铜的喹哪啶配合物[Cu(Me-quin)2H2O]的合成、表征及晶体结构

本文合成了铜的喹哪啶配合物[Cu(Me-quin)     

基于流媒体的视频点播系统设计

结合流媒体技术和网页技术，探讨如何实现一个流媒体系统同时支持Real System和Windows Media两种流媒体格式的发布以及怎样设计数据库来管理流媒体资源，给出流媒体的制作、播放和管理方法，最后模拟了一个基于流媒体的网上视频点播系统。     

采用干法刻蚀进行微通道板扩口理论模型研究

开口面积比是微通道板（MCP）重要的性能指标,在MCP输入面进行扩口,对于MCP的探测效率、噪声因子等参数有显著的提升作用,在微光夜视仪、粒子探测器等军用、民用领域具有巨大的应用潜力。采用湿法腐蚀进行微通道板扩口,面临工艺一致性差、选择性腐蚀造成锥度尺寸难以达标等难题,实质性批量应用非常困难。针对扩口MCP难以制作和应用的问题,提出一种采用干法刻蚀进行MCP扩口的方法,阐述了干法刻蚀进行MCP扩口原理及可行性。通过建立理论模型研究干法刻蚀工艺参数如刻蚀角度、刻蚀时间等对于MCP开口面积比、通道内刻蚀深度、通道内壁刻蚀锥度等性能参数的影响,计算出合适的工艺参数范围,为开展实验研究奠定了基础。     

宽带射频功放晶体管非线性输出电容研究

分析了GaN(氮化镓)HEMT(高电子迁移率晶体管)非线性输出电容Cout与宽带功放效率的关系。通过建立非线性电路模型分析得出,利用Cout控制漏极端电压电流波形能减轻对谐波阻抗的精确要求,使高效率阻抗区域扩大化,从而使宽带功放匹配变为可能。选用GaN HEMT器件设计2~3 GHz频段射频功率放大器,实测结果为该放大器最高漏极效率(DE)为81.7%,功率附加效率(PAE)78.3%,功率为40.75 dBm。在1 GHz带宽内PAE也可达65%以上。实测结果验证了原理分析的可靠性,提出的方法不仅可用于宽带GaN功率放大器设计,对其他类型的微波功放设计同样有借鉴作用。     

针对一类JPEG图像伪造的被动盲取证

图像合成是一种最常见的图像伪造手段。该文针对一类JPEG图像合成伪造,根据篡改区域与非篡改区域块效应的不一致性,提出了一种简单有效的检测算法。首先利用估计的一次压缩质量因子对待检测图像进行裁剪再压缩,然后通过计算压缩前后的失真提取图像的块效应指数映射图,最后采用图像分割的方法实现篡改区域的自动检测与定位。实验结果表明,算法对于各种质量的JPEG图像和较小的篡改区域均能有效检测,当二次压缩与一次压缩的质量因子之差在15以上,虚警率控制在5%以内时,检测率可达93%以上。     

咪唑配合物[Co(C3H4N2)6](PhCHCHCOO)2的合成及晶体结构

The complex [Co(Im)6](Cin)2 (Im=imidazole,Cin=cinnamate) was prepared by reaction of Co(PhCHCHCOO)2 with imidazole in ethanol. It has been determined by single crystal X-ray analyses. The crystals are triclinic, space group P, with a=9.7601(3),b=10.5935(3),c=11.3269(2)(A),α =69.948(1),β =71.027(1),γ =62.803(1)°, and Z=1. The crystal structure of the title complex consists of monomeric [Co(Im)6]2+ cations and cinnamate anions in which the cobalt(Ⅱ) ion assumes a centrosymmetric octahedral geometry with the CoN6 chromophore. In the solid state, the complex forms a three dimensional network through N-H… O hydrogen bonds, the intermolecular hydrogen bonds connect the [Co(Im)6]2+ cations and cinnamate anions.The cinnamate anions are nearly planar.     

A Density Functional Theory Study on Electronic Structure and Second—order Nonlinear Optical Properties of Some Push—Pull Molecules

Time-dependent density-functional theory(TDDFT)has been applied to calculate the electronic structure and second-order nonlinear optical(NLO) properties of some organic molecules.The two-dimensional(2-D)charge transfer charateristics of calculated molecules were studied and compared with corresponding experimental results.All the theoretical results agree well with the measurement.For 2-D molecule with two-fold symmetry,the dominant charge transfer is off-diagonal,while for three-fold symmetry 2-D molecule,the dominant charge transfer is not only between branches and central group but also among branches.     

Synthesis and Crystal Structure of 2-Chloromethyl-1H-benzimidazole Nitrate, [ClCH_2(C_7H_6N_2)]NO_3

1 INTRODUCTION Benzimidazole is an interesting heterocyclic compound because it is found in various naturally occurring drugs, such as omeprazole, astemizole and emedastine difumarate[1]. The efficacy of sub- stituted benzimidazoles in the treatment of parasitic infections is well known[2～4]. Substituted benzimid- azole moieties are established pharmacophores in parasitic chemotherapy. Bis(2-benzimidazole) and some substituted bis(benzimidazol-2-yl)alkanes have attracted much interest …     

Crystal Structure of Chlorinate （N,N-1,3-Dibenzyl-benzimidazole） Hydrate

1 INTRODUCTION Benzimidazole is an interesting heterocyclic ring because it is present in various naturally occurring drugs, such as omeprazole, astemizole and emedastine difumarate[1]. The efficacy of substituted benzimidazoles in the treatment of parasitic infections is well known[2～4], and the pharmacophores in parasitic chemotherapy are established by benzimidazole-substituted moieties. Bis(2-benzimidazoles) and some substituted bis- (benzimi-dazol-2-yl) alkanes have attracted much…     

一种新的De Novo生物活性分子设计方法

由药效团进行虚拟活性结构生成与3D-QSAR模型相结合,筛选出有前途的结构多样性的化合物,并从中寻找活性先导化合物,是一种新的分子设计方法。采用这种方法对抗小麦赤霉病类含氟农药进行了研究,共生成了53个虚拟活性结构,通过3D-QSAR模型筛选出其中10个活性较高的结构,在活性最高的化合物基础上进行了结构修饰,得到了活性更高且毒性较低的理想化合物。研究结果表明这种方法能突破原模型化合物结构模式的局限,可以找到结构新颖的活性先导化合物,是一种非常有前途的分子设计方法,而且具有较高的筛选效率。