Simultaneous determination of trap depth and the ratio of the rate of recombination to that of capture from thermo-luminescence

Thermo-luminescence (TL) is a kind of luminescence decay measured with varying temperature. In the process of TL the decay parameter itself involves the temperature effect of traps. Thus the trap depth is inseparable from the decay parameter. There are two separate peaks in the TL curve of ZnS:Cu,Co if the measurement starts from liquid nitrogen temperature. In the experiment we started from zero Celsius temperature to isolate the deeper traps. We have proposed and realized three methods for simultaneous determination of trap depth and decay parameter based on the quasi-equilibrium model and experimental data. If we treat the case of kinetic order \alpha =1 as \alpha =2, the error might be as large as 100%.     

固态阴极射线器件复合加速层的研究

固态阴极射线器件的加速层,是提高固态阴极射线性能的重要部分,它能够加大电子能量,倍增电子数量。其中增加注入电子从而提高过热电子的数量,是提高固态阴极射线器件性能的关键。为此 ,文章尝试将加速层复合,兼顾加速与电子注入性能。首先将SiO₂,ZnS和ZnO分别与有机聚合物MEH-PPV组合,确定较适合的复合加速层的组合：SiO₂/ZnS和 ZnO/SiO₂。然后将这两种复合加速层的性能对比,发现SiO₂/ZnS的性能更优越,因为电子注入性能ZnS和ZnO相当,而电子加速倍增性能ZnS明显优于ZnO,其中 SiO₂为主要的加速层,而ZnS起到降低注入势垒变成阶梯势垒的作用。最后又将复合加速层结构的固态阴极射线器件和传统的SiO₂夹层固态阴极射线器件对比,发现这种复合 加速层结构,尤其在高场下,可提高固态阴极射线的初电子源和过热电子的数目,从而提高其发光效率具有促进作用。     

水溶性CuPc旋涂转速及退火方式对蓝色有机电致发光器件性能的影响

本文以Be(PP)₂为发光层、水溶性酞菁铜(WS-CuPc)为空穴注入层、NPB为空穴传输层,制备了结构为ITO/WS-CuPc/NPB/Be(PP)₂/LiF/Al的蓝色有机发光二极管(OLEDs).研究了WS-CuPc不同旋涂转速对器件性能的影响.并在WS-CuPc最佳旋涂转速的基础上,进一步研究了WS-CuPc薄膜不同退火方式对器件性能的影响.实验中,对WS-CuPc层采用了一种新的退火方式,即对ITO玻璃衬底先加热后旋涂WS-CuPc层,并与传统退火方式 关键词： 水溶性CuPc 蓝色有机电致发光 旋涂转速 退火方式     

有机薄膜晶体管中接触效应的研究

研究了接触效应对有机薄膜晶体管性能的影响.首先在n型重掺杂Si片上制备了以M_OO₃修饰的Al电极为源漏电极的Pentacene基OTFTs(organic thin film transistors),器件场效应迁移率μ_ef达到0.42 cm²/V ·s,阈值电压V_T为-9.16 V,开关比4.7×10³.通过中间探针法,对器件电势分布做了定性判断 关键词： 有机薄膜晶体管 场效应迁移率 接触效应 电荷漂移     

Highly sensitive polymer photodetectors with a wide spectral response range

A series of highly sensitive polymer photodetectors(PPDs) was fabricated with P3HT100-x:PBDT-TS1x:PC71BM1 as the active layers, where x represents the PBDT-TS1 doping weight ratio in donors. The response range of PPDs can cover from the UV to near-infrared regions by adjusting the PBDT-TS1 doping weight ratio. The best external quantum efficiency(EQE) values of ternary PPDs with P3HT:PBDT-TS1:PC_(71)BM(50:50:1 wt/wt/wt) as the active layers reach 830%, 720%,and 330% under 390-, 625-, and 760-nm light illumination and-10 V bias, respectively. The large EQE values indicate that the photodetectors utilise photomultiplication(PM). The working mechanism of PM-type PPDs can be attributed to interfacial trap-assisted hole tunnelling injection from the external circuit under light illumination. The calculated optical field and photogenerated electron volume density in the active layers can well explain the EQE spectral shape as a function of the PBDT-TS1 doping weight ratio in donors.     

