全文获取类型
收费全文 | 6380篇 |
免费 | 231篇 |
国内免费 | 183篇 |
专业分类
化学 | 4894篇 |
晶体学 | 1篇 |
力学 | 58篇 |
综合类 | 3篇 |
数学 | 197篇 |
物理学 | 1269篇 |
无线电 | 372篇 |
出版年
2024年 | 87篇 |
2023年 | 177篇 |
2022年 | 282篇 |
2021年 | 163篇 |
2020年 | 62篇 |
2019年 | 70篇 |
2018年 | 53篇 |
2017年 | 71篇 |
2016年 | 38篇 |
2015年 | 61篇 |
2014年 | 98篇 |
2013年 | 73篇 |
2012年 | 663篇 |
2011年 | 865篇 |
2010年 | 203篇 |
2009年 | 90篇 |
2008年 | 524篇 |
2007年 | 535篇 |
2006年 | 562篇 |
2005年 | 447篇 |
2004年 | 284篇 |
2003年 | 233篇 |
2002年 | 182篇 |
2001年 | 167篇 |
2000年 | 161篇 |
1999年 | 96篇 |
1998年 | 104篇 |
1997年 | 23篇 |
1996年 | 39篇 |
1995年 | 29篇 |
1994年 | 66篇 |
1993年 | 81篇 |
1992年 | 69篇 |
1991年 | 29篇 |
1990年 | 40篇 |
1989年 | 15篇 |
1988年 | 8篇 |
1987年 | 7篇 |
1986年 | 6篇 |
1985年 | 7篇 |
1984年 | 7篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1975年 | 1篇 |
1966年 | 1篇 |
1965年 | 2篇 |
1964年 | 2篇 |
1951年 | 1篇 |
排序方式: 共有6794条查询结果,搜索用时 437 毫秒
1.
Hao Lu Xiaodong Wang Hang Wang Andong Zhang Xinming Zheng Na Yu Zheng Tang Xinjun Xu Yahui Liu Ya-Nan Chen Zhishan Bo 《中国科学:化学(英文版)》2022,65(3):594-601
Three nonfused ring electron acceptors (NFREAs) TTC6,TT-C8T and TT-TC8 were purposefully designed and synthesized.The molecular geometry can be adjusted by the steric hindrance of lateral substituents.According to the DFT calculations,from TTC6 to TT-C8T and TT-TC8,planarity of the molecular backbone is gradually improved,accompanying with the enhancing of intramolecular charge transfer effect.As for TT-TC8,the two phenyl substituents are almost perpendicular to the molecular backbone,which endues the acceptor with good solubility and suppresses it to form over-aggregation.Multidirectional regular molecular orientation and closer molecular stacking are formed in TT-TC8 film.As a result,TT-TC8 based devices afford the highest PCE of 13.13%,which is much higher than that of TTC6 (4.41%) and TT-C8T (10.42%) and among the highest PCE values based on NFREAs. 相似文献
2.
Difeng Yin Yucen Li Lingling Xia Wenbo Li Wei Chu Jianping Yu Miao Wu Ya Cheng Ming Hu 《中国化学快报》2022,(2):1077-1080
Despite the continuously increased requirement on automated synthesis of medicines for distributed manufacturing and personal care, it remains a challenge to realize automated synthesis which requires solid-liquid phase reactions. In this work, we demonstrated an automated solid-liquid synthesis for gadopentetate dimeglumine, the most widely used magnetic resonance imaging(MRI) contrast agent. The high-efficiency reaction was performed in a 3 D microfluidic chip which was fabricated by femtoseco... 相似文献
3.
Xiangwen Kong Fang Yu Shengtong Niu Fan Gong Shuang Yang Jinggong Liu Benlong Luo Xinqiang Fang 《中国化学快报》2022,33(6):2997-3002
Copper-catalyzed divergent annulations between α-diketones and alkynyl α-diketones have been achieved, delivering a series of highly functionalized and biologically important cis-hexahydro-2Hcyclopenta[b]furan(HCPF) and 2-hydroxydihydrofuran-3(2H)-one(HDFO) products with high levels of stereoselectivity under identical conditions. The protocol features the use of earth-abundant copper catalyst, mild conditions, shortening synthetic routes in constructing different molecular frameworks, and reduc... 相似文献
4.
The simulation and analysis of S-shaped waveguide bend are presented.Bend radius larger than 30 mm assures less than 0.5 dB radiation loss for a 4-μm-wide silicon-on-insulator waveguide bend with 2-μm etch depth.Intersection angle greater than 20° provides negligible crosstalk (<-30 dB) and very low insertion loss.Any reduction in bend radius and intersection angle is at the cost of the degradation of characteristics of bent waveguide and intersecting waveguide, respectively. 相似文献
5.
Ri Cheng XUAN* Wei Xiao HU Zhong Yu YANG Ya Ping LU College of Pharmaceutical Sciences Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(2)
2-Chloro-5-methylpyridine is an important intermediate for the preparation of biological active compounds, especially insecticides1, e.g. imidacloprid2, and is usually manufac- tured from 3-methylpyridine N-oxide. However, the manufacturing process also forms the by-products: 3-methylpyridine and its isomer 2-chloro-3-methylpyridine3. The pro- perties of the isomers are similar, it is difficult to separate by ordinary methods, such as distillation. Scheme 1 79.4%13.6%5.2%NClCH3NCH3ClNC… 相似文献
6.
Zhong Hong YAN Chun Hao YANG Xi Han WU Yu Yuan XIEDivision of Chemistry Shanghai Second Medical University Shanghai Sate Key Laboratory of Drug Research Shanghai Institute of Materia Medica Shanghai Institutesfor Biological Sciences Shanghai 《中国化学快报》2004,(4)
The first and facile synthesis of (±)syringaresinol was described. 相似文献
7.
ZHANG Lin-bo LIU Xiao-hua JIANG Yuan GUO Ping SHA Li-jin LI Yu 《高等学校化学研究》2006,22(2):139-144
After establishing hemi-Parkinsonian rat models, the relationships between neuron death and the expression of several proteins, such as c-Fos, GFAP, GDNF, NF-κB and some cytokines were determined. Therapeutics experiments with notoginsenoside-Rg1 were carried out. The research results show that the expressions of GFAP, NF-Kκ and c-Fos will obviously increase in the lesion side of the striatum and the expression of GDNF will decrease, which implies that the signal transduction pathway may participate in the apoptosis in neurons. The levels of some cytokines such as TNF-α, IL-1β in the striatum of PD rat models increased compared to those of normal rats. The results of the therapeutics experiments show that notoginsenoside-Rg1 may repress the immune inflammation response and regulate the immune function through the neuro-immune molecular network. Therefore, notoginsenoside-Rg1 can be used as an effective drug for anti-oxidation and anti-inflammation, and can be used in the therapy of Parkinson's disease(PD). 相似文献
8.
9.
Yuan-Hui Yu 《中国电子科技》2007,5(3):215-217
The technical characters of mobile agent (MA) originated in the distributional artificial intelligence domain is introduced. A network management construction based on agent (NMCA) is then proposed. The NMCA structure features are elaborated in detail. A prototype design of NMCA is given by using the jKQML programming. The establishment of NMCA platform will be helpful to reduce the correspondence load of network management and improves the efficiency and the expansion ability of network management systems. 相似文献
10.
A glass fiber piezooptical optical bistability device is reported.Basing on pho-toelastic and strain effects of single-mode fiber,we have realized piezooptical modulation andperformed experiments of optical bistability. 相似文献