硫代双烯酮与硫甲醛环加成反应机理的理论研究

采用从头算HF/6-31G^*和密度泛函B3LYP/6-31++G^*^*方法研究了硫代双烯酮与硫甲醛两种可能的环加成反应的机理,并对反应各驻点进行了电子密度拓扑分析研究.结果表明,这两个生成不同四元杂环产物的平行反应均为有一两性离子中间体的分步反应.两个反应均较易进行,但反应(1)更容易一些,结果与实验一致.     

城镇流动人口管理模式研究

本文在系统地分析流动人口基本特征的基础上,提出了流动人口管理的基本思路和目标模式。流动人口对城镇发展有着积极的推动作用,也给城镇的发展带来一系列的问题。对流动人口的管理是一项复杂的系统工程,其管理需要在统一思想认识的基础上,建立健全有关法规,由各有关部门积极协作,制订一系列的具体措施共同来完成。     

PandaX实验的进展与展望

PandaX是位于四川的中国锦屏地下实验室（CJPL）内的,利用氙作为工作物质,探测暗物质等其它极稀有事件的大型地下粒子探测实验计划。PandaX探测器中的氙工作在气液两相的模式。通过检测液相和气相中闪烁光强的比例,实现对目标粒子包括WIMP和Axion等疑似信号的鉴别。PandaX已顺利完成了有效区体积约为120 kg氙的一期计划,目前正在运行实施有效区体积约为500 kg氙的二期计划。在WIMP质量为45 GeV/c2附近,探测灵敏度达2.97×10-45 cm2（90%置信度）,没有发现WIMP疑似信号。本工作介绍了PandaX一期和二期的进展,以及后续升级计划,其中包括升级PandaX的时间投影室至4吨,建造用于屏蔽岩石放射性本底的水屏蔽,以及136Xe双贝塔衰变的研究计划等。PandaX is a xenon-based dark matter and other rare events searching project located at China JinPing underground Laboratory (CJPL), Sichuan province, China. Dual phases, liquid and gas phase of xenon are used in the detector. Particles, including Weak Interaction Massive Particles (WIMPs) or axions etc., may induce scintillating signals in both liquid (S1 signal) and gas (S2 signal) phases, and then are identified by analyzing the ratio of S1 and S2. The PandaX had completed its first stage, the 120 kg in fiducial volume, and now is running in its stage Ⅱ with fiducial volume of 500 kg. The running results show that the WIMP-matter cross section detecting sensitivity of about 2.97×10-45 cm2(90% C.L.) has been achieved at a WIMP mass of 44.7 GeV/c2, and no WIMP candidates are identified. The upgrading plan of the PandaX is discussed, which include to build a larger Time project chamber (TPC) of about 4 tons, a water tank for radiation shielding, and the plan of 136Xe double beta decay studies.     

轻粒子产额及其关联的同位旋效应

用晶格气体模型系统地研究了热发射体的粒子发射特性,阐述了发射体系的同位旋对轻系统的中子、带电粒子和轻粒子产额,以及对轻粒子产额比和双产额同位素比的影响.发现轻粒子产额和产额比是复合系统同位旋的敏感观测量,而双产额同位素比几乎不依赖于体系的同位旋.     

微观半经典Vlasov框架下的巨偶极共振的系统学与同位旋效应

用微观半经典Vlasov方法研究了同位旋矢量巨偶极共振(GDR)的系统学.计算的GDR强度分布的峰位能量和宽度与实验结果是一致的,并与经验公式相符.计算还表明峰位能量有微小的同位旋效应,而峰的宽度几乎没有同位旋效应.     

“颈”发射过程中的中等质量碎片的研究

系统地研究“颈”发射过程中的中等质量碎片,能使我们更好地理解中能核反应的动力学和热力学性质.采用具有不同的同位旋靶核研究了靶同位旋与中等质量碎片的关系,以及区分反应过程中类弹、类靶产生的中等质量碎片和“颈”发射过程中产生的中等质量碎片.HJ4/9] By systematic study of the IMF produced the “neck”emission process, one can understand much better about the dynamics and thermodymanics of the intermediate energy nuclear reaction. The isospin dependence of IMF emission was studied for the reaction system with different isospin target nucleus and the different IMF production mechanisms that originate from projectile like、 target like and the “neck” were distinguished.     

[2+2]环加成反应机理的理论研究

[2+2]环加成反应是有机化学中非常重要的一类反应,其机理的研究一直是实验和理论工作者关注的课题之一。本文从理论的角度综述了三类[2+2]环加成反应的反应机理,即简单烯烃或炔烃参与的环加成反应、累积双键体系参与的环加成反应以及稀土钍化合物参与的环加成反应, 得出对于简单的烯烃或炔烃之间的环加成反应一般是按双自由基机理进行,而其他两类反应主要按协同或两性离子方式进行,并且从前线分子轨道作用理论角度分析了产生不同反应机理的原因。     

采用隔离池的毛细管电泳-间接紫外吸收法测定茶叶中的氨基酸

改进的毛细管电泳-间接紫外吸收法采用了自制隔离池,以对氨基苯甲酸(PAB)为背景电解质,对茶叶中的氨基酸进行了测定。PAB能够提高分离效率,降低检出限。隔离池的使用避免了PAB的电极反应,降低了基线噪声,维持了两缓冲液池间的电流导通。研究了背景电解质的浓度、pH值以及电渗流改性剂的种类和浓度对氨基酸分离的影响。在优化的实验条件下,16种氨基酸在14 min内达到了基线分离,峰面积的相对标准偏差小于5%(n=5),检出限为1.7~4.5 μmol/L,回收率为83.0%~106%。该法快速、便捷和灵敏,已成功应用于茶叶中11种游离氨基酸的检测。     

Scaling of anisotropic flows and nuclear equation of state in intermediate energy heavy ion collisions

Elliptic flow ($v_2$) and hexadecupole flow ($v_4$) of light clusters have been studied in detail for 25 MeV/nucleon $^{86}$Kr + $^{124}$Sn at large impact parameters by using a quantum molecular dynamics model with different potential parameters. Four sets of parameters including soft or hard equation of state (EOS) with or without symmetry energy term are used. Both number-of-nucleon ($A$) scaling of the elliptic flow versus transverse momentum ($p_{\rm t}$) and the scaling of $v_4/A^{2}$ versus $(p_{\rm t}/A)^2$ have been demonstrated for the light clusters in all above calculation conditions. It is also found that the ratio of $v_4/{v_2}^2$ maintains a constant of 1/2 which is independent of $p_{\rm t}$ for all the light fragments. Comparisons among different combinations of the EOS and the symmetry potential term show that the above scaling behaviours are sound and independent of the details of potential, while the strengths of flows are sensitive to the EOS and the symmetry potential term.     

Isoscaling of projectile-like fragments

In this paper, the isotopic and isotonic distributions of projectile fragmentation products have been simulated by a modified statistical abrasion--ablation model and the isoscaling behaviour of projectile-like fragments has been discussed. The isoscaling parameters α and β have been extracted respectively, for hot fragments before evaporation and cold fragments after evaporation. It looks that the evaporation has stronger effect on α than β. For cold fragments, a monotonic increase of α and β with the increase of Z and N is observed. The relation between isoscaling parameter and the change of isospin content is discussed.