排序方式: 共有37条查询结果,搜索用时 15 毫秒
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用振簧法在-150℃至100℃温度范围内测定了聚二甲基硅氧烷和聚甲基(苯基)硅氧烷嵌段共聚物及与其组份相同的共混物的动态力学温度谱。在研究的温度范围内嵌段共聚和共混试样都有两个内耗峰、分别为橡胶相和树脂相的玻璃化转变T_g1和T_g2。嵌段共聚或共混对T_g1和T_g2峰位置的影响较小。用归一化作图法比较了T_g1和T_g2内耗峰的形状,发现嵌段共聚的T_g1峰较共混者宽,而T_g2峰较共混者为窄,并从第二组份对分子运动影响的观点对此现象作了解释。研究了橡胶链段长度对嵌段共聚物T_g1位置和峰形影响的规律。估算出聚二甲基硅氧烷玻璃化转变运动单元的链段长度(Si—O)_n,n大约是80。 相似文献
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多嵌段聚氨酯(SPU)是一种重要的医用高分子材料,其表面化学组成、表面结构,对血液相容性有直接关系。本文用电子能谱(ESCA)研究了两种链结构SPU的表面化学组成,其目的是了解表面组成与其本体结构及性能的关系,并将SPU表面组成与本体的相分离程度联系起来。实验结果表明:(1)在SPU-空气界面上O/N原子比大于其本体O/N原子比,即软段富集于表面;(2)分相程度高的SPU试样较分相程度低的试样其软段在表面富集得更多;(3)在50左右深度的表面层内相分离程度高的试样其O/N组成变化的梯度较大。 相似文献
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5G边缘计算和网络切片技术 总被引:7,自引:3,他引:4
由于能够以低成本提供5G无线网络中多样化的业务场景,网络切片和边缘计算一直以来深受学术界和工业界的提倡.网络切片通过将网络实体划分成多个逻辑独立网络,为不同业务场景提供所需服务,而边缘计算利用网络中用户和边缘网络设备的计算和存储功能,承载部分核心节点中的控制、管理、业务功能,能够提升传统移动宽带业务能力和应对新兴的机器类业务.将网络切片和边缘计算融合,提出了基于边缘计算的接入网络切片,能够满足5G中广泛的用例和商业模型,使得运营商能够根据第三方需求和网络状况以低成本为用户灵活提供个性化的网络服务. 相似文献
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PLC在榨菜自动包装机控制系统中的应用 总被引:2,自引:0,他引:2
介绍了PLC在榨菜自动包装机控制系统中的应用及梯形图编程,并对其运行状态的通讯监测系统作了阐述。 相似文献
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Blends of PVC and polyurethanes with four different soft segments of molecular weight 1000 were prepared and studied by dynamic mechanical and DSC techniques. It was found that the compatibility of PVC with segmented polyurethanes was related to the mixing of PVC molecules and the soft segments of the polyurethanes. Polyester based polyurethanes are more compatible with PVC than polyether based polyurethanes. Solution cast blends of PVC with PCL-polyurethane (1/2/1) exhibit single and narrow glass transition, while the blends with PPO-polyurethane (1/2/1) are completely incompatible. The compatibility was found to decrease with increasing hard segment content for all the polyurethanes used. The methods of blend preparation may change the compatibility of PVC/PU blends through their influence on the mixing or demixing of the hard and soft segments. 相似文献
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SHAPE MEMORY EFFECT OF SLIGHTLY-CROSSLINKED POLYETHYLENE 总被引:3,自引:0,他引:3
A series of slightly crosslinked polyethylenes (SXLPE) was prepared by aone-step method using dicumyl peroxide as crosslinking agent in a Haake Mixer. The gelcontents G (Soxhlet extracted) of the samples are in the range from 5% to 20% by weight.Their shear viscosity, crystallization and melting behavior, dynamic mechanical propertiesand shape recovery effect were systematically investigated in terms of the content of thecrosslinking agent. It shows that under certain experimental conditions the SXLPE's mayexhibit good shape fixation ability and shape memory properties, which are similar to thoseof the commercially available shape memory polyethylenes prepared by gamma-irradiationtechnique. However the shape memory behavior of these samples is not very stable due totheir low crosslinking degree, or gel content. Thus their application is limited in specialcases with fast strain fixing procedures. 相似文献
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1-苯并噻唑硫乙酰基-4-芳酰氨基硫脲类化合物的合成 总被引:5,自引:0,他引:5
Dorothy曾对烷基和芳基取代的硫脲类化合物的合成及应用作过评论[1]. 相似文献