(S)-(+)-姜黄烯的立体选择性全合成

利用不对称双羟化反应和Raney镍的原位还原,高对映选择性和高产率地实现了(S)-(+)-α-姜黄烯(1)的立体选择性合成.用MsCl保护化合物7a和7b时,发现了有趣的消除和重排反应,得到对应的二烯化合物8.     

An alternating periodic－chaotic ISI sequence of HH neuron under external sinusoidal stimulus

A study of Hodgkin－Huxley (HH) neuron under external sinusoidal excited stimulus is presented in this paper. As is well known, the stimulus frequency is to be considered as a bifurcate parameter, and numerous phenomena, such as synchronization, period, and chaos appear alternatively with the changing of the stimulus frequency. For the stimulus frequency less than 2f_B (f_B being the base frequency in this paper), the simulation results demonstrate that the single HH neuron could completely convey the sinusoidal signal in anti-phase into interspike interval (ISI) sequences. We also report, perhaps for the first time, another kind of phenomenon, the beat phenomenon, which exists in the phase dynamics of the ISI sequences of the HH neuron stimulated by a sinusoidal current. It is shown furthermore that intermittent transition results in the general route to chaos.     

弱的参数周期扰动对一非线性系统安全域的影响与分形侵蚀安全域的控制

讨论了弱参数周期扰动对于非线性系统安全域的影响,在一定频率下的参数周期扰动将加速安全域的分形侵蚀,而在另一些频率的扰动下,将抑制安全域的分形侵蚀,并且存在着增进安全域的最优频率.提出了用弱参数周期扰动控制受到分形侵蚀的安全域的方法,并用Melnikov方法进行了分析.最后讨论了这种控制安全域的方法在实际环境中当具有外加噪声时的鲁棒性. 关键词： 分形吸引域边界 参数的周期扰动 控制     

GaAs光导开关飞秒激光点触发实验及分析

针对光导开关阵列和光纤分束耦合的实际应用环境,提出一种新的实验方案,用于测试当触发光源相对于开关光敏面为点光源时入射位置对输出脉冲的影响.实验证明,不同的入射位置对开关输出脉冲有很大的影响.在入射光从负极向正极扫描过程中输出脉冲逐渐增强,在正极附近输出达到峰值,但在电极边缘处有所减弱.分析表明,这一现象和开关体内电场的分布有密切联系.     

915 nm宽条形半导体激光器输出特性

为了研究温升对915 nm宽条形应变量子阱半导体激光器输出特性的影响,搭建了基于半导体制冷片(TEC)的双向温控平台对其进行了测试。首先,改变激光器的外表面温度,测量其在不同注入电流时的光功率和波长,并利用CCD相机测量其慢轴发散角。然后,利用计算机仿真软件对激光器的工作状态进行稳态模拟,从而获得了其对应的热分布情况,通过将模拟得到的数据与实验测量的结果进行比较,获得了两者趋于一致的结论:当热功率从2.1 W升高至20.0 W时,慢轴发散角从2.6°增大至5.0°,同时波长发生红移,热透镜焦距减小;激光器波长随温度变化关系的系数约为0.4 nm/℃,器件热阻为1.5 K/W。因此,为了同时获得高的输出功率和稳定的输出波长,有必要将激光器外表面温度精确控制在某一数值,否则波长将会发生漂移;此外,在设计制作高功率半导体激光器时,通过适当增加条宽并采用散热良好的封装结构,可以减小对慢轴发散角的影响。     

图形处理器并行计算用于离子发动机粒子模拟

为了研究离子发动机羽流对航天器的影响,采用质点网格-蒙特卡罗碰撞方法对离子发动机羽流中的交换电荷离子进行了模拟。利用计算设备统一架构技术,开发出一套基于图形处理器的并行粒子模拟程序。随机数生成采用并行MT19937伪随机数生成器算法,电场方程使用完全近似存储格式的代数多重网格法求解。r-z轴对称坐标系中,在z=0 m处获得的电流密度均值为4.5×10-5 A/m2,图形处理器所得结果与中央处理器模拟结果吻合。在16核心的NVIDIA GeForce 9400 GT图形显示卡上,取得相对于Intel Core 2 E6300中央处理器4.5~10.0倍的加速比。     