倾斜式生长ZnS纳米柱状薄膜及其透射性能的研究

采用倾斜式生长的方法,在本底真空为3×10-4 Pa,生长率为0.2 nm·s-1的条件下,通过改变衬底的法线方向与入射粒子流的夹角α,在ITO导电玻璃衬底上制备了ZnS纳米薄膜。在α=80°和85°时,样品的Ｘ射线衍射谱证实了不同倾斜角时所制备薄膜中均有纳米ZnS晶体形成,扫描电子显微镜(SEM)图像显示,所形成的薄膜均呈现出了柱状结构,并且倾斜角为85°时所得到的纳米柱直径大于80°时所得结果;在α=0°时,相应测量结果表明,虽然在不同衬底上也形成了纳米ZnS晶体薄膜,但并未见柱状结构,而是形成了一层均匀且致密的薄膜。对两种薄膜结构的生长动力学过程作了分析。ITO衬底上薄膜的透射光谱表明ZnS柱状薄膜能够提高可见光的透过率,因此对柱状ZnS纳米薄膜的研究将有利于提高电致发光器件的发光效率。     

Thickness dependence of surface morphology and charge carrier mobility in organic field-effect transistors

With the aim of understanding the relationships between organic small molecule field-effect transistors (FETs) and organic conjugated polymer FETs, we investigate the thickness dependence of surface morphology and charge carrier mobility in pentacene and regioregular poly (3-hexylthiophene) (RR-P3HT) field-effect transistors. On the basis of the results of surface morphologies and electrical properties, we presume that the charge carrier mobility is largely related to the morphology of the organic active layer. We observe that the change trends of the surface morphologies (average size and average roughness) of pentacene and RR-P3HT thin films are mutually opposite, as the thickness of the organic layer increases. Further, we demonstrate that the change trends of the field-effect mobilities of pentacene and RR-P3HT FETs are also opposite to each other, as the thickness of the organic layer increases within its limit.     

有机无线射频识别技术的研究进展

介绍了有机无线射频识别（RFID）标签的工作及制备技术原理。为了解决RFID标签的高成本一直制约RFID技术普及的问题,提出了采用有机半导体进行RFID标签制备的方案,分析了有机RFID标签的含义、构成、制备技术特点以及国外研究概况、未来市场状况等方面的内容。讨论了有机RFID与无机RFID标签在材料及加工工艺方面的区别,有机电子可以通过采用印刷工艺,完成大规模有机电路的集成,大大降低RFID标签的成本。指出有机RFID技术无论是生产材料还是生产方式都比无机RFID技术极具优势,符合未来商业化的要求及应用。     

ZnSe为发光层的蓝绿光薄膜电致发光器件的发光性能

采用具有电子加速能力的Si02代替传统夹层结构中的绝缘层,利用电子束蒸发的方法制备了结构为ITO/SiO2/ZnSe/SiO2/Al的电致发光器件,观察到了传统夹层结构所没有的ZnSe层电致发光.测量了器件的电致发光光谱及总发光强度随着驱动电压及驱动频率的变化关系.讨论了器件的发光机理,认为是初电子经过SiO2层加速,获得较高能量,然后碰撞ZnSe分子,将其价带的电子激发到导带,再跃迁回价带或缺陷能级与空穴复合发光.由于这种发光方式类似于阴极射线发光,只不过电子在固体中而不是真空中加速,所以称之为固态阴极射线发光.这种机理为实现蓝色电致发光提供了新的途径.     

ZnSe为发光层的蓝绿光薄膜电致发光器件的发光性能

采用具有电子加速能力的Si02代替传统夹层结构中的绝缘层,利用电子束蒸发的方法制备了结构为ITO/SiO2/ZnSe/SiO2/Al的电致发光器件,观察到了传统夹层结构所没有的ZnSe层电致发光.测量了器件的电致发光光谱及总发光强度随着驱动电压及驱动频率的变化关系.讨论了器件的发光机理,认为是初电子经过SiO2层加速,获得较高能量,然后碰撞ZnSe分子,将其价带的电子激发到导带,再跃迁回价带或缺陷能级与空穴复合发光.由于这种发光方式类似于阴极射线发光,只不过电子在固体中而不是真空中加速,所以称之为固态阴极射线发光.这种机理为实现蓝色电致发光提供了新的途径.