貌观察、粒子大小测定及电子衍射等方法加以系统研究硫化锌纳米级粒子化膜的制备与气相性质的影响．     

希托夫法求离子迁移数计算通式

在研究电解质溶液理论时,通过计算离子迁移数,可以求出电解质溶液中离子电导、离子淌度、电位梯度等一系列重要物理量。离子迁移数常用的实验室测定方法有:希托夫(Hittof)法、界面移动法和电动势法。其中希托夫法在目前物理化学教材中没有简便统一的计算公式可循。笔者结合教学实践,根据离子迁移数定义与不同情况下离子在阴、阳极区电解前后浓度变     

Synthesis and Characterization of Poly（butylene adipate-co-terephthalate） Catalyzed by Rare Earth Stearates

Rare earth （Nd, Y, La, Dy） stearates have been synthesized and used as single component catalysts for the polycondensation of dimethyl terephthalate, adipic acid and 1,4-butanediol for the first time preparing biodegradable poly（butylene adipate-co-terephthalate） （PBAT） with high molecular weight, The microstructures of PBAT were characterized by ^1H NMR spectra. The PBAT exhibits good mechanical properties such as high tensile strength （ca. 20 MPa） and long break elongation （〉700%）.     

Isolation, Mapping, DNA Sequence and RFLPs Studies of Random Single-Copy DNA Segments on Human X Chromosome

Using the total human/mouse DNA as the probe, screening has been carried out three times with in situ plaque hybridization to obtain the single-copy DNA sequence from the human X chromosome genomic library. The effective rate of screening is 1. 45%. DNAs from clones containing single-copy inserts have been analyzed by a panel of hybrid cells with or without human X chromosome. Three segments, designated by DXFD52,73,75, are mapped to the X chromosome. DXFD52 has been precisely localized on Xq12-q13 with in situ chromosomal hybridization. DXFD52 has been partially sequenced. The results indicate that DXFD52 is a new isolated single-copy segment on the X chromosome. Great progress in the RFLPs study with DXFD52 has been achieved in the population of Chongqing, Sichuan Province. The results show that the DXFD52 can be used to detect the RFLP with Hind Ⅲ, Bgl Ⅱ, and Hinf Ⅰ. DXFD52 will be a potential "landmark" for the construction of the complete linkage map of human genome and the analysis of genomic s     

基于改进U-Net的低剂量CT图像重建方法

针对低剂量CT图像重建会产生噪声和伪影的问题,在U-Net神经网络基础上引入残差学习和空间注意力机制,在编解码过程中嵌入跳跃连接为上采样增加多尺度信息,使用AAPM公开数据集CT影像进行模型训练和测试。选取峰值信噪比（PSNR）、结构相似性（SSIM）和均方根误差（RMSE）作为图像性能评价指标。在CT重建结果的测试中,与未处理的图像相比,网络模型处理后图像的PSNR、SSIM和RMSE指标平均值分别提升21.699%、2.263%和40.833%。实验结果表明,改进的U-Net神经网络模型能够减少噪声和伪影,保留了更多的纹理细节,对低剂量CT重建图像质量的提高有一定效果。     

基于铌酸锂薄膜的Y波导集成调制器设计

近年来,基于薄膜铌酸锂（TFLN）平台的高性能电光调制器以其小体积、低能量损耗等特点受到广泛关注。本文提出了一种新的具有垂直电极结构的Y波导铌酸锂薄膜电光调制器。研究了调制器的半波电压与缓冲层厚度之间的关系,优化了Y波导的设计参数,最后设计得到插入损耗<5 dB, 半波电压<1.5 V的高性能调制器。本文不仅为基于TFLN平台的小型化波导的设计和实现提供了思路,而且为制造高性能和多功能的电光调制器提供了实验依据。     

支持车联网的无线光信道副载波调制方法

传统载波调制方法存在较高的误码率缺陷,为此提出了支持车联网的无线光信道副载波调制方法。首先建立车联网环境下的无线光信道模型,从频率和时间两个方面分析无线光信道的选择性衰落特性,然后设计无线光信道副载波调制框架,以子符号加和的方式,调制无线光信道副载波信号,支持车联网运行。实验结果:相对对比方法,在不同信道信噪比条件下,所提方法的误码率均值较三组对比方法分别减小0.000 079 5 bit/s、0.000 044 5 bit/s、0.000 002 bit/s;在不同副载波调制阶数和传输速率条件下,所提方法的无线光信道通信时具有较小的误码率。     

静电喷印技术在太赫兹超表面制备中的应用

近年来,太赫兹技术快速发展,基于超表面的太赫兹器件受到广泛关注,并已应用于太赫兹成像、光谱和生物传感等诸多领域。但太赫兹超表面器件的制备复杂且成本高,而静电喷印技术无需掩模版,成本低、精度高且易于在异形曲面上制作。基于静电喷印技术设计和制备了太赫兹吸波器,并利用太赫兹时域光谱系统（THz-TDS）对样品进行了性能测试,实验与仿真结果基本相符,在0.098~0.353 THz频段内吸收大于90%。此外,还设计了太赫兹线极化转换器,在0.167~0.355 THz频段内的极化转换大于95%,相对带宽约72%,并分析了所设计样品的制备工艺条件,验证了静电喷印技术对于制备太赫兹极化转换器的可行性。研究成果表明,静电喷印技术在太赫兹超表面器件的制备中具有广泛的应用前景。     

札赉诺尔褐煤轻度氧解制取腐殖酸的反应条件考察

札赉诺尔褐煤易被稀硝酸或热空气氧化,并能得到高收率的再生腐殖酸.用硝酸氧化的最佳条件为:温度50℃,反应时间1小时,硝酸浓度10%,硝酸添加量:煤=0.5:1;用热空气在沸腾层内氧化24小时,温度为220℃,可得到75%收率的氧化煤,含腐殖酸90%(无水无灰基).对氧化煤的若干性质作了分析.氧化煤可用稀氨水或氨-空气混合物氨化.其氨化产物为多效的水溶性有机化学肥料,亦为一有效的陶瓷泥浆处理剂.