基于多曝光图像融合的沙尘图像增强

针对沙尘图像存在细节模糊、对比度低和颜色偏移等问题,提出了基于多曝光图像融合的沙尘图像增强算法.首先对蓝通道进行补偿,以弥补沙尘图像的蓝光损失;其次对图像的RGB三通道分别进行标准化,以减小通道直方图之间的偏离,从而去除偏色.为了提高图像中不同区域的细节,采用线性参数控制的方法生成多幅曝光图像.通过用对比度、饱和度和良...     

一段反应法制备宽/双峰聚乙烯催化剂的研究进展

阐述了采用一段反应法制备宽/双峰聚乙烯催化剂的研究开发进展,并根据催化剂的组成和结构,将催化体系归纳为复合催化剂和单组分催化剂.复合催化剂包括茂金属/Ziegler-Natta复合催化剂、不同茂金属复合催化剂、铬系/Ziegler-Natta复合催化剂、茂金属/后过渡金属复合催化剂、非茂单活性中心/茂金属复合催化剂、非茂单活性中心/Ziegler-Natta复合催化剂和不同后过渡金属复合催化剂.复合催化剂中多活性组分具有不同的链增长、链转移、链终止速率常数,从而在聚合反应中得到不同相对分子质量的聚合物,导致其相对分子质量分布加宽,因而复合催化剂可用于一段反应法制备宽/双峰聚乙烯.单组分催化剂包括单核茂金属催化剂、多核茂金属催化剂、后过渡金属催化剂及其它单组分催化剂.单组分催化剂可用于一段反应法制备宽/双峰聚乙烯,其催化机理是中心金属原子与主配体、辅配体、助催化剂、其它添加剂及载体形成了多种活性中心.     

A light scalar in the Minimal Dilaton Model in light of the LHC constraints

Whether an additional light scalar exists is an interesting topic in particle physics beyond the Standard Model(SM), as we do not know as yet the nature of physics beyond the SM in the low mass region in view of the inconsistent results of the ATLAS and CMS collaborations in their search for light resonances around 95 GeV in the diphoton channel. We study a light scalar in the Minimal Dilaton Model(MDM). Under the theoretical and the latest experimental constraints, we sort the selected data samples into two scenarios according to the diphoton rate of the light scalar: the large-diphoton scenario(with σ_(γγ)/SM■0.2) and the small-diphoton scenario(with σ_(γγ)/SM■0.2),which are favored by the CMS and ATLAS results, respectively. We compare the two scenarios, test the characteristics of the model parameters, the scalar couplings, production and decay, and consider how they could be further discerned at colliders. We draw the following conclusions for the two scenarios:(i) The large-diphoton scenario has in general a small Higgs-dilaton mixing angle(|sinθ_S|■0.2) and a small dilaton vacuum expectation value(VEV)f(0.5■η≡ v/f■1),and the small-diphoton scenario has large mixing(| sinθ_S|■0.4) or large VEV(η≡v/f ■0.3).(ii) The large-diphoton scenario in general predicts small syy coupling(|C_(sγγ)/SM|■ 0.3) and large sgg coupling(0.6■|C_(sgg)/SM|■1.2), while the small-diphoton scenario predicts small sgg coupling(|C_(sgg)/SM|■0.5).(iii) The large-diphoton scenario can interpret the small diphoton excess seen by CMS at its central value, when m_s■ 95 GeV,η■0.6 and | sinθ_S|■0.(iv) The large-diphoton scenario in general predicts a negative correlation between the Higgs couplings |C_(hγγ)/SMI and |C_(hgg)/SM|, while the small-diphoton scenario predicts that both couplings are smaller than 1,or |C_(hγγ)/SM|■0.9■|C_(hgg)/SM|